Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Luminescence of monoclinic Y2O3:Eu nanophosphor produced via laser vaporization. / Kostyukov, A. I.; Snytnikov, Vl N.; Ishchenko, A. V. и др.
в: Optical Materials, Том 104, 109843, 06.2020.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Luminescence of monoclinic Y2O3:Eu nanophosphor produced via laser vaporization
AU - Kostyukov, A. I.
AU - Snytnikov, Vl N.
AU - Ishchenko, A. V.
AU - Rakhmanova, M. I.
AU - Molokeev, M. S.
AU - Krylov, A. S.
AU - Aleksandrovsky, A. S.
PY - 2020/6
Y1 - 2020/6
N2 - Europium doped Y2O3spherical nanoparticles with the diameter ~10 nmobtained via cw laser vaporization are shown to crystallize in monoclinic symmetry class (C2/m space group). The size of nanoparticles established via HRTEM coincides with coherent scattering region established by XRD. Luminescence spectrum in the vicinity of ultranarrow transition demonstrates three peaks consistent with three inequivalent positions of Eu3+ ion in monoclinic Y2O3 lattice. Hypersensitive transition dominates in the spectrum, admitting the lack of inversion symmetry at Cs sites occupied by Eu3+. The spectrum of hypersensitive transition is expanded to the red part of spectrum due intense transitions terminating at higher-lying components of crystal-field-split 7F2 energy level. Obtaining chromaticity coordinates (0.669, 0.331)and absolute quantum yield (~21%) is possible using red phosphor based on monoclinic Y2O3:Eu3+.
AB - Europium doped Y2O3spherical nanoparticles with the diameter ~10 nmobtained via cw laser vaporization are shown to crystallize in monoclinic symmetry class (C2/m space group). The size of nanoparticles established via HRTEM coincides with coherent scattering region established by XRD. Luminescence spectrum in the vicinity of ultranarrow transition demonstrates three peaks consistent with three inequivalent positions of Eu3+ ion in monoclinic Y2O3 lattice. Hypersensitive transition dominates in the spectrum, admitting the lack of inversion symmetry at Cs sites occupied by Eu3+. The spectrum of hypersensitive transition is expanded to the red part of spectrum due intense transitions terminating at higher-lying components of crystal-field-split 7F2 energy level. Obtaining chromaticity coordinates (0.669, 0.331)and absolute quantum yield (~21%) is possible using red phosphor based on monoclinic Y2O3:Eu3+.
KW - Laser vaporization
KW - Monoclinic YO:Eu nanophosphor
KW - Photoluminescence of Eu
KW - PHOTOLUMINESCENCE
KW - SPECTROSCOPIC PROPERTIES
KW - Photoluminescence of Eu3+
KW - Monoclinic Y2O3:Eu nanophosphor
KW - EMISSION
UR - http://www.scopus.com/inward/record.url?scp=85082167837&partnerID=8YFLogxK
U2 - 10.1016/j.optmat.2020.109843
DO - 10.1016/j.optmat.2020.109843
M3 - Article
AN - SCOPUS:85082167837
VL - 104
JO - Optical Materials
JF - Optical Materials
SN - 0925-3467
M1 - 109843
ER -
ID: 23878864