Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
New High-Pressure and High-Temperature CaCO3Polymorph. / Druzhbin, Dmitrii; Rashchenko, Sergey V.; Shatskiy, Anton и др.
в: ACS Earth and Space Chemistry, Том 6, № 6, 16.06.2022, стр. 1506-1513.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - New High-Pressure and High-Temperature CaCO3Polymorph
AU - Druzhbin, Dmitrii
AU - Rashchenko, Sergey V.
AU - Shatskiy, Anton
AU - Crichton, Wilson A.
N1 - Funding Information: W.A.C. and D.D. were supported by the European Synchrotron Radiation Facility (ESRF). The work of S.V.R. was supported by RSF grant #21-77-00016. A.S. was supported by the state assignment of IGAC RAS. Publisher Copyright: © 2022 American Chemical Society.
PY - 2022/6/16
Y1 - 2022/6/16
N2 - In this work, we report an experimental observation of a new CaCO3calcite-Vb phase, which occurs as the intermediate between aragonite and calcite-V at pressures >3.5 GPa and temperatures >1200 °C, suggesting it can exist in CaCO3-containing rocks at â 125-200 km. Calcite-Vb is determined to have the KClO3-Type structure with the monoclinic P21/m space group and lattice parameters of a = 6.284(5) Å, b = 4.870(3) Å, c = 3.991(4) Å, β = 107.94(3)°, and V = 116.19(15) Å3. Possible transformation mechanisms between calcite-Vb, aragonite, and calcite-V are illustrated.
AB - In this work, we report an experimental observation of a new CaCO3calcite-Vb phase, which occurs as the intermediate between aragonite and calcite-V at pressures >3.5 GPa and temperatures >1200 °C, suggesting it can exist in CaCO3-containing rocks at â 125-200 km. Calcite-Vb is determined to have the KClO3-Type structure with the monoclinic P21/m space group and lattice parameters of a = 6.284(5) Å, b = 4.870(3) Å, c = 3.991(4) Å, β = 107.94(3)°, and V = 116.19(15) Å3. Possible transformation mechanisms between calcite-Vb, aragonite, and calcite-V are illustrated.
KW - aragonite
KW - calcite
KW - high-pressure
KW - multianvil
KW - phase transition
KW - X-ray diffraction
UR - http://www.scopus.com/inward/record.url?scp=85131464572&partnerID=8YFLogxK
U2 - 10.1021/acsearthspacechem.2c00019
DO - 10.1021/acsearthspacechem.2c00019
M3 - Article
AN - SCOPUS:85131464572
VL - 6
SP - 1506
EP - 1513
JO - ACS Earth and Space Chemistry
JF - ACS Earth and Space Chemistry
SN - 2472-3452
IS - 6
ER -
ID: 36436511