Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Interface properties of VOPc on Ni(111) and graphene/Ni(111) : Orientation-dependent charge transfer. / Adler, Hilmar; Paszkiewicz, Mateusz; Uihlein, Johannes и др.
в: Journal of Physical Chemistry C, Том 119, № 16, 23.04.2015, стр. 8755-8762.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Interface properties of VOPc on Ni(111) and graphene/Ni(111)
T2 - Orientation-dependent charge transfer
AU - Adler, Hilmar
AU - Paszkiewicz, Mateusz
AU - Uihlein, Johannes
AU - Polek, Małgorzata
AU - Ovsyannikov, Ruslan
AU - Basova, Tamara V.
AU - Chassé, Thomas
AU - Peisert, Heiko
PY - 2015/4/23
Y1 - 2015/4/23
N2 - Interface properties of VOPc films on Ni(111) and graphene/Ni(111) were investigated by X-ray photoemission spectroscopy (XPS), ultraviolet photoemission spectroscopy (UPS), and X-ray absorption spectroscopy (XAS). The XAS spectra reveal that the molecules grow highly ordered on both substrates, flat lying on the substrate surface. On Ni(111), strong interactions between vanadium ions of the VOPc molecules and the substrate were observed. It seems, however, that not all molecules of the first monolayer interact with the substrate. Scanning tunneling microscopy (STM) suggests that the strength of the interaction depends on the molecular orientation (oxygen-up or oxygen-down). The interaction can be completely prevented by graphene as an intermediate layer. Graphene affects not only the strength of the interaction at the interface, but also the energy level alignment.
AB - Interface properties of VOPc films on Ni(111) and graphene/Ni(111) were investigated by X-ray photoemission spectroscopy (XPS), ultraviolet photoemission spectroscopy (UPS), and X-ray absorption spectroscopy (XAS). The XAS spectra reveal that the molecules grow highly ordered on both substrates, flat lying on the substrate surface. On Ni(111), strong interactions between vanadium ions of the VOPc molecules and the substrate were observed. It seems, however, that not all molecules of the first monolayer interact with the substrate. Scanning tunneling microscopy (STM) suggests that the strength of the interaction depends on the molecular orientation (oxygen-up or oxygen-down). The interaction can be completely prevented by graphene as an intermediate layer. Graphene affects not only the strength of the interaction at the interface, but also the energy level alignment.
UR - http://www.scopus.com/inward/record.url?scp=84928577284&partnerID=8YFLogxK
U2 - 10.1021/acs.jpcc.5b01485
DO - 10.1021/acs.jpcc.5b01485
M3 - Article
AN - SCOPUS:84928577284
VL - 119
SP - 8755
EP - 8762
JO - Journal of Physical Chemistry C
JF - Journal of Physical Chemistry C
SN - 1932-7447
IS - 16
ER -
ID: 25436018