Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Low-Temperature Steam Conversion of Natural Gas to Methane–Hydrogen Mixtures. / Potemkin, D. I.; Uskov, S. I.; Gorlova, A. M. и др.
в: Catalysis in Industry, Том 12, № 3, 01.07.2020, стр. 244-249.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Low-Temperature Steam Conversion of Natural Gas to Methane–Hydrogen Mixtures
AU - Potemkin, D. I.
AU - Uskov, S. I.
AU - Gorlova, A. M.
AU - Kirillov, V. A.
AU - Shigarov, A. B.
AU - Brayko, A. S.
AU - Rogozhnikov, V. N.
AU - Snytnikov, P. V.
AU - Pechenkin, A. A.
AU - Belyaev, V. D.
AU - Pimenov, A. A.
AU - Sobyanin, V. A.
PY - 2020/7/1
Y1 - 2020/7/1
N2 - A thermodynamic analysis is performed of the patterns of steam conversion of natural gas at temperatures of 300–600°C, pressures of 0.1–4 MPa and H2O : C molar ratios of 0.8‒1.2. Under these conditions, the reaction product is methane–hydrogen mixtures with hydrogen concentrations of 10–30 vol %. A rise in temperature, molar ratio Н2О : С, and a decrease in pressure contribute to an increase in the concentration of hydrogen in the reaction products. The thermodynamic boundaries of the process with no carbonization of the catalyst are determined. Experiments are performed to obtain methane–hydrogen mixtures from methane with an output concentration of 15–35 vol % hydrogen on industrial Ni-CrOx-Al2O3 catalyst at 325–425°C, a H2O : C molar ratio of 0.8–1.0, and atmospheric pressure. It is shown that under these conditions, the process proceeds without the formation of carbon on the catalyst.
AB - A thermodynamic analysis is performed of the patterns of steam conversion of natural gas at temperatures of 300–600°C, pressures of 0.1–4 MPa and H2O : C molar ratios of 0.8‒1.2. Under these conditions, the reaction product is methane–hydrogen mixtures with hydrogen concentrations of 10–30 vol %. A rise in temperature, molar ratio Н2О : С, and a decrease in pressure contribute to an increase in the concentration of hydrogen in the reaction products. The thermodynamic boundaries of the process with no carbonization of the catalyst are determined. Experiments are performed to obtain methane–hydrogen mixtures from methane with an output concentration of 15–35 vol % hydrogen on industrial Ni-CrOx-Al2O3 catalyst at 325–425°C, a H2O : C molar ratio of 0.8–1.0, and atmospheric pressure. It is shown that under these conditions, the process proceeds without the formation of carbon on the catalyst.
KW - hydrogen
KW - methane–hydrogen mixtures
KW - natural gas
KW - nickel catalyst
KW - steam reforming
KW - BIOHYTHANE PRODUCTION
KW - ANAEROBIC-DIGESTION
KW - methane-hydrogen mixtures
KW - FLARE GASES
KW - HYTHANE
KW - BIOMASS
KW - RICH GAS
KW - FERMENTATION
KW - CATALYSTS
UR - http://www.scopus.com/inward/record.url?scp=85091644687&partnerID=8YFLogxK
U2 - 10.1134/S2070050420030101
DO - 10.1134/S2070050420030101
M3 - Article
AN - SCOPUS:85091644687
VL - 12
SP - 244
EP - 249
JO - Catalysis in Industry
JF - Catalysis in Industry
SN - 2070-0504
IS - 3
ER -
ID: 25584960