TY - JOUR

T1 - Monomers with a High Refraction Index Based on Acryloyl Derivatives of Spirocyclic Piperidin-4-One Thioacetals

AU - Basistyi, V. S.

AU - Bukhtoyarova, A. D.

AU - Vasil’ev, E. V.

AU - Shelkovnikov, V. V.

PY - 2018/7/1

Y1 - 2018/7/1

N2 - Dithioazaspiroheterocyclic derivatives are synthesized by condensing dithiols with piperidin-4-one in the presence of catalytic amounts of Lewis acids. Acrylic dithioazaspiroheterocyclic derivatives are obtained by the reaction with acryloyl chloride. The polymerization of monomers yields transparent polymer films of optical quality. The refractive indices for the synthesized monomers and polymers are in the range of n = 1.59–1.64.

AB - Dithioazaspiroheterocyclic derivatives are synthesized by condensing dithiols with piperidin-4-one in the presence of catalytic amounts of Lewis acids. Acrylic dithioazaspiroheterocyclic derivatives are obtained by the reaction with acryloyl chloride. The polymerization of monomers yields transparent polymer films of optical quality. The refractive indices for the synthesized monomers and polymers are in the range of n = 1.59–1.64.

UR - http://www.scopus.com/inward/record.url?scp=85052196520&partnerID=8YFLogxK

U2 - 10.1134/S0030400X18070044

DO - 10.1134/S0030400X18070044

M3 - Article

AN - SCOPUS:85052196520

VL - 125

SP - 82

EP - 87

JO - Optics and Spectroscopy (English translation of Optika i Spektroskopiya)

JF - Optics and Spectroscopy (English translation of Optika i Spektroskopiya)

SN - 0030-400X

IS - 1

ER -