Magnetic Resonance Characteristics of Negative Polarons in Neat Poly(3-hexyl-thiophene)

Standard

Magnetic Resonance Characteristics of Negative Polarons in Neat Poly(3-hexyl-thiophene). / Borovkov, V. I.; Shchegoleva, L. N.

в: Journal of Physical Chemistry C, Том 123, № 46, 21.11.2019, стр. 28058-28065.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Borovkov, VI & Shchegoleva, LN 2019, 'Magnetic Resonance Characteristics of Negative Polarons in Neat Poly(3-hexyl-thiophene)', Journal of Physical Chemistry C, Том. 123, № 46, стр. 28058-28065. https://doi.org/10.1021/acs.jpcc.9b08331

APA

Borovkov, V. I., & Shchegoleva, L. N. (2019). Magnetic Resonance Characteristics of Negative Polarons in Neat Poly(3-hexyl-thiophene). Journal of Physical Chemistry C, 123(46), 28058-28065. https://doi.org/10.1021/acs.jpcc.9b08331

Vancouver

Borovkov VI, Shchegoleva LN. Magnetic Resonance Characteristics of Negative Polarons in Neat Poly(3-hexyl-thiophene). Journal of Physical Chemistry C. 2019 нояб. 21;123(46):28058-28065. doi: 10.1021/acs.jpcc.9b08331

Author

Borovkov, V. I. ; Shchegoleva, L. N. / Magnetic Resonance Characteristics of Negative Polarons in Neat Poly(3-hexyl-thiophene). в: Journal of Physical Chemistry C. 2019 ; Том 123, № 46. стр. 28058-28065.

BibTeX

@article{965d77644775423297efe66e4ca75de7,

title = "Magnetic Resonance Characteristics of Negative Polarons in Neat Poly(3-hexyl-thiophene)",

abstract = "Magnetic resonance characteristics of carriers of both electron spin and electric charge (polarons) in conjugated polymers are required for a deeper understanding of properties of these semiconducting materials. In poly(3-hexyl-thiophene), P3HT, which is an important material for photovoltaic applications, such information is available only for positive polarons, which are readily generated in the presence of electron acceptors via photoinduced processes. Influence of an external magnetic field on X-ray-induced delayed fluorescence from undoped P3HT and its solutions allowed us to visualize the spin interactions in the primary polaron pairs and to estimate the g-tensor components (g⊥ ≈ 2.0023, g|| ≈ 2.008) for the negative charge carriers in P3HT molecules. There is evidence that in neat regioregular P3HT, the g-tensor anisotropy for the polarons, migrating along polymer chains, is averaged partially because of irregularities in the polymer structure.",

keywords = "ELECTRON-SPIN-RESONANCE, MULTIFREQUENCY EPR, RADICAL CATIONS, POLY(3-HEXYLTHIOPHENE), ANISOTROPY, DYNAMICS, MOBILITY, POLYMER",

author = "Borovkov, {V. I.} and Shchegoleva, {L. N.}",

year = "2019",

month = nov,

day = "21",

doi = "10.1021/acs.jpcc.9b08331",

language = "English",

volume = "123",

pages = "28058--28065",

journal = "Journal of Physical Chemistry C",

issn = "1932-7447",

publisher = "American Chemical Society",

number = "46",

}

RIS

TY - JOUR

T1 - Magnetic Resonance Characteristics of Negative Polarons in Neat Poly(3-hexyl-thiophene)

AU - Borovkov, V. I.

AU - Shchegoleva, L. N.

PY - 2019/11/21

Y1 - 2019/11/21

N2 - Magnetic resonance characteristics of carriers of both electron spin and electric charge (polarons) in conjugated polymers are required for a deeper understanding of properties of these semiconducting materials. In poly(3-hexyl-thiophene), P3HT, which is an important material for photovoltaic applications, such information is available only for positive polarons, which are readily generated in the presence of electron acceptors via photoinduced processes. Influence of an external magnetic field on X-ray-induced delayed fluorescence from undoped P3HT and its solutions allowed us to visualize the spin interactions in the primary polaron pairs and to estimate the g-tensor components (g⊥ ≈ 2.0023, g|| ≈ 2.008) for the negative charge carriers in P3HT molecules. There is evidence that in neat regioregular P3HT, the g-tensor anisotropy for the polarons, migrating along polymer chains, is averaged partially because of irregularities in the polymer structure.

AB - Magnetic resonance characteristics of carriers of both electron spin and electric charge (polarons) in conjugated polymers are required for a deeper understanding of properties of these semiconducting materials. In poly(3-hexyl-thiophene), P3HT, which is an important material for photovoltaic applications, such information is available only for positive polarons, which are readily generated in the presence of electron acceptors via photoinduced processes. Influence of an external magnetic field on X-ray-induced delayed fluorescence from undoped P3HT and its solutions allowed us to visualize the spin interactions in the primary polaron pairs and to estimate the g-tensor components (g⊥ ≈ 2.0023, g|| ≈ 2.008) for the negative charge carriers in P3HT molecules. There is evidence that in neat regioregular P3HT, the g-tensor anisotropy for the polarons, migrating along polymer chains, is averaged partially because of irregularities in the polymer structure.

KW - ELECTRON-SPIN-RESONANCE

KW - MULTIFREQUENCY EPR

KW - RADICAL CATIONS

KW - POLY(3-HEXYLTHIOPHENE)

KW - ANISOTROPY

KW - DYNAMICS

KW - MOBILITY

KW - POLYMER

UR - http://www.scopus.com/inward/record.url?scp=85075048196&partnerID=8YFLogxK

U2 - 10.1021/acs.jpcc.9b08331

DO - 10.1021/acs.jpcc.9b08331

M3 - Article

AN - SCOPUS:85075048196

VL - 123

SP - 28058

EP - 28065

JO - Journal of Physical Chemistry C

JF - Journal of Physical Chemistry C

SN - 1932-7447

IS - 46

ER -

ID: 22336350