Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Layered metal-organic coordination polymers based on Bi- and trinuclear cadmium blocks and octafluorobiphenyl-4,4′-dicarboxylate anions. / Cheplakova, A. M.; Gusarov, V. S.; Samsonenko, D. G. и др.
в: Journal of Structural Chemistry, Том 63, № 6, 06.2022, стр. 895-904.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Layered metal-organic coordination polymers based on Bi- and trinuclear cadmium blocks and octafluorobiphenyl-4,4′-dicarboxylate anions
AU - Cheplakova, A. M.
AU - Gusarov, V. S.
AU - Samsonenko, D. G.
AU - Vinogradov, A. S.
AU - Kovalenko, K. A.
AU - Rakhmanova, M. I.
AU - Fedin, V. P.
N1 - Funding Information: The work was supported by RFBR and the Government of the Novosibirsk Oblast within scientific project No. 20-43-540004 and The Ministry of Science and Higher Education of the Russian Federation (No. 121031700321-3). Publisher Copyright: © 2022, Pleiades Publishing, Ltd.
PY - 2022/6
Y1 - 2022/6
N2 - Two new layered metal-organic coordination polymers [Cd2(CH3CN)4(oFBPDC)2]·4CH3CN (1) and [Cd3((CH3)3СOH)4(oFBPDC)3]·3(CH3)3СOH·H2O (2), containing an octafluorobiphenyl-4,4′-dicarboxylic acid anion (oFBPDC2–) are obtained and characterized by the single crystal X-ray diffraction analysis. It is shown that on the long-term storage of 1 in air it transforms into another crystalline phase 1a. Solid 1a exhibits ultraviolet/blue photoluminescence caused by intraligand transitions.
AB - Two new layered metal-organic coordination polymers [Cd2(CH3CN)4(oFBPDC)2]·4CH3CN (1) and [Cd3((CH3)3СOH)4(oFBPDC)3]·3(CH3)3СOH·H2O (2), containing an octafluorobiphenyl-4,4′-dicarboxylic acid anion (oFBPDC2–) are obtained and characterized by the single crystal X-ray diffraction analysis. It is shown that on the long-term storage of 1 in air it transforms into another crystalline phase 1a. Solid 1a exhibits ultraviolet/blue photoluminescence caused by intraligand transitions.
KW - cadmium
KW - crystal structure
KW - metal-organic coordination polymers
KW - octafluorobiphenyl-4,4′-dicarboxylate
UR - http://www.scopus.com/inward/record.url?scp=85133124036&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/b202749a-20ce-389b-aa98-02f2e9fdc1ec/
U2 - 10.1134/S0022476622060063
DO - 10.1134/S0022476622060063
M3 - Article
AN - SCOPUS:85133124036
VL - 63
SP - 895
EP - 904
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 6
ER -
ID: 36511252