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Isomorphism and solid solutions among Ag- and Au-selenides. / Palyanova, Galina A.; Seryotkin, Yurii V.; Kokh, Konstantin A. и др.
в: Journal of Solid State Chemistry, Том 241, 01.09.2016, стр. 157-163.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Isomorphism and solid solutions among Ag- and Au-selenides
AU - Palyanova, Galina A.
AU - Seryotkin, Yurii V.
AU - Kokh, Konstantin A.
AU - Bakakin, Vladimir V.
PY - 2016/9/1
Y1 - 2016/9/1
N2 - Au-Ag selenides were synthesized by heating stoichiometric mixtures of elementary substances of initial compositions Ag2-xAuxSe with a step of x=0.25 (0≤x≤2) to 1050 °C and annealing at 500 °C. Scanning electron microscopy, optical microscopy, electron microprobe analysis and X-ray powder diffraction methods have been applied to study synthesized samples. Results of studies of synthesized products revealed the existence of three solid solutions with limited isomorphism Ag Au: naumannite Ag2Se - Ag1.94Au0.06Se, fischesserite Ag3AuSe2 - Ag3.2Au0.8Se2 and gold selenide AuSe - Au0.94Ag0.06Se. Solid solutions and AgAuSe phases were added to the phase diagram of Ag-Au-Se system. Crystal-chemical interpretation of Ag-Au isomorphism in selenides was made on the basis of structural features of fischesserite, naumannite, and AuSe.
AB - Au-Ag selenides were synthesized by heating stoichiometric mixtures of elementary substances of initial compositions Ag2-xAuxSe with a step of x=0.25 (0≤x≤2) to 1050 °C and annealing at 500 °C. Scanning electron microscopy, optical microscopy, electron microprobe analysis and X-ray powder diffraction methods have been applied to study synthesized samples. Results of studies of synthesized products revealed the existence of three solid solutions with limited isomorphism Ag Au: naumannite Ag2Se - Ag1.94Au0.06Se, fischesserite Ag3AuSe2 - Ag3.2Au0.8Se2 and gold selenide AuSe - Au0.94Ag0.06Se. Solid solutions and AgAuSe phases were added to the phase diagram of Ag-Au-Se system. Crystal-chemical interpretation of Ag-Au isomorphism in selenides was made on the basis of structural features of fischesserite, naumannite, and AuSe.
KW - Gold
KW - Isomorphism
KW - Silver
KW - Solid solutions (Ag,Au)Se
KW - Structure features
UR - http://www.scopus.com/inward/record.url?scp=84976315456&partnerID=8YFLogxK
U2 - 10.1016/j.jssc.2016.06.008
DO - 10.1016/j.jssc.2016.06.008
M3 - Article
AN - SCOPUS:84976315456
VL - 241
SP - 157
EP - 163
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
SN - 0022-4596
ER -
ID: 25753710