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Influence of a synthesis method and a support nature on physicochemical and catalytic properties of supported rhodium catalysts for the partial oxidation of hydrocarbons. I. Chloride series. / Shefer, K. I.; Rogozhnikov, V. N.; Larina, T. V. и др.

в: Molecular Catalysis, Том 508, 111605, 05.2021.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Shefer, KI, Rogozhnikov, VN, Larina, TV, Kovtunova, LM, Stonkus, OA, Chetyrin, IA, Suprun, EA & Moroz, EM 2021, 'Influence of a synthesis method and a support nature on physicochemical and catalytic properties of supported rhodium catalysts for the partial oxidation of hydrocarbons. I. Chloride series', Molecular Catalysis, Том. 508, 111605. https://doi.org/10.1016/j.mcat.2021.111605

APA

Shefer, K. I., Rogozhnikov, V. N., Larina, T. V., Kovtunova, L. M., Stonkus, O. A., Chetyrin, I. A., Suprun, E. A., & Moroz, E. M. (2021). Influence of a synthesis method and a support nature on physicochemical and catalytic properties of supported rhodium catalysts for the partial oxidation of hydrocarbons. I. Chloride series. Molecular Catalysis, 508, [111605]. https://doi.org/10.1016/j.mcat.2021.111605

Vancouver

Shefer KI, Rogozhnikov VN, Larina TV, Kovtunova LM, Stonkus OA, Chetyrin IA и др. Influence of a synthesis method and a support nature on physicochemical and catalytic properties of supported rhodium catalysts for the partial oxidation of hydrocarbons. I. Chloride series. Molecular Catalysis. 2021 май;508:111605. doi: 10.1016/j.mcat.2021.111605

Author

Shefer, K. I. ; Rogozhnikov, V. N. ; Larina, T. V. и др. / Influence of a synthesis method and a support nature on physicochemical and catalytic properties of supported rhodium catalysts for the partial oxidation of hydrocarbons. I. Chloride series. в: Molecular Catalysis. 2021 ; Том 508.

BibTeX

@article{0f5e818423934601b8ce25850d15be2a,
title = "Influence of a synthesis method and a support nature on physicochemical and catalytic properties of supported rhodium catalysts for the partial oxidation of hydrocarbons. I. Chloride series",
abstract = "Rhodium catalysts supported on bayerite and pseudoboehmite alumina, calcined at 800 °С, were synthesized and tested in the partial oxidation of methane. Rhodium (III) chloride was used as an active component precursor. The supports and catalysts were investigated by a wide range of physicochemical methods: XRD, SEM and HR TEM, XPS and UV–vis DRS. In both cases, large rhodium particles with a coherent scattering region size of 15–19 nm are formed, and small ones with dimensions less than 1 nm. On the whole, smaller rhodium particles are formed on the bayerite oxide. The catalyst with pseudoboehmite-type support shows better results in the reaction.",
keywords = "Alumina, Catalyst characterization, Partial oxidation of hydrocarbons, Rhodium, Supported catalysts",
author = "Shefer, {K. I.} and Rogozhnikov, {V. N.} and Larina, {T. V.} and Kovtunova, {L. M.} and Stonkus, {O. A.} and Chetyrin, {I. A.} and Suprun, {E. A.} and Moroz, {E. M.}",
note = "Authors are grateful to Dr. A.A. Zhdanov for his assistance with elemental analysis. This work was supported by the Russian Foundation for Basic Research, project No. 190300595, and partially supported by the Ministry of Science and Higher Education of the Russian Federation within the governmental order for Boreskov Institute of Catalysis (project AAAA-A21-121011390053-4).",
year = "2021",
month = may,
doi = "10.1016/j.mcat.2021.111605",
language = "English",
volume = "508",
journal = "Molecular Catalysis",
issn = "2468-8231",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Influence of a synthesis method and a support nature on physicochemical and catalytic properties of supported rhodium catalysts for the partial oxidation of hydrocarbons. I. Chloride series

AU - Shefer, K. I.

AU - Rogozhnikov, V. N.

AU - Larina, T. V.

AU - Kovtunova, L. M.

AU - Stonkus, O. A.

AU - Chetyrin, I. A.

AU - Suprun, E. A.

AU - Moroz, E. M.

N1 - Authors are grateful to Dr. A.A. Zhdanov for his assistance with elemental analysis. This work was supported by the Russian Foundation for Basic Research, project No. 190300595, and partially supported by the Ministry of Science and Higher Education of the Russian Federation within the governmental order for Boreskov Institute of Catalysis (project AAAA-A21-121011390053-4).

PY - 2021/5

Y1 - 2021/5

N2 - Rhodium catalysts supported on bayerite and pseudoboehmite alumina, calcined at 800 °С, were synthesized and tested in the partial oxidation of methane. Rhodium (III) chloride was used as an active component precursor. The supports and catalysts were investigated by a wide range of physicochemical methods: XRD, SEM and HR TEM, XPS and UV–vis DRS. In both cases, large rhodium particles with a coherent scattering region size of 15–19 nm are formed, and small ones with dimensions less than 1 nm. On the whole, smaller rhodium particles are formed on the bayerite oxide. The catalyst with pseudoboehmite-type support shows better results in the reaction.

AB - Rhodium catalysts supported on bayerite and pseudoboehmite alumina, calcined at 800 °С, were synthesized and tested in the partial oxidation of methane. Rhodium (III) chloride was used as an active component precursor. The supports and catalysts were investigated by a wide range of physicochemical methods: XRD, SEM and HR TEM, XPS and UV–vis DRS. In both cases, large rhodium particles with a coherent scattering region size of 15–19 nm are formed, and small ones with dimensions less than 1 nm. On the whole, smaller rhodium particles are formed on the bayerite oxide. The catalyst with pseudoboehmite-type support shows better results in the reaction.

KW - Alumina

KW - Catalyst characterization

KW - Partial oxidation of hydrocarbons

KW - Rhodium

KW - Supported catalysts

UR - http://www.scopus.com/inward/record.url?scp=85105559272&partnerID=8YFLogxK

U2 - 10.1016/j.mcat.2021.111605

DO - 10.1016/j.mcat.2021.111605

M3 - Article

AN - SCOPUS:85105559272

VL - 508

JO - Molecular Catalysis

JF - Molecular Catalysis

SN - 2468-8231

M1 - 111605

ER -

ID: 28555011