TY - JOUR

T1 - Halobismuthates with bis(pyridinium)alkane cations

T2 - Correlations in crystal structures and optical properties

AU - Adonin, Sergey A.

AU - Gorokh, Igor D.

AU - Samsonenko, Denis G.

AU - Antonova, Olga V.

AU - Korolkov, Ilya V.

AU - Sokolov, Maxim N.

AU - Fedin, Vladimir P.

N1 - Publisher Copyright: © 2017 Elsevier B.V.

PY - 2018/1/1

Y1 - 2018/1/1

N2 - A series of four chloro- and bromobismuthates with bis(pyridinium)alkane cations (Py(CH2)nPy)2+(Cn) and (4-PyH)(CH2)n(4-PyH)2+(H2Cn) were synthesized and characterized. Analysis of their crystal structures, as well as previously reported data, results in establishment of correlations between the type of halobismuthate anion and the nature of cation. Luminescent properties of obtained compounds are reported and discussed.

AB - A series of four chloro- and bromobismuthates with bis(pyridinium)alkane cations (Py(CH2)nPy)2+(Cn) and (4-PyH)(CH2)n(4-PyH)2+(H2Cn) were synthesized and characterized. Analysis of their crystal structures, as well as previously reported data, results in establishment of correlations between the type of halobismuthate anion and the nature of cation. Luminescent properties of obtained compounds are reported and discussed.

KW - Bismuth

KW - Crystal structure

KW - Halide complexes

KW - Halometalate

KW - Luminescence

KW - PHOTOCATALYTIC PROPERTIES

KW - PHASE-TRANSITIONS

KW - COMPLEXES

KW - BAND-GAP

KW - BISMUTH IODIDE

KW - BIDENTATE BASE SYSTEMS

KW - LIGHT-HARVESTING MATERIAL

KW - VIBRATIONAL PROPERTIES

KW - HYBRID

KW - VIOLOGEN

UR - http://www.scopus.com/inward/record.url?scp=85028931283&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2017.08.058

DO - 10.1016/j.ica.2017.08.058

M3 - Article

AN - SCOPUS:85028931283

VL - 469

SP - 32

EP - 37

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

ER -