TY - JOUR

T1 - LBO Crystallization in the Li2O–B2O3–LiF System

AU - Khan, E. V.

AU - Kokh, K. A.

N1 - This study was funded by the State Assignment (project No. 122041400031-2) and by a grant of Russian Federation (project No. 25-23-20004) as far as crystal preparation and data interpreting. Khan, E. V. LBO Crystallization in the Li2O–B2O3–LiF System / E. V. Khan, K. A. Kokh // Journal of Structural Chemistry. – 2025. – Vol. 66, No. 9. – P. 1903-1907. – DOI 10.1134/S0022476625090124.

PY - 2025/10/9

Y1 - 2025/10/9

N2 - Abstract: Phase equilibria in the Li2O–B2O3–LiF ternary system are studied. It is established that the LBO primary crystallization region has a narrow concentration interval limited by Li3B7O12–LiF and Li2B8O18–LiF lines. The hydropyrolysis of LiF in air is studied. It is shown experimentally that the decomposition of LiF from the LiBO2–LiF melt at 800 °C is insignificant, but the LiF content decreases notably with time at 900 °C.

AB - Abstract: Phase equilibria in the Li2O–B2O3–LiF ternary system are studied. It is established that the LBO primary crystallization region has a narrow concentration interval limited by Li3B7O12–LiF and Li2B8O18–LiF lines. The hydropyrolysis of LiF in air is studied. It is shown experimentally that the decomposition of LiF from the LiBO2–LiF melt at 800 °C is insignificant, but the LiF content decreases notably with time at 900 °C.

KW - LiB3O5

KW - phase equilibria

KW - primary crystallization region

KW - triangulation

UR - https://www.mendeley.com/catalogue/6885335c-05ca-390c-8784-30940ea475df/

UR - https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=105018633116&origin=inward

UR - https://www.elibrary.ru/item.asp?id=83009107

U2 - 10.1134/S0022476625090124

DO - 10.1134/S0022476625090124

M3 - Article

VL - 66

SP - 1903

EP - 1907

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 9

ER -