Standard

Kinetics of the Hydrodeoxygenation of Ethyl Ester of Decanoic Acid over the Ni–Cu–Mo/Al2O3 Catalyst. / Kukushkin, R. G.; Reshetnikov, S. I.; Zavarukhin, S. G. и др.

в: Catalysis in Industry, Том 11, № 3, 01.07.2019, стр. 191-197.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

Kukushkin, RG, Reshetnikov, SI, Zavarukhin, SG, Eletskii, PM & Yakovlev, VA 2019, 'Kinetics of the Hydrodeoxygenation of Ethyl Ester of Decanoic Acid over the Ni–Cu–Mo/Al2O3 Catalyst', Catalysis in Industry, Том. 11, № 3, стр. 191-197. https://doi.org/10.1134/S207005041903005X

APA

Kukushkin, R. G., Reshetnikov, S. I., Zavarukhin, S. G., Eletskii, P. M., & Yakovlev, V. A. (2019). Kinetics of the Hydrodeoxygenation of Ethyl Ester of Decanoic Acid over the Ni–Cu–Mo/Al2O3 Catalyst. Catalysis in Industry, 11(3), 191-197. https://doi.org/10.1134/S207005041903005X

Vancouver

Kukushkin RG, Reshetnikov SI, Zavarukhin SG, Eletskii PM, Yakovlev VA. Kinetics of the Hydrodeoxygenation of Ethyl Ester of Decanoic Acid over the Ni–Cu–Mo/Al2O3 Catalyst. Catalysis in Industry. 2019 июль 1;11(3):191-197. doi: 10.1134/S207005041903005X

Author

Kukushkin, R. G. ; Reshetnikov, S. I. ; Zavarukhin, S. G. и др. / Kinetics of the Hydrodeoxygenation of Ethyl Ester of Decanoic Acid over the Ni–Cu–Mo/Al2O3 Catalyst. в: Catalysis in Industry. 2019 ; Том 11, № 3. стр. 191-197.

BibTeX

@article{6afd9eab012d4ac99980c82cfe071d30,
title = "Kinetics of the Hydrodeoxygenation of Ethyl Ester of Decanoic Acid over the Ni–Cu–Mo/Al2O3 Catalyst",
abstract = "Abstract: The use of nickel-based catalysts in the hydrodeoxygenation of vegetable oils is an alternative to employing systems based on noble metals and sulfided hydrotreatment catalysts. Modifying nickel hydrodeoxygenation catalysts with molybdenum and copper increases the yield of target reaction products and the resistance of catalytic systems to the effect of an aggressive medium. The aim of this work is to determine the dependence between the temperature, contact time, and activity of modified nickel-containing catalyst in the hydrodeoxygenation of esters of fatty carboxylic acids and determine the effective kinetic parameters for the consumption of the reagent. The experiments are performed in a continuous flow reactor with a fixed catalyst bed at $${{P}_{{{{{\text{H}}}_{2}}}}}$$ = 0.25 MPa, temperatures of 270, 285, 300, and 315°C, and a contact time varying from 600 to 1800 s. The results show the selectivity toward the main reaction products (nonane and decane) remains the same when either the temperature of experiment or the contact time are varied. Experimental data are used to determine the effective rate constant and energy of activation of ester consumption.",
keywords = "biofuel, heterogeneous catalyst, hydrodeoxygenation, nickel-containing catalysts, BIOFUELS, AQUEOUS-PHASE HYDRODEOXYGENATION, NICKEL-CATALYSTS, ALIPHATIC ESTERS, MO, SULFIDED NIMO/GAMMA-AL2O3, BIO-OIL, NI",
author = "Kukushkin, {R. G.} and Reshetnikov, {S. I.} and Zavarukhin, {S. G.} and Eletskii, {P. M.} and Yakovlev, {V. A.}",
note = "Publisher Copyright: {\textcopyright} 2019, Pleiades Publishing, Ltd. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.",
year = "2019",
month = jul,
day = "1",
doi = "10.1134/S207005041903005X",
language = "English",
volume = "11",
pages = "191--197",
journal = "Catalysis in Industry",
issn = "2070-0504",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "3",

}

RIS

TY - JOUR

T1 - Kinetics of the Hydrodeoxygenation of Ethyl Ester of Decanoic Acid over the Ni–Cu–Mo/Al2O3 Catalyst

AU - Kukushkin, R. G.

AU - Reshetnikov, S. I.

AU - Zavarukhin, S. G.

AU - Eletskii, P. M.

AU - Yakovlev, V. A.

N1 - Publisher Copyright: © 2019, Pleiades Publishing, Ltd. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.

PY - 2019/7/1

Y1 - 2019/7/1

N2 - Abstract: The use of nickel-based catalysts in the hydrodeoxygenation of vegetable oils is an alternative to employing systems based on noble metals and sulfided hydrotreatment catalysts. Modifying nickel hydrodeoxygenation catalysts with molybdenum and copper increases the yield of target reaction products and the resistance of catalytic systems to the effect of an aggressive medium. The aim of this work is to determine the dependence between the temperature, contact time, and activity of modified nickel-containing catalyst in the hydrodeoxygenation of esters of fatty carboxylic acids and determine the effective kinetic parameters for the consumption of the reagent. The experiments are performed in a continuous flow reactor with a fixed catalyst bed at $${{P}_{{{{{\text{H}}}_{2}}}}}$$ = 0.25 MPa, temperatures of 270, 285, 300, and 315°C, and a contact time varying from 600 to 1800 s. The results show the selectivity toward the main reaction products (nonane and decane) remains the same when either the temperature of experiment or the contact time are varied. Experimental data are used to determine the effective rate constant and energy of activation of ester consumption.

AB - Abstract: The use of nickel-based catalysts in the hydrodeoxygenation of vegetable oils is an alternative to employing systems based on noble metals and sulfided hydrotreatment catalysts. Modifying nickel hydrodeoxygenation catalysts with molybdenum and copper increases the yield of target reaction products and the resistance of catalytic systems to the effect of an aggressive medium. The aim of this work is to determine the dependence between the temperature, contact time, and activity of modified nickel-containing catalyst in the hydrodeoxygenation of esters of fatty carboxylic acids and determine the effective kinetic parameters for the consumption of the reagent. The experiments are performed in a continuous flow reactor with a fixed catalyst bed at $${{P}_{{{{{\text{H}}}_{2}}}}}$$ = 0.25 MPa, temperatures of 270, 285, 300, and 315°C, and a contact time varying from 600 to 1800 s. The results show the selectivity toward the main reaction products (nonane and decane) remains the same when either the temperature of experiment or the contact time are varied. Experimental data are used to determine the effective rate constant and energy of activation of ester consumption.

KW - biofuel

KW - heterogeneous catalyst

KW - hydrodeoxygenation

KW - nickel-containing catalysts

KW - BIOFUELS

KW - AQUEOUS-PHASE HYDRODEOXYGENATION

KW - NICKEL-CATALYSTS

KW - ALIPHATIC ESTERS

KW - MO

KW - SULFIDED NIMO/GAMMA-AL2O3

KW - BIO-OIL

KW - NI

UR - http://www.scopus.com/inward/record.url?scp=85073261419&partnerID=8YFLogxK

U2 - 10.1134/S207005041903005X

DO - 10.1134/S207005041903005X

M3 - Article

AN - SCOPUS:85073261419

VL - 11

SP - 191

EP - 197

JO - Catalysis in Industry

JF - Catalysis in Industry

SN - 2070-0504

IS - 3

ER -

ID: 21861243