Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Inelastic light scattering study of hydrogen-bonded glass formers : Glycerol and ethanol. / Zykova, V. A.; Surovtsev, N. V.
в: Journal of Non-Crystalline Solids, Том 471, 01.09.2017, стр. 429-434.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Inelastic light scattering study of hydrogen-bonded glass formers
T2 - Glycerol and ethanol
AU - Zykova, V. A.
AU - Surovtsev, N. V.
PY - 2017/9/1
Y1 - 2017/9/1
N2 - Temperature dependences of the structural relaxation time τα(T) of two hydrogen-bonded glass formers, glycerol and ethanol, were investigated by depolarized light scattering technique. τα(T) of glycerol demonstrates a transition from the Arrhenius law at high temperatures to a non-Arrhenius behavior at TA ~ 366 K. Combination of derivative analysis results for τα(T) from light scattering and dielectric spectroscopes reveals this transition near ~ 200 K in the case of ethanol. The obtained values of TA are close to the temperatures below which the excess of the Landau-Placzek ratio, associated with the appearance of locally favored structures, was observed earlier.
AB - Temperature dependences of the structural relaxation time τα(T) of two hydrogen-bonded glass formers, glycerol and ethanol, were investigated by depolarized light scattering technique. τα(T) of glycerol demonstrates a transition from the Arrhenius law at high temperatures to a non-Arrhenius behavior at TA ~ 366 K. Combination of derivative analysis results for τα(T) from light scattering and dielectric spectroscopes reveals this transition near ~ 200 K in the case of ethanol. The obtained values of TA are close to the temperatures below which the excess of the Landau-Placzek ratio, associated with the appearance of locally favored structures, was observed earlier.
KW - Alpha relaxation
KW - Fragile behavior
KW - Glass-forming liquids
KW - Raman scattering
KW - STRUCTURAL GLASS
KW - FORMING LIQUIDS
KW - ALPHA-RELAXATION
KW - VISCOSITY
KW - DIELECTRIC-SPECTROSCOPY
KW - HETEROGENEOUS DYNAMICS
KW - SUPERCOOLED LIQUIDS
KW - TRANSITION
KW - BETA-RELAXATION
KW - MONOHYDROXY ALCOHOLS
UR - http://www.scopus.com/inward/record.url?scp=85023615601&partnerID=8YFLogxK
U2 - 10.1016/j.jnoncrysol.2017.06.036
DO - 10.1016/j.jnoncrysol.2017.06.036
M3 - Article
AN - SCOPUS:85023615601
VL - 471
SP - 429
EP - 434
JO - Journal of Non-Crystalline Solids
JF - Journal of Non-Crystalline Solids
SN - 0022-3093
ER -
ID: 9981022