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Monoterpenoid Oximes Hydrogenation Over Platinum Catalysts. / Demidova, Yu S.; Mozhaitsev, E. S.; Munkuev, A. A. и др.

в: Topics in Catalysis, Том 63, № 1-2, 01.03.2020, стр. 187-195.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

Demidova, YS, Mozhaitsev, ES, Munkuev, AA, Suslov, EV, Saraev, AA, Volcho, KP, Salakhutdinov, NF, Simakova, IL & Murzin, DY 2020, 'Monoterpenoid Oximes Hydrogenation Over Platinum Catalysts', Topics in Catalysis, Том. 63, № 1-2, стр. 187-195. https://doi.org/10.1007/s11244-020-01234-x

APA

Demidova, Y. S., Mozhaitsev, E. S., Munkuev, A. A., Suslov, E. V., Saraev, A. A., Volcho, K. P., Salakhutdinov, N. F., Simakova, I. L., & Murzin, D. Y. (2020). Monoterpenoid Oximes Hydrogenation Over Platinum Catalysts. Topics in Catalysis, 63(1-2), 187-195. https://doi.org/10.1007/s11244-020-01234-x

Vancouver

Demidova YS, Mozhaitsev ES, Munkuev AA, Suslov EV, Saraev AA, Volcho KP и др. Monoterpenoid Oximes Hydrogenation Over Platinum Catalysts. Topics in Catalysis. 2020 март 1;63(1-2):187-195. doi: 10.1007/s11244-020-01234-x

Author

Demidova, Yu S. ; Mozhaitsev, E. S. ; Munkuev, A. A. и др. / Monoterpenoid Oximes Hydrogenation Over Platinum Catalysts. в: Topics in Catalysis. 2020 ; Том 63, № 1-2. стр. 187-195.

BibTeX

@article{eccb14b6bcd0465fbd61bafbbf23f18a,
title = "Monoterpenoid Oximes Hydrogenation Over Platinum Catalysts",
abstract = "Platinum nanoparticles supported on MgO, Al2O3, ZrO2, TiO2 were utilized for monoterpenoid oximes hydrogenation. Monocyclic menthone and carvone oximes synthesized from bio-derived monoterpenoids with a different structure were used to explore the effect of substrate structure on the reaction regularities. The oximes hydrogenation was carried out under hydrogen atmosphere at 100 °C using methanol as a solvent. Platinum catalysts were prepared by the impregnation methods. The catalysts were characterized by transmission electron microscopy, X-ray photoelectron spectroscopy, X-ray fluorescence spectroscopy, nitrogen physisorption. Hydrogenation of carvone oxime containing a conjugated oxime group and several reducible functional groups resulted in both hydrogenation and deoximation giving 5-isopropyl-2-methylcyclohexanamine and carvomenthone over Pt/Al2O3 and Pt/ZrO2 catalysts. Menthone oxime hydrogenation over Pt/Al2O3 catalysts with an average particle size of 0.8 nm provided the desired menthylamine formation with the selectivity of 90% at complete oxime conversion. Platinum catalysts based on MgO, ZrO2 and TiO2 enhanced menthone oxime deoximation to menthone.",
keywords = "Carvone oxime, Hydrogenation, Menthone oxime, Menthylamine, Platinum catalyst, Terpene, OXIDATION, NANOPARTICLES, REDUCTION, METAL, SELECTIVITY",
author = "Demidova, {Yu S.} and Mozhaitsev, {E. S.} and Munkuev, {A. A.} and Suslov, {E. V.} and Saraev, {A. A.} and Volcho, {K. P.} and Salakhutdinov, {N. F.} and Simakova, {I. L.} and Murzin, {D. Yu}",
note = "Publisher Copyright: {\textcopyright} 2020, Springer Science+Business Media, LLC, part of Springer Nature. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2020",
month = mar,
day = "1",
doi = "10.1007/s11244-020-01234-x",
language = "English",
volume = "63",
pages = "187--195",
journal = "Topics in Catalysis",
issn = "1022-5528",
publisher = "Springer Netherlands",
number = "1-2",

}

RIS

TY - JOUR

T1 - Monoterpenoid Oximes Hydrogenation Over Platinum Catalysts

AU - Demidova, Yu S.

AU - Mozhaitsev, E. S.

AU - Munkuev, A. A.

AU - Suslov, E. V.

AU - Saraev, A. A.

AU - Volcho, K. P.

AU - Salakhutdinov, N. F.

AU - Simakova, I. L.

AU - Murzin, D. Yu

N1 - Publisher Copyright: © 2020, Springer Science+Business Media, LLC, part of Springer Nature. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/3/1

Y1 - 2020/3/1

N2 - Platinum nanoparticles supported on MgO, Al2O3, ZrO2, TiO2 were utilized for monoterpenoid oximes hydrogenation. Monocyclic menthone and carvone oximes synthesized from bio-derived monoterpenoids with a different structure were used to explore the effect of substrate structure on the reaction regularities. The oximes hydrogenation was carried out under hydrogen atmosphere at 100 °C using methanol as a solvent. Platinum catalysts were prepared by the impregnation methods. The catalysts were characterized by transmission electron microscopy, X-ray photoelectron spectroscopy, X-ray fluorescence spectroscopy, nitrogen physisorption. Hydrogenation of carvone oxime containing a conjugated oxime group and several reducible functional groups resulted in both hydrogenation and deoximation giving 5-isopropyl-2-methylcyclohexanamine and carvomenthone over Pt/Al2O3 and Pt/ZrO2 catalysts. Menthone oxime hydrogenation over Pt/Al2O3 catalysts with an average particle size of 0.8 nm provided the desired menthylamine formation with the selectivity of 90% at complete oxime conversion. Platinum catalysts based on MgO, ZrO2 and TiO2 enhanced menthone oxime deoximation to menthone.

AB - Platinum nanoparticles supported on MgO, Al2O3, ZrO2, TiO2 were utilized for monoterpenoid oximes hydrogenation. Monocyclic menthone and carvone oximes synthesized from bio-derived monoterpenoids with a different structure were used to explore the effect of substrate structure on the reaction regularities. The oximes hydrogenation was carried out under hydrogen atmosphere at 100 °C using methanol as a solvent. Platinum catalysts were prepared by the impregnation methods. The catalysts were characterized by transmission electron microscopy, X-ray photoelectron spectroscopy, X-ray fluorescence spectroscopy, nitrogen physisorption. Hydrogenation of carvone oxime containing a conjugated oxime group and several reducible functional groups resulted in both hydrogenation and deoximation giving 5-isopropyl-2-methylcyclohexanamine and carvomenthone over Pt/Al2O3 and Pt/ZrO2 catalysts. Menthone oxime hydrogenation over Pt/Al2O3 catalysts with an average particle size of 0.8 nm provided the desired menthylamine formation with the selectivity of 90% at complete oxime conversion. Platinum catalysts based on MgO, ZrO2 and TiO2 enhanced menthone oxime deoximation to menthone.

KW - Carvone oxime

KW - Hydrogenation

KW - Menthone oxime

KW - Menthylamine

KW - Platinum catalyst

KW - Terpene

KW - OXIDATION

KW - NANOPARTICLES

KW - REDUCTION

KW - METAL

KW - SELECTIVITY

UR - http://www.scopus.com/inward/record.url?scp=85079452538&partnerID=8YFLogxK

U2 - 10.1007/s11244-020-01234-x

DO - 10.1007/s11244-020-01234-x

M3 - Article

AN - SCOPUS:85079452538

VL - 63

SP - 187

EP - 195

JO - Topics in Catalysis

JF - Topics in Catalysis

SN - 1022-5528

IS - 1-2

ER -

ID: 23523933