Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Heteroleptic Binuclear Iodoacetate Copper(II) Complexes with 3-Bromopyridine and 4-Ethylpyridine : Crystal Structures and Peculiarities of Contacts Halogen···Halogen. / Adonin, S. A.; Novikov, A. S.; Fedin, V. P.
в: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 46, № 2, 01.02.2020, стр. 119-124.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Heteroleptic Binuclear Iodoacetate Copper(II) Complexes with 3-Bromopyridine and 4-Ethylpyridine
T2 - Crystal Structures and Peculiarities of Contacts Halogen···Halogen
AU - Adonin, S. A.
AU - Novikov, A. S.
AU - Fedin, V. P.
PY - 2020/2/1
Y1 - 2020/2/1
N2 - The reactions of [Cu2(IOAc)4(H2O)2] with 3-bromopyridine and 4-ethylpyridine in acetone afford heteroligand complexes [Cu2(IOAc)4(3-BrPy)2] (I) and [Cu2(IOAc)4(4-EtPy)2] (II). Their structures are determined by X-ray diffraction analysis (CIF files CCDC nos. 1945900 (I) and 1945901 (II)). Specific noncovalent interactions I···I and Br···I leading to the formation of supramolecular polymers are observed in the crystal structure of complex I. The energies of the contacts are determined using quantum chemical methods.
AB - The reactions of [Cu2(IOAc)4(H2O)2] with 3-bromopyridine and 4-ethylpyridine in acetone afford heteroligand complexes [Cu2(IOAc)4(3-BrPy)2] (I) and [Cu2(IOAc)4(4-EtPy)2] (II). Their structures are determined by X-ray diffraction analysis (CIF files CCDC nos. 1945900 (I) and 1945901 (II)). Specific noncovalent interactions I···I and Br···I leading to the formation of supramolecular polymers are observed in the crystal structure of complex I. The energies of the contacts are determined using quantum chemical methods.
KW - copper
KW - crystal structure
KW - halogen bond
KW - N-donor ligands
KW - quantum chemical calculations
KW - ANIONS
KW - HALIDES
KW - DIIODINE
KW - CU(II)
KW - CL
KW - NONCOVALENT INTERACTIONS
KW - HETEROMETALLIC COMPLEXES
KW - HYDROGEN
KW - METAL-IONS
KW - BOND
UR - http://www.scopus.com/inward/record.url?scp=85082064074&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/2e38f746-2fa7-3b85-8dd5-fd0b698512d6/
U2 - 10.1134/S1070328420020013
DO - 10.1134/S1070328420020013
M3 - Article
AN - SCOPUS:85082064074
VL - 46
SP - 119
EP - 124
JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
SN - 1070-3284
IS - 2
ER -
ID: 23875436