Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Formation and decomposition of methane hydrate in pores of γ-Al2O3 и θ-Al2O3 : The dependence of water to hydrate transformation degree on pressure and temperature. / Smirnov, Vyacheslav G.; Manakov, Andrey Y.; Lyrshchikov, Sergey Yu и др.
в: Journal of Molecular Liquids, Том 328, 115486, 15.04.2021.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Formation and decomposition of methane hydrate in pores of γ-Al2O3 и θ-Al2O3
T2 - The dependence of water to hydrate transformation degree on pressure and temperature
AU - Smirnov, Vyacheslav G.
AU - Manakov, Andrey Y.
AU - Lyrshchikov, Sergey Yu
AU - Rodionova, Tatyana V.
AU - Dyrdin, Valeriy V.
AU - Ismagilov, Zinfer R.
N1 - Funding Information: This work was supported by the Russian Ministry of Science and Higher Education . The authors are grateful to Dr. E.S. Mikhaylova and Dr. Yu. S. Dudnikova for help in preparing the article. Some experiments were performed using equipment of Analytic Center of FCCCR SB RAS. Publisher Copyright: © 2021 Copyright: Copyright 2021 Elsevier B.V., All rights reserved.
PY - 2021/4/15
Y1 - 2021/4/15
N2 - The formation and decomposition of methane hydrate in the mesopores of two polymorphous modifications of Al2O3 and the state of water adsorbed in the mesopores were studied in the work. It is demonstrated that adsorbed water may have several energy states differing from each other in the degree of interaction with pore walls. Methane hydrate may be formed from different types of water present in the sample, and the amount of water transformed into hydrate depends on the conditions of hydrate formation. A conceptual model explaining the observations is proposed.
AB - The formation and decomposition of methane hydrate in the mesopores of two polymorphous modifications of Al2O3 and the state of water adsorbed in the mesopores were studied in the work. It is demonstrated that adsorbed water may have several energy states differing from each other in the degree of interaction with pore walls. Methane hydrate may be formed from different types of water present in the sample, and the amount of water transformed into hydrate depends on the conditions of hydrate formation. A conceptual model explaining the observations is proposed.
KW - Confined melting
KW - Gas hydrate
KW - Mesoporous materials
KW - Methane
UR - http://www.scopus.com/inward/record.url?scp=85100259961&partnerID=8YFLogxK
U2 - 10.1016/j.molliq.2021.115486
DO - 10.1016/j.molliq.2021.115486
M3 - Article
AN - SCOPUS:85100259961
VL - 328
JO - Journal of Molecular Liquids
JF - Journal of Molecular Liquids
SN - 0167-7322
M1 - 115486
ER -
ID: 27706533