(Fe,Ni)2P allabogdanite can be an ambient pressure phase in iron meteorites

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(Fe,Ni)₂P allabogdanite can be an ambient pressure phase in iron meteorites. / Litasov, Konstantin D.; Bekker, Tatyana B.; Sagatov, Nursultan E. и др.

в: Scientific Reports, Том 10, № 1, 8956, 02.06.2020.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{6631425e85e741a9b8f2dd57f6f52977,

title = "(Fe,Ni)2P allabogdanite can be an ambient pressure phase in iron meteorites",

abstract = "An orthorhombic modification of (Fe,Ni)2P, allabogdanite, found in iron meteorites was considered to be thermodynamically stable at pressures above 8 GPa and temperatures of 1673 K according to the results of recent static high-pressure and high-temperature experiments. A hexagonal polymorphic modification of (Fe,Ni)2P, barringerite, was considered to be stable at ambient conditions. Experimental investigation through the solid-state synthesis supported by ab initio calculations was carried out to clarify the stability fields of (Fe,Ni)2P polymorphs. Both experimental and theoretical studies show that Fe2P-allabogdanite is a low-temperature phase stable at ambient conditions up to a temperature of at least 773 K and, therefore, is not necessarily associated with high pressures. This is consistent with the textural relationships of allabogdanite in iron meteorites.",

keywords = "PYROMETAMORPHIC ROCKS, NEUTRON-DIFFRACTION, MAGNETIC-PROPERTIES, HATRURIM FORMATION, CRYSTAL-STRUCTURE, ONELLO, FE2P, MOSSBAUER, PHOSPHIDE, DIAGRAM",

author = "Litasov, {Konstantin D.} and Bekker, {Tatyana B.} and Sagatov, {Nursultan E.} and Gavryushkin, {Pavel N.} and Krinitsyn, {Pavel G.} and Kuper, {Konstantin E.}",

note = "We thank two anonymous reviewers for valuable suggestions, which improved the quality of the manuscript. The work was supported by the Russian Science Foundation, grant No. 17-17-01177.",

year = "2020",

month = jun,

day = "2",

doi = "10.1038/s41598-020-66039-0",

language = "English",

volume = "10",

journal = "Scientific Reports",

issn = "2045-2322",

publisher = "Nature Publishing Group",

number = "1",

}

RIS

TY - JOUR

T1 - (Fe,Ni)2P allabogdanite can be an ambient pressure phase in iron meteorites

AU - Litasov, Konstantin D.

AU - Bekker, Tatyana B.

AU - Sagatov, Nursultan E.

AU - Gavryushkin, Pavel N.

AU - Krinitsyn, Pavel G.

AU - Kuper, Konstantin E.

N1 - We thank two anonymous reviewers for valuable suggestions, which improved the quality of the manuscript. The work was supported by the Russian Science Foundation, grant No. 17-17-01177.

PY - 2020/6/2

Y1 - 2020/6/2

N2 - An orthorhombic modification of (Fe,Ni)2P, allabogdanite, found in iron meteorites was considered to be thermodynamically stable at pressures above 8 GPa and temperatures of 1673 K according to the results of recent static high-pressure and high-temperature experiments. A hexagonal polymorphic modification of (Fe,Ni)2P, barringerite, was considered to be stable at ambient conditions. Experimental investigation through the solid-state synthesis supported by ab initio calculations was carried out to clarify the stability fields of (Fe,Ni)2P polymorphs. Both experimental and theoretical studies show that Fe2P-allabogdanite is a low-temperature phase stable at ambient conditions up to a temperature of at least 773 K and, therefore, is not necessarily associated with high pressures. This is consistent with the textural relationships of allabogdanite in iron meteorites.

AB - An orthorhombic modification of (Fe,Ni)2P, allabogdanite, found in iron meteorites was considered to be thermodynamically stable at pressures above 8 GPa and temperatures of 1673 K according to the results of recent static high-pressure and high-temperature experiments. A hexagonal polymorphic modification of (Fe,Ni)2P, barringerite, was considered to be stable at ambient conditions. Experimental investigation through the solid-state synthesis supported by ab initio calculations was carried out to clarify the stability fields of (Fe,Ni)2P polymorphs. Both experimental and theoretical studies show that Fe2P-allabogdanite is a low-temperature phase stable at ambient conditions up to a temperature of at least 773 K and, therefore, is not necessarily associated with high pressures. This is consistent with the textural relationships of allabogdanite in iron meteorites.

KW - PYROMETAMORPHIC ROCKS

KW - NEUTRON-DIFFRACTION

KW - MAGNETIC-PROPERTIES

KW - HATRURIM FORMATION

KW - CRYSTAL-STRUCTURE

KW - ONELLO

KW - FE2P

KW - MOSSBAUER

KW - PHOSPHIDE

KW - DIAGRAM

UR - http://www.scopus.com/inward/record.url?scp=85085908505&partnerID=8YFLogxK

U2 - 10.1038/s41598-020-66039-0

DO - 10.1038/s41598-020-66039-0

M3 - Article

C2 - 32488079

AN - SCOPUS:85085908505

VL - 10

JO - Scientific Reports

JF - Scientific Reports

SN - 2045-2322

IS - 1

M1 - 8956

ER -

ID: 24457150