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Influence of content of pressure-transmitting medium on structural evolution of heulandite : Single-crystal X-ray diffraction study. / Seryotkin, Yurii V.
в: Microporous and Mesoporous Materials, Том 214, 28.05.2015, стр. 127-135.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Influence of content of pressure-transmitting medium on structural evolution of heulandite
T2 - Single-crystal X-ray diffraction study
AU - Seryotkin, Yurii V.
PY - 2015/5/28
Y1 - 2015/5/28
N2 - The structural evolution of natural heulandite Ca2.90Na2.07Sr0.25K0.16Ba0.06(H2O)n[Al8.65Si27.35O72] was studied upon compression in penetrating (water-containing) and non-penetrating (paraffin) media using single-crystal X-ray diffraction data in a diamond-anvil cell. Compression in a water-containing medium results in an additional hydration of heulandite from 23 molecules per unit cell at ambient conditions to ≈27 at 3.27 GPa. Water molecules enter both initially vacant and partly occupied positions. Additional hydration stabilizes the crystal structure decreasing its compressibility.
AB - The structural evolution of natural heulandite Ca2.90Na2.07Sr0.25K0.16Ba0.06(H2O)n[Al8.65Si27.35O72] was studied upon compression in penetrating (water-containing) and non-penetrating (paraffin) media using single-crystal X-ray diffraction data in a diamond-anvil cell. Compression in a water-containing medium results in an additional hydration of heulandite from 23 molecules per unit cell at ambient conditions to ≈27 at 3.27 GPa. Water molecules enter both initially vacant and partly occupied positions. Additional hydration stabilizes the crystal structure decreasing its compressibility.
KW - Crystal structure
KW - Heulandite
KW - High pressure
KW - Hydration
KW - Zeolite
UR - http://www.scopus.com/inward/record.url?scp=84930225678&partnerID=8YFLogxK
U2 - 10.1016/j.micromeso.2015.05.015
DO - 10.1016/j.micromeso.2015.05.015
M3 - Article
AN - SCOPUS:84930225678
VL - 214
SP - 127
EP - 135
JO - Microporous and Mesoporous Materials
JF - Microporous and Mesoporous Materials
SN - 1387-1811
ER -
ID: 25761719