Standard

Gas Hydrate and Corrosion Inhibition Performance of the Newly Synthesized Polyurethanes : Potential Dual Function Inhibitors. / Farhadian, Abdolreza; Varfolomeev, Mikhail A.; Rahimi, Alireza и др.

в: Energy and Fuels, Том 35, № 7, 01.04.2021, стр. 6113-6124.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

Farhadian, A, Varfolomeev, MA, Rahimi, A, Mendgaziev, RI, Semenov, AP, Stoporev, AS, Vinogradova, SS, Karwt, R & Kelland, MA 2021, 'Gas Hydrate and Corrosion Inhibition Performance of the Newly Synthesized Polyurethanes: Potential Dual Function Inhibitors', Energy and Fuels, Том. 35, № 7, стр. 6113-6124. https://doi.org/10.1021/acs.energyfuels.1c00101

APA

Farhadian, A., Varfolomeev, M. A., Rahimi, A., Mendgaziev, R. I., Semenov, A. P., Stoporev, A. S., Vinogradova, S. S., Karwt, R., & Kelland, M. A. (2021). Gas Hydrate and Corrosion Inhibition Performance of the Newly Synthesized Polyurethanes: Potential Dual Function Inhibitors. Energy and Fuels, 35(7), 6113-6124. https://doi.org/10.1021/acs.energyfuels.1c00101

Vancouver

Farhadian A, Varfolomeev MA, Rahimi A, Mendgaziev RI, Semenov AP, Stoporev AS и др. Gas Hydrate and Corrosion Inhibition Performance of the Newly Synthesized Polyurethanes: Potential Dual Function Inhibitors. Energy and Fuels. 2021 апр. 1;35(7):6113-6124. Epub 2021 март 22. doi: 10.1021/acs.energyfuels.1c00101

Author

Farhadian, Abdolreza ; Varfolomeev, Mikhail A. ; Rahimi, Alireza и др. / Gas Hydrate and Corrosion Inhibition Performance of the Newly Synthesized Polyurethanes : Potential Dual Function Inhibitors. в: Energy and Fuels. 2021 ; Том 35, № 7. стр. 6113-6124.

BibTeX

@article{bd493f0c0d2b4673bc582f502726c824,
title = "Gas Hydrate and Corrosion Inhibition Performance of the Newly Synthesized Polyurethanes: Potential Dual Function Inhibitors",
abstract = "Gas hydrate plugging and corrosion are two major flow assurance problems in oil and gas transmission pipelines. Since an incompatibility problem can occur during the simultaneous injection of gas hydrate and corrosion inhibitors, efficient dual function inhibitors would be an advantage. This study reports several newly synthesized waterborne polyurethanes (WPUs) that have a high potential as both corrosion inhibitors and gas hydrate kinetic ones. The length of the side substituents in different parts of the polymer and the ratio of polyethylene glycol (PEG) 400/1,2-butanediol were varied. The hydrate inhibition ability of WPUs was assessed using sapphire rocking cells (RCS6); weight loss, open circuit potential, and potentiodynamic polarization tests were employed to estimate their anti-corrosion activity. It was revealed that butyl derivatives (ethyl-butyl and methyl-butyl combinations) showed slightly better inhibition performance than commercial hydrate inhibitor poly(N-vinyl caprolactam) at 0.25 wt %, while partial replacement of PEG 400 with 1,2-butanediol reduced the inhibition activity. The gravimetric and electrochemical measurements confirmed that WPUs can suppress significantly the mild steel corrosion in both distilled and oilfield produced water saturated with CO2. Almost complete corrosion inhibition (96% and 98%) was achieved with 0.25 wt % of ethyl-butyl and methyl-butyl derivatives (without 1,2-butanediol), respectively. These findings indicate that WPUs can be considered as potential dual function reagents for inhibiting the gas hydrate formation and mild steel corrosion in CO2 saturated environments. ",
author = "Abdolreza Farhadian and Varfolomeev, {Mikhail A.} and Alireza Rahimi and Mendgaziev, {Rais I.} and Semenov, {Anton P.} and Stoporev, {Andrey S.} and Vinogradova, {Svetlana S.} and Rawdah Karwt and Kelland, {Malcolm A.}",
note = "Funding Information: The reported study was funded by RFBR and The Research Council of Norway according to the research project No. 20-55-20010. The work of A.P.S. and R.I.M. (rocking cells experiments) was supported by the State Assignment FSZE-2020-0007 (project 0768-2020-0007) in scientific activities in Gubkin University. The authors gratefully thank Roman S. Pavelyev (Kazan Federal University) for his help in analyzing the results. A.F. gives special thanks to the Vice-Presidency for Science and Technology of Iran for their support. Publisher Copyright: {\textcopyright} 2021 American Chemical Society. All rights reserved. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = apr,
day = "1",
doi = "10.1021/acs.energyfuels.1c00101",
language = "English",
volume = "35",
pages = "6113--6124",
journal = "Energy & Fuels",
issn = "0887-0624",
publisher = "American Chemical Society",
number = "7",

}

RIS

TY - JOUR

T1 - Gas Hydrate and Corrosion Inhibition Performance of the Newly Synthesized Polyurethanes

T2 - Potential Dual Function Inhibitors

AU - Farhadian, Abdolreza

AU - Varfolomeev, Mikhail A.

AU - Rahimi, Alireza

AU - Mendgaziev, Rais I.

AU - Semenov, Anton P.

AU - Stoporev, Andrey S.

AU - Vinogradova, Svetlana S.

AU - Karwt, Rawdah

AU - Kelland, Malcolm A.

N1 - Funding Information: The reported study was funded by RFBR and The Research Council of Norway according to the research project No. 20-55-20010. The work of A.P.S. and R.I.M. (rocking cells experiments) was supported by the State Assignment FSZE-2020-0007 (project 0768-2020-0007) in scientific activities in Gubkin University. The authors gratefully thank Roman S. Pavelyev (Kazan Federal University) for his help in analyzing the results. A.F. gives special thanks to the Vice-Presidency for Science and Technology of Iran for their support. Publisher Copyright: © 2021 American Chemical Society. All rights reserved. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/4/1

Y1 - 2021/4/1

N2 - Gas hydrate plugging and corrosion are two major flow assurance problems in oil and gas transmission pipelines. Since an incompatibility problem can occur during the simultaneous injection of gas hydrate and corrosion inhibitors, efficient dual function inhibitors would be an advantage. This study reports several newly synthesized waterborne polyurethanes (WPUs) that have a high potential as both corrosion inhibitors and gas hydrate kinetic ones. The length of the side substituents in different parts of the polymer and the ratio of polyethylene glycol (PEG) 400/1,2-butanediol were varied. The hydrate inhibition ability of WPUs was assessed using sapphire rocking cells (RCS6); weight loss, open circuit potential, and potentiodynamic polarization tests were employed to estimate their anti-corrosion activity. It was revealed that butyl derivatives (ethyl-butyl and methyl-butyl combinations) showed slightly better inhibition performance than commercial hydrate inhibitor poly(N-vinyl caprolactam) at 0.25 wt %, while partial replacement of PEG 400 with 1,2-butanediol reduced the inhibition activity. The gravimetric and electrochemical measurements confirmed that WPUs can suppress significantly the mild steel corrosion in both distilled and oilfield produced water saturated with CO2. Almost complete corrosion inhibition (96% and 98%) was achieved with 0.25 wt % of ethyl-butyl and methyl-butyl derivatives (without 1,2-butanediol), respectively. These findings indicate that WPUs can be considered as potential dual function reagents for inhibiting the gas hydrate formation and mild steel corrosion in CO2 saturated environments.

AB - Gas hydrate plugging and corrosion are two major flow assurance problems in oil and gas transmission pipelines. Since an incompatibility problem can occur during the simultaneous injection of gas hydrate and corrosion inhibitors, efficient dual function inhibitors would be an advantage. This study reports several newly synthesized waterborne polyurethanes (WPUs) that have a high potential as both corrosion inhibitors and gas hydrate kinetic ones. The length of the side substituents in different parts of the polymer and the ratio of polyethylene glycol (PEG) 400/1,2-butanediol were varied. The hydrate inhibition ability of WPUs was assessed using sapphire rocking cells (RCS6); weight loss, open circuit potential, and potentiodynamic polarization tests were employed to estimate their anti-corrosion activity. It was revealed that butyl derivatives (ethyl-butyl and methyl-butyl combinations) showed slightly better inhibition performance than commercial hydrate inhibitor poly(N-vinyl caprolactam) at 0.25 wt %, while partial replacement of PEG 400 with 1,2-butanediol reduced the inhibition activity. The gravimetric and electrochemical measurements confirmed that WPUs can suppress significantly the mild steel corrosion in both distilled and oilfield produced water saturated with CO2. Almost complete corrosion inhibition (96% and 98%) was achieved with 0.25 wt % of ethyl-butyl and methyl-butyl derivatives (without 1,2-butanediol), respectively. These findings indicate that WPUs can be considered as potential dual function reagents for inhibiting the gas hydrate formation and mild steel corrosion in CO2 saturated environments.

UR - http://www.scopus.com/inward/record.url?scp=85105016279&partnerID=8YFLogxK

U2 - 10.1021/acs.energyfuels.1c00101

DO - 10.1021/acs.energyfuels.1c00101

M3 - Article

AN - SCOPUS:85105016279

VL - 35

SP - 6113

EP - 6124

JO - Energy & Fuels

JF - Energy & Fuels

SN - 0887-0624

IS - 7

ER -

ID: 28496615