Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Hybrid film structures based on palladium layers and metal phthalocyanines. / Dorovskikh, Svetlana I.; Vikulova, Evgeniya S.; Nikolaeva, Natalia S. и др.
в: Science of Advanced Materials, Том 9, № 7, 07.2017, стр. 1087-1092.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Hybrid film structures based on palladium layers and metal phthalocyanines
AU - Dorovskikh, Svetlana I.
AU - Vikulova, Evgeniya S.
AU - Nikolaeva, Natalia S.
AU - Shushanyan, Artem D.
AU - Parkhomenko, Roman G.
AU - Morozova, Natalia B.
AU - Basova, Tamara V.
PY - 2017/7
Y1 - 2017/7
N2 - In this work, we demonstrate the application of a Metal-Organic Chemical Vapor Deposition (MOCVD) technique for deposition of the palladium electrodes on the surface of metal phthalocyanine films. It is expected that these hybrid multifunctional materials can be effective chemical sensors for hydrogen detection. Two palladium β-diketonate derivatives, palladium hexafluoroacetylacetonate Pd(hfac)2 and novel Pd(NMe2i-acac)2 were synthesized and characterized. Pd(NMe2i-acac)2 was shown to transfer to the gaseous phase with decomposition. Pd(hfac)2 was used as a precursor in MOCVD processes. The structure and morphology of Pd layers deposited both on Si(100) substrate and on the surface of metal phthalocyanine films were studied by means of XRD and scanning electron microscopy. The influence of the deposition of Pd as a top layer on the phase composition of metal phthalocyanine films was also discussed.
AB - In this work, we demonstrate the application of a Metal-Organic Chemical Vapor Deposition (MOCVD) technique for deposition of the palladium electrodes on the surface of metal phthalocyanine films. It is expected that these hybrid multifunctional materials can be effective chemical sensors for hydrogen detection. Two palladium β-diketonate derivatives, palladium hexafluoroacetylacetonate Pd(hfac)2 and novel Pd(NMe2i-acac)2 were synthesized and characterized. Pd(NMe2i-acac)2 was shown to transfer to the gaseous phase with decomposition. Pd(hfac)2 was used as a precursor in MOCVD processes. The structure and morphology of Pd layers deposited both on Si(100) substrate and on the surface of metal phthalocyanine films were studied by means of XRD and scanning electron microscopy. The influence of the deposition of Pd as a top layer on the phase composition of metal phthalocyanine films was also discussed.
KW - Chemical sensors
KW - Metal phthalocyanines
KW - MOCVD
KW - Palladium layers
KW - Thin films
KW - THIN-FILMS
KW - ENERGY
KW - CHEMICAL-VAPOR-DEPOSITION
KW - CRYSTAL-STRUCTURE
KW - HYDROGEN DETECTION
KW - COMPLEXES
KW - Chemical Sensors
KW - MEMBRANES
KW - Palladium Layers
KW - Metal Phthalocyanines
KW - GAS-SENSING PROPERTIES
KW - Thin Films
KW - MORPHOLOGY
UR - http://www.scopus.com/inward/record.url?scp=85019246935&partnerID=8YFLogxK
U2 - 10.1166/sam.2017.2794
DO - 10.1166/sam.2017.2794
M3 - Article
AN - SCOPUS:85019246935
VL - 9
SP - 1087
EP - 1092
JO - Science of Advanced Materials
JF - Science of Advanced Materials
SN - 1947-2935
IS - 7
ER -
ID: 10192720