Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Growth and crystal structure of Li3Ba4Sc3B8O22 borate and its Tb3+ doped green-emitting phosphor. / Kuznetsov, A. B.; Kokh, K. A.; Kononova, N. G. и др.
в: Journal of Luminescence, Том 217, 116755, 01.01.2020.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Growth and crystal structure of Li3Ba4Sc3B8O22 borate and its Tb3+ doped green-emitting phosphor
AU - Kuznetsov, A. B.
AU - Kokh, K. A.
AU - Kononova, N. G.
AU - Shevchenko, V. S.
AU - Rashchenko, S. V.
AU - Uralbekov, B.
AU - Svetlichnyi, V. A.
AU - Simonova, E. A.
AU - Kokh, A. E.
N1 - Funding Information: This work was supported by Russian Foundation for Basic Research (RFBR) project # 18-32-20001 , Russian Science Foundation project (RSF) project # 19-42-02003 in the part of structure refinement, project GF MES RK « New rare-earth borates: synthesis, crystal-chemical features, optical properties»(IRN AP05130794), and state assignment of IGM SB RAS. Publisher Copyright: © 2019 Elsevier B.V. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.
PY - 2020/1/1
Y1 - 2020/1/1
N2 - A new lithium barium scandium borate (Li3Ba4Sc3B8O22) was obtained by solid-state synthesis and grown by spontaneous crystallization. Single-crystal X-ray diffraction analysis showed that it crystallizes in the centrosymmetric space group P-1 with the cell dimensions a = 5.2230(4) Å, b = 8.5609(6) Å, c = 11.4157(8) Å, α = 73.3750(6)°, β = 78.5020(6)°, γ = 87.0520(6)°, and V = 479.28(6) Å3 and a structure that consists of two layers formed by single [BO3] and double [B2O5] triangles, [ScO6] octahedra, [BaO9] polyhedra, and disordered [LiO4] tetrahedra or squares. The diffuse optical reflection spectrum indicates that Li3Ba4Sc3B8O22 is transparent in the range of 250–800 nm. Furthermore, an effective green emission centred at 545 nm was observed for the as-prepared Tb3+-doped Li3Ba4Sc3B8O22, making this borate compound a promising host material for engineering light-emitting phosphors.
AB - A new lithium barium scandium borate (Li3Ba4Sc3B8O22) was obtained by solid-state synthesis and grown by spontaneous crystallization. Single-crystal X-ray diffraction analysis showed that it crystallizes in the centrosymmetric space group P-1 with the cell dimensions a = 5.2230(4) Å, b = 8.5609(6) Å, c = 11.4157(8) Å, α = 73.3750(6)°, β = 78.5020(6)°, γ = 87.0520(6)°, and V = 479.28(6) Å3 and a structure that consists of two layers formed by single [BO3] and double [B2O5] triangles, [ScO6] octahedra, [BaO9] polyhedra, and disordered [LiO4] tetrahedra or squares. The diffuse optical reflection spectrum indicates that Li3Ba4Sc3B8O22 is transparent in the range of 250–800 nm. Furthermore, an effective green emission centred at 545 nm was observed for the as-prepared Tb3+-doped Li3Ba4Sc3B8O22, making this borate compound a promising host material for engineering light-emitting phosphors.
KW - LUMINESCENCE PROPERTIES
KW - CE3+
UR - http://www.scopus.com/inward/record.url?scp=85072782007&partnerID=8YFLogxK
U2 - 10.1016/j.jlumin.2019.116755
DO - 10.1016/j.jlumin.2019.116755
M3 - Article
AN - SCOPUS:85072782007
VL - 217
JO - Journal of Luminescence
JF - Journal of Luminescence
SN - 0022-2313
M1 - 116755
ER -
ID: 21753770