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Fluorinated diaminobicyclooxacalixarene and diaminotetraoxacalixarenes: Synthesis and conformational behaviour. / Han, Huizhe; Kovtonyuk, Vladimir N.; Gatilov, Yurii V. и др.

в: Journal of Fluorine Chemistry, Том 273, 110235, 01.2024.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Han, H, Kovtonyuk, VN, Gatilov, YV, Andreev, RV & Nefedov, AA 2024, 'Fluorinated diaminobicyclooxacalixarene and diaminotetraoxacalixarenes: Synthesis and conformational behaviour', Journal of Fluorine Chemistry, Том. 273, 110235. https://doi.org/10.1016/j.jfluchem.2023.110235

APA

Han, H., Kovtonyuk, V. N., Gatilov, Y. V., Andreev, R. V., & Nefedov, A. A. (2024). Fluorinated diaminobicyclooxacalixarene and diaminotetraoxacalixarenes: Synthesis and conformational behaviour. Journal of Fluorine Chemistry, 273, [110235]. https://doi.org/10.1016/j.jfluchem.2023.110235

Vancouver

Han H, Kovtonyuk VN, Gatilov YV, Andreev RV, Nefedov AA. Fluorinated diaminobicyclooxacalixarene and diaminotetraoxacalixarenes: Synthesis and conformational behaviour. Journal of Fluorine Chemistry. 2024 янв.;273:110235. doi: 10.1016/j.jfluchem.2023.110235

Author

Han, Huizhe ; Kovtonyuk, Vladimir N. ; Gatilov, Yurii V. и др. / Fluorinated diaminobicyclooxacalixarene and diaminotetraoxacalixarenes: Synthesis and conformational behaviour. в: Journal of Fluorine Chemistry. 2024 ; Том 273.

BibTeX

@article{3b84149ed0a344f39f756cf1f1be1970,
title = "Fluorinated diaminobicyclooxacalixarene and diaminotetraoxacalixarenes: Synthesis and conformational behaviour",
abstract = "Polyfluorinated diaminotetraoxacalixarenes and diaminobicyclooxacalixarene were obtained in good yield by reduction of the corresponding dinitrooxacalixarenes with sodium dithionite. Fluorinated tetraoxacalix[4]arenes with nitro and amino groups located in the inner rim of the macrocycle exists in the solution as an equilibrium mixture of two conformers. For diaminotetraoxacalixarenes the conformational equilibrium is shifted towards conformers having a 1,3-alternate structure. The ESI-MS method shows the possibility of complexing fluorinated diaminotetraoxacalixarenes and diaminobicyclooxacalixarenes with metal cations.",
keywords = "Diaminobicycloxacalixarenes, Fluorinated diaminotetraoxacalixarenes, Orcinol, Conformational equilibrium, Pentafluoronitrobenzene, X-ray diffraction, Complexation",
author = "Huizhe Han and Kovtonyuk, {Vladimir N.} and Gatilov, {Yurii V.} and Andreev, {Rodion V.} and Nefedov, {Andrey A.}",
note = "The investigation was carried out with the financial support of the Ministry of Education and Science of Russia. Huizhe Han thanks the China Scholarship Council for financial support. Authors would like to acknowledge the Multi-Access Chemical Research Center SB RAS for spectral and analytical measurements. ",
year = "2024",
month = jan,
doi = "10.1016/j.jfluchem.2023.110235",
language = "English",
volume = "273",
journal = "Journal of Fluorine Chemistry",
issn = "0022-1139",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Fluorinated diaminobicyclooxacalixarene and diaminotetraoxacalixarenes: Synthesis and conformational behaviour

AU - Han, Huizhe

AU - Kovtonyuk, Vladimir N.

AU - Gatilov, Yurii V.

AU - Andreev, Rodion V.

AU - Nefedov, Andrey A.

N1 - The investigation was carried out with the financial support of the Ministry of Education and Science of Russia. Huizhe Han thanks the China Scholarship Council for financial support. Authors would like to acknowledge the Multi-Access Chemical Research Center SB RAS for spectral and analytical measurements.

PY - 2024/1

Y1 - 2024/1

N2 - Polyfluorinated diaminotetraoxacalixarenes and diaminobicyclooxacalixarene were obtained in good yield by reduction of the corresponding dinitrooxacalixarenes with sodium dithionite. Fluorinated tetraoxacalix[4]arenes with nitro and amino groups located in the inner rim of the macrocycle exists in the solution as an equilibrium mixture of two conformers. For diaminotetraoxacalixarenes the conformational equilibrium is shifted towards conformers having a 1,3-alternate structure. The ESI-MS method shows the possibility of complexing fluorinated diaminotetraoxacalixarenes and diaminobicyclooxacalixarenes with metal cations.

AB - Polyfluorinated diaminotetraoxacalixarenes and diaminobicyclooxacalixarene were obtained in good yield by reduction of the corresponding dinitrooxacalixarenes with sodium dithionite. Fluorinated tetraoxacalix[4]arenes with nitro and amino groups located in the inner rim of the macrocycle exists in the solution as an equilibrium mixture of two conformers. For diaminotetraoxacalixarenes the conformational equilibrium is shifted towards conformers having a 1,3-alternate structure. The ESI-MS method shows the possibility of complexing fluorinated diaminotetraoxacalixarenes and diaminobicyclooxacalixarenes with metal cations.

KW - Diaminobicycloxacalixarenes

KW - Fluorinated diaminotetraoxacalixarenes

KW - Orcinol, Conformational equilibrium

KW - Pentafluoronitrobenzene

KW - X-ray diffraction, Complexation

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85179407995&origin=inward&txGid=c589bca86217c5a45278df02052faca9

UR - https://www.mendeley.com/catalogue/69c4b1e8-cc32-35cf-9ed2-d3ae93736534/

U2 - 10.1016/j.jfluchem.2023.110235

DO - 10.1016/j.jfluchem.2023.110235

M3 - Article

VL - 273

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

SN - 0022-1139

M1 - 110235

ER -

ID: 60401890