Standard

Molecular hydrogen in minerals as a clue to interpret ∂D variations in the mantle. / Moine, B. N.; Bolfan-Casanova, N.; Radu, I. B. и др.

в: Nature Communications, Том 11, № 1, 3604, 17.07.2020.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Moine, BN, Bolfan-Casanova, N, Radu, IB, Ionov, DA, Costin, G, Korsakov, AV, Golovin, AV, Oleinikov, OB, Deloule, E & Cottin, JY 2020, 'Molecular hydrogen in minerals as a clue to interpret ∂D variations in the mantle', Nature Communications, Том. 11, № 1, 3604. https://doi.org/10.1038/s41467-020-17442-8

APA

Moine, B. N., Bolfan-Casanova, N., Radu, I. B., Ionov, D. A., Costin, G., Korsakov, A. V., Golovin, A. V., Oleinikov, O. B., Deloule, E., & Cottin, J. Y. (2020). Molecular hydrogen in minerals as a clue to interpret ∂D variations in the mantle. Nature Communications, 11(1), [3604]. https://doi.org/10.1038/s41467-020-17442-8

Vancouver

Moine BN, Bolfan-Casanova N, Radu IB, Ionov DA, Costin G, Korsakov AV и др. Molecular hydrogen in minerals as a clue to interpret ∂D variations in the mantle. Nature Communications. 2020 июль 17;11(1):3604. doi: 10.1038/s41467-020-17442-8

Author

Moine, B. N. ; Bolfan-Casanova, N. ; Radu, I. B. и др. / Molecular hydrogen in minerals as a clue to interpret ∂D variations in the mantle. в: Nature Communications. 2020 ; Том 11, № 1.

BibTeX

@article{856eaf3e7c8143ce8e507d5a1b74600c,
title = "Molecular hydrogen in minerals as a clue to interpret ∂D variations in the mantle",
abstract = "Trace amounts of water dissolved in minerals affect density, viscosity and melting behaviour of the Earth{\textquoteright}s mantle and play an important role in global tectonics, magmatism and volatile cycle. Water concentrations and the ratios of hydrogen isotopes in the mantle give insight into these processes, as well as into the origin of terrestrial water. Here we show the presence of molecular H2 in minerals (omphacites) from eclogites from the Kaapvaal and Siberian cratons. These omphacites contain both high amounts of H2 (70 to 460 wt. ppm) and OH. Furthermore, their ∂D values increase with dehydration, suggesting a positive H isotope fractionation factor between minerals and H2–bearing fluid, contrary to what is expected in case of isotopic exchange between minerals and H2O-fluids. The possibility of incorporation of large quantities of H as H2 in nominally anhydrous minerals implies that the storage capacity of H in the mantle may have been underestimated, and sheds new light on H isotope variations in mantle magmas and minerals.",
keywords = "ISOTOPE FRACTIONATION, LITHOSPHERIC MANTLE, OXYGEN FUGACITY, WATER-CONTENT, SILICATE MELTS, PERIDOTITE, DIFFUSION, OLIVINE, STATE, D/H",
author = "Moine, {B. N.} and N. Bolfan-Casanova and Radu, {I. B.} and Ionov, {D. A.} and G. Costin and Korsakov, {A. V.} and Golovin, {A. V.} and Oleinikov, {O. B.} and E. Deloule and Cottin, {J. Y.}",
year = "2020",
month = jul,
day = "17",
doi = "10.1038/s41467-020-17442-8",
language = "English",
volume = "11",
journal = "Nature Communications",
issn = "2041-1723",
publisher = "Nature Publishing Group",
number = "1",

}

RIS

TY - JOUR

T1 - Molecular hydrogen in minerals as a clue to interpret ∂D variations in the mantle

AU - Moine, B. N.

AU - Bolfan-Casanova, N.

AU - Radu, I. B.

AU - Ionov, D. A.

AU - Costin, G.

AU - Korsakov, A. V.

AU - Golovin, A. V.

AU - Oleinikov, O. B.

AU - Deloule, E.

AU - Cottin, J. Y.

PY - 2020/7/17

Y1 - 2020/7/17

N2 - Trace amounts of water dissolved in minerals affect density, viscosity and melting behaviour of the Earth’s mantle and play an important role in global tectonics, magmatism and volatile cycle. Water concentrations and the ratios of hydrogen isotopes in the mantle give insight into these processes, as well as into the origin of terrestrial water. Here we show the presence of molecular H2 in minerals (omphacites) from eclogites from the Kaapvaal and Siberian cratons. These omphacites contain both high amounts of H2 (70 to 460 wt. ppm) and OH. Furthermore, their ∂D values increase with dehydration, suggesting a positive H isotope fractionation factor between minerals and H2–bearing fluid, contrary to what is expected in case of isotopic exchange between minerals and H2O-fluids. The possibility of incorporation of large quantities of H as H2 in nominally anhydrous minerals implies that the storage capacity of H in the mantle may have been underestimated, and sheds new light on H isotope variations in mantle magmas and minerals.

AB - Trace amounts of water dissolved in minerals affect density, viscosity and melting behaviour of the Earth’s mantle and play an important role in global tectonics, magmatism and volatile cycle. Water concentrations and the ratios of hydrogen isotopes in the mantle give insight into these processes, as well as into the origin of terrestrial water. Here we show the presence of molecular H2 in minerals (omphacites) from eclogites from the Kaapvaal and Siberian cratons. These omphacites contain both high amounts of H2 (70 to 460 wt. ppm) and OH. Furthermore, their ∂D values increase with dehydration, suggesting a positive H isotope fractionation factor between minerals and H2–bearing fluid, contrary to what is expected in case of isotopic exchange between minerals and H2O-fluids. The possibility of incorporation of large quantities of H as H2 in nominally anhydrous minerals implies that the storage capacity of H in the mantle may have been underestimated, and sheds new light on H isotope variations in mantle magmas and minerals.

KW - ISOTOPE FRACTIONATION

KW - LITHOSPHERIC MANTLE

KW - OXYGEN FUGACITY

KW - WATER-CONTENT

KW - SILICATE MELTS

KW - PERIDOTITE

KW - DIFFUSION

KW - OLIVINE

KW - STATE

KW - D/H

UR - http://www.scopus.com/inward/record.url?scp=85088133618&partnerID=8YFLogxK

U2 - 10.1038/s41467-020-17442-8

DO - 10.1038/s41467-020-17442-8

M3 - Article

C2 - 32681113

AN - SCOPUS:85088133618

VL - 11

JO - Nature Communications

JF - Nature Communications

SN - 2041-1723

IS - 1

M1 - 3604

ER -

ID: 24785097