TY - JOUR

T1 - Function composition of modified reduced graphite oxide

AU - Kobets, A. A.

AU - Lobiak, E. V.

AU - Krivyakin, G. K.

AU - Kallio, T.

AU - Fedorovskaya, E. O.

N1 - Funding Information: This work was financially support by the Grants Council of the President of the Russian Federation (grant MK 712.2019.3). The authors acknowledge resource center "VTAN" (Novosibirsk State University) for the access to experimental equipment. Publisher Copyright: © 2020 Elsevier Ltd Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/9/1

Y1 - 2020/9/1

N2 - Reduced graphite oxide (RGO) is prospective for application as an active material for supercapacitor electrodes due to the simple synthesis, the high specific surface area and the presence of oxygen-containing functional groups. Functionalization of such materials affects hydrophilicity, surface morphology and contributes to the redox processes when potential is applied. In this article RGO was treatment by mixture of potassium hydroxide and chloroacetic acid; hydrobromic acid and oxalic acid; in various ratio of strong nitric, sulfuric and phosphoric acids. Such functionalization of RGO leads to decrease in particle size, increase the quantity of oxygen-containing groups on the surface of the materials and affects the change of carbon hybridization from sp2 to sp3. Furthermore, all the samples were investigated by cyclic voltammetry (CV) to study the redox processes occurring on the electrode material surface. The peaks on the CV curves were compared with the corresponding redox reversible reactions. Furthermore, the specific capacity of all samples was calculated. Thus, at low carboxylation level of RGO specific capacity is increased due to significant contribution of redox processes while high functionalization leads to decrease in conductivity and, as well in specific capacity.

AB - Reduced graphite oxide (RGO) is prospective for application as an active material for supercapacitor electrodes due to the simple synthesis, the high specific surface area and the presence of oxygen-containing functional groups. Functionalization of such materials affects hydrophilicity, surface morphology and contributes to the redox processes when potential is applied. In this article RGO was treatment by mixture of potassium hydroxide and chloroacetic acid; hydrobromic acid and oxalic acid; in various ratio of strong nitric, sulfuric and phosphoric acids. Such functionalization of RGO leads to decrease in particle size, increase the quantity of oxygen-containing groups on the surface of the materials and affects the change of carbon hybridization from sp2 to sp3. Furthermore, all the samples were investigated by cyclic voltammetry (CV) to study the redox processes occurring on the electrode material surface. The peaks on the CV curves were compared with the corresponding redox reversible reactions. Furthermore, the specific capacity of all samples was calculated. Thus, at low carboxylation level of RGO specific capacity is increased due to significant contribution of redox processes while high functionalization leads to decrease in conductivity and, as well in specific capacity.

KW - Carboxylation

KW - Cyclic voltammetry

KW - Graphene material

KW - Oxygen-containing functional groups

KW - X-ray photoelectron spectroscopy

KW - STORAGE

KW - GRAPHENE OXIDE

KW - ELECTRODE MATERIALS

KW - CHEMICAL-REDUCTION

KW - PERFORMANCE

KW - NANOSHEETS

KW - CARBON NANOMATERIALS

KW - CAPACITANCE

KW - SPECTROSCOPY

KW - PRODUCE

UR - http://www.scopus.com/inward/record.url?scp=85087769765&partnerID=8YFLogxK

U2 - 10.1016/j.mtchem.2020.100311

DO - 10.1016/j.mtchem.2020.100311

M3 - Article

AN - SCOPUS:85087769765

VL - 17

JO - Materials Today Chemistry

JF - Materials Today Chemistry

SN - 2468-5194

M1 - 100311

ER -