TY - JOUR

T1 - Lithium carboxylate coordination polymers based on trimesic acid

AU - Koltunova, T. K.

AU - Samsonenko, D. G.

AU - Dybtsev, D. N.

AU - Fedin, V. P.

PY - 2017/9/1

Y1 - 2017/9/1

N2 - Three new metal-organic coordination polymers (H2NMe2)2[Li3(btc)(Hbtc)(DMF)4] (1), [Li5(DMF)6(btc)(Hbtc)]·2DMF (2), and [Li6(DMF)8(bdc)(Hbtc)] (3) (H3btc is trimesic acid, H2bdc is terephthalic acid) are prepared by heating LiOH with different aromatic carboxylic acids in dimethyl formamide (or its mixture with water). The crystal structures and composition of the compounds are determined by single crystal X-ray diffraction. Compound 1 has a layered structure; compounds 2 and 3 have a framework structure.

AB - Three new metal-organic coordination polymers (H2NMe2)2[Li3(btc)(Hbtc)(DMF)4] (1), [Li5(DMF)6(btc)(Hbtc)]·2DMF (2), and [Li6(DMF)8(bdc)(Hbtc)] (3) (H3btc is trimesic acid, H2bdc is terephthalic acid) are prepared by heating LiOH with different aromatic carboxylic acids in dimethyl formamide (or its mixture with water). The crystal structures and composition of the compounds are determined by single crystal X-ray diffraction. Compound 1 has a layered structure; compounds 2 and 3 have a framework structure.

KW - coordination polymers

KW - framework structures

KW - lithium(I) complexes

KW - single crystal X-ray diffraction analysis

KW - METAL-ORGANIC FRAMEWORKS

UR - http://www.scopus.com/inward/record.url?scp=85032281157&partnerID=8YFLogxK

U2 - 10.1134/S0022476617050274

DO - 10.1134/S0022476617050274

M3 - Article

AN - SCOPUS:85032281157

VL - 58

SP - 1048

EP - 1055

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 5

ER -