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First examples of Co(II), Ni(II), and Cu(II) coordination compounds with 1-(pyrid-2-yl)-1H-tetrazole : Synthesis, structure and properties. / Ivanova, Alina D.; Grigoriev, Yury V.; Yu. Komarov, Vladislav и др.
в: Polyhedron, Том 189, 114750, 01.10.2020.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - First examples of Co(II), Ni(II), and Cu(II) coordination compounds with 1-(pyrid-2-yl)-1H-tetrazole
T2 - Synthesis, structure and properties
AU - Ivanova, Alina D.
AU - Grigoriev, Yury V.
AU - Yu. Komarov, Vladislav
AU - Sukhikh, Taisiya S.
AU - Bogomyakov, Artem S.
AU - Sheludyakova, Liliya A.
AU - Lavrenova, Ludmila G.
PY - 2020/10/1
Y1 - 2020/10/1
N2 - Coordination compounds of cobalt(II), nickel(II), and copper(II) with a poly nitrogen-containing heterocyclic ligand 1-(pyrid-2-yl)-1H-tetrazole (1-Pytz) such as [Cu(1-Pytz)2Cl2]n, [M(1-Pytz)2(H2O)Cl2] (M = Co, Ni), [M(1-Pytz)2(C2N3)2]n (M = Co, Ni) have been synthesized. The compounds have been studied by means of infrared diffuse reflectance spectroscopy, single-crystal and powder X-ray diffraction, and static magnetic susceptibility. The studies on the µeff(T) for the [Cu(1-Pytz)2Cl2]n, [Co(1-Pytz)2(C2N3)2]n and [Ni(1-Pytz)2(C2N3)2]n polynuclear complexes in the temperature range of 2–300 K have shown that exchange interactions between spins of metal ions are weak.
AB - Coordination compounds of cobalt(II), nickel(II), and copper(II) with a poly nitrogen-containing heterocyclic ligand 1-(pyrid-2-yl)-1H-tetrazole (1-Pytz) such as [Cu(1-Pytz)2Cl2]n, [M(1-Pytz)2(H2O)Cl2] (M = Co, Ni), [M(1-Pytz)2(C2N3)2]n (M = Co, Ni) have been synthesized. The compounds have been studied by means of infrared diffuse reflectance spectroscopy, single-crystal and powder X-ray diffraction, and static magnetic susceptibility. The studies on the µeff(T) for the [Cu(1-Pytz)2Cl2]n, [Co(1-Pytz)2(C2N3)2]n and [Ni(1-Pytz)2(C2N3)2]n polynuclear complexes in the temperature range of 2–300 K have shown that exchange interactions between spins of metal ions are weak.
KW - 1-(pyrid-2-yl)-1H-tetrazole
KW - 3d Metals
KW - Complex
KW - Magnetic properties
KW - X-ray structure
KW - POLYMERS
KW - NETWORK
KW - SERIES
KW - CRYSTAL-STRUCTURE
KW - COPPER(II)
KW - COMPLEXES
KW - PYRIDYL-TETRAZOLE LIGANDS
KW - FRAMEWORK
UR - http://www.scopus.com/inward/record.url?scp=85089811171&partnerID=8YFLogxK
U2 - 10.1016/j.poly.2020.114750
DO - 10.1016/j.poly.2020.114750
M3 - Article
AN - SCOPUS:85089811171
VL - 189
JO - Polyhedron
JF - Polyhedron
SN - 0277-5387
M1 - 114750
ER -
ID: 25300192