Functional borates and their high-pressure polymorphic modifications. Review

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Functional borates and their high-pressure polymorphic modifications. Review. / Bekker, Tatyana B.; Davydov, Aleksey V.; Sagatov, Nursultan E.

в: Condensed Matter and Interphases, Том 26, № 4, 15.10.2024, стр. 620-632.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{7f8ffc9eafdc40ecb1afaa918d2731bc,

title = "Functional borates and their high-pressure polymorphic modifications. Review",

abstract = "The article presents the results of many years of studies of the growth of a low-temperature modification of barium borate b-BaB2O4 (R3с) crystals in the Na, Ba, B // O, F quaternary reciprocal system. Barium borate b-BaB2O4 is the most important nonlinear optical crystal of the UV spectrum. The key factor determining the quality of crystals is the choice of an optimal solvent. The article presents phase diagrams and the results of the growth of b-BaB2O4 crystals in several subsystems of the studied quaternary reciprocal system. Using atomistic modeling, we predicted and then experimentally obtained new high-pressure modifications: g-BaB2O4 (P21/n), whose structure includes edge-sharing tetrahedra, and d-BaB2O4 with assumed symmetry Pa{\=3}. In our study, we also focused on a solid solution with an “antizeolite” structure, which also crystallizes in the Na, Ba, B // O, F system.",

keywords = "Borates with “antizeolite” structure, High-temperature solution growth, Low-temperature modification of barium metaborate, Quaternary reciprocal system",

author = "Bekker, {Tatyana B.} and Davydov, {Aleksey V.} and Sagatov, {Nursultan E.}",

year = "2024",

month = oct,

day = "15",

doi = "10.17308/kcmf.2024.26/12384",

language = "English",

volume = "26",

pages = "620--632",

journal = "Конденсированные среды и межфазные границы",

issn = "1606-867X",

publisher = "Издательство: Воронежский государственный университет",

number = "4",

}

RIS

TY - JOUR

T1 - Functional borates and their high-pressure polymorphic modifications. Review

AU - Bekker, Tatyana B.

AU - Davydov, Aleksey V.

AU - Sagatov, Nursultan E.

PY - 2024/10/15

Y1 - 2024/10/15

N2 - The article presents the results of many years of studies of the growth of a low-temperature modification of barium borate b-BaB2O4 (R3с) crystals in the Na, Ba, B // O, F quaternary reciprocal system. Barium borate b-BaB2O4 is the most important nonlinear optical crystal of the UV spectrum. The key factor determining the quality of crystals is the choice of an optimal solvent. The article presents phase diagrams and the results of the growth of b-BaB2O4 crystals in several subsystems of the studied quaternary reciprocal system. Using atomistic modeling, we predicted and then experimentally obtained new high-pressure modifications: g-BaB2O4 (P21/n), whose structure includes edge-sharing tetrahedra, and d-BaB2O4 with assumed symmetry Pa3̄. In our study, we also focused on a solid solution with an “antizeolite” structure, which also crystallizes in the Na, Ba, B // O, F system.

AB - The article presents the results of many years of studies of the growth of a low-temperature modification of barium borate b-BaB2O4 (R3с) crystals in the Na, Ba, B // O, F quaternary reciprocal system. Barium borate b-BaB2O4 is the most important nonlinear optical crystal of the UV spectrum. The key factor determining the quality of crystals is the choice of an optimal solvent. The article presents phase diagrams and the results of the growth of b-BaB2O4 crystals in several subsystems of the studied quaternary reciprocal system. Using atomistic modeling, we predicted and then experimentally obtained new high-pressure modifications: g-BaB2O4 (P21/n), whose structure includes edge-sharing tetrahedra, and d-BaB2O4 with assumed symmetry Pa3̄. In our study, we also focused on a solid solution with an “antizeolite” structure, which also crystallizes in the Na, Ba, B // O, F system.

KW - Borates with “antizeolite” structure

KW - High-temperature solution growth

KW - Low-temperature modification of barium metaborate

KW - Quaternary reciprocal system

UR - https://www.mendeley.com/catalogue/eea7f00e-7770-3ed4-9451-af91d6404d4b/

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85214647597&origin=inward&txGid=9c87bd6fdd0bec78f46b065bbc7aa836

U2 - 10.17308/kcmf.2024.26/12384

DO - 10.17308/kcmf.2024.26/12384

M3 - Article

VL - 26

SP - 620

EP - 632

JO - Конденсированные среды и межфазные границы

JF - Конденсированные среды и межфазные границы

SN - 1606-867X

IS - 4

ER -

ID: 62761836