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Facile Synthesis of 3-(Azol-1-yl)-1-adamantanecarboxylic Acids—New Bifunctional Angle-Shaped Building Blocks for Coordination Polymers. / Pavlov, Dmitry; Sukhikh, Taisiya; Filatov, Evgeny и др.

в: Molecules, Том 24, № 15, 2717, 26.07.2019.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Pavlov, D, Sukhikh, T, Filatov, E & Potapov, A 2019, 'Facile Synthesis of 3-(Azol-1-yl)-1-adamantanecarboxylic Acids—New Bifunctional Angle-Shaped Building Blocks for Coordination Polymers', Molecules, Том. 24, № 15, 2717. https://doi.org/10.3390/molecules24152717

APA

Pavlov, D., Sukhikh, T., Filatov, E., & Potapov, A. (2019). Facile Synthesis of 3-(Azol-1-yl)-1-adamantanecarboxylic Acids—New Bifunctional Angle-Shaped Building Blocks for Coordination Polymers. Molecules, 24(15), [2717]. https://doi.org/10.3390/molecules24152717

Vancouver

Pavlov D, Sukhikh T, Filatov E, Potapov A. Facile Synthesis of 3-(Azol-1-yl)-1-adamantanecarboxylic Acids—New Bifunctional Angle-Shaped Building Blocks for Coordination Polymers. Molecules. 2019 июль 26;24(15):2717. doi: 10.3390/molecules24152717

Author

Pavlov, Dmitry ; Sukhikh, Taisiya ; Filatov, Evgeny и др. / Facile Synthesis of 3-(Azol-1-yl)-1-adamantanecarboxylic Acids—New Bifunctional Angle-Shaped Building Blocks for Coordination Polymers. в: Molecules. 2019 ; Том 24, № 15.

BibTeX

@article{e562232490c54677ba09a606480193ce,
title = "Facile Synthesis of 3-(Azol-1-yl)-1-adamantanecarboxylic Acids—New Bifunctional Angle-Shaped Building Blocks for Coordination Polymers",
abstract = "For the first time, orthogonally substituted azole-carboxylate adamantane ligands were synthesized and used for preparation of coordination polymers. The angle-shaped ligands were prepared by the reaction of 1-adamantanecarboxylic acid and azoles (1H-1,2,4-triazole, 3-methyl-1H-1,2,4-triazole, 3,5-dimethyl-1H-1,2,4-triazole, 1H-tetrazole, 5-methyl-1H-tetrazole) in concentrated sulfuric acid. Variation of the solvent and substituents in azole rings allowed to prepare both 1D and 2D copper(II) and nickel(II) coordination polymers, [Cu2(trzadc)4(H2O)0.7]·DMF·0.3H2O, [Cu(trzadc)2(MeOH)]·MeOH, [Ni(trzadc)2(MeOH)2] and [Cu2(mtrzadc)3(MeOH)]+NO3 – (trzadc-3-(1,2,4-triazol-1-yl)-adamantane-1-carboxylic acid; mtrzadc-3-(3-methyl-1,2,4-triazol-1-yl)-adamantane-1-carboxylic acid) which were structurally characterized by single crystal X-ray diffraction. Complex [Cu(trzadc)2(MeOH)]·MeOH was shown to act as a catalyst in the Chan-Evans-Lam arylation reaction.",
keywords = "Adamantane, Carboxylate ligands, Chain structures, Heterocyclic ligands, Metal-organic frameworks, DESIGN, CRYSTAL-STRUCTURE, COMPLEXES, ADAMANTANEDICARBOXYLATE, metal-organic frameworks, CATALYZED ADAMANTYLATION, adamantane, TECTONS, carboxylate ligands, heterocyclic ligands, chain structures, DIVERSITY, ADAMANTANE",
author = "Dmitry Pavlov and Taisiya Sukhikh and Evgeny Filatov and Andrei Potapov",
year = "2019",
month = jul,
day = "26",
doi = "10.3390/molecules24152717",
language = "English",
volume = "24",
journal = "Molecules",
issn = "1420-3049",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "15",

}

RIS

TY - JOUR

T1 - Facile Synthesis of 3-(Azol-1-yl)-1-adamantanecarboxylic Acids—New Bifunctional Angle-Shaped Building Blocks for Coordination Polymers

AU - Pavlov, Dmitry

AU - Sukhikh, Taisiya

AU - Filatov, Evgeny

AU - Potapov, Andrei

PY - 2019/7/26

Y1 - 2019/7/26

N2 - For the first time, orthogonally substituted azole-carboxylate adamantane ligands were synthesized and used for preparation of coordination polymers. The angle-shaped ligands were prepared by the reaction of 1-adamantanecarboxylic acid and azoles (1H-1,2,4-triazole, 3-methyl-1H-1,2,4-triazole, 3,5-dimethyl-1H-1,2,4-triazole, 1H-tetrazole, 5-methyl-1H-tetrazole) in concentrated sulfuric acid. Variation of the solvent and substituents in azole rings allowed to prepare both 1D and 2D copper(II) and nickel(II) coordination polymers, [Cu2(trzadc)4(H2O)0.7]·DMF·0.3H2O, [Cu(trzadc)2(MeOH)]·MeOH, [Ni(trzadc)2(MeOH)2] and [Cu2(mtrzadc)3(MeOH)]+NO3 – (trzadc-3-(1,2,4-triazol-1-yl)-adamantane-1-carboxylic acid; mtrzadc-3-(3-methyl-1,2,4-triazol-1-yl)-adamantane-1-carboxylic acid) which were structurally characterized by single crystal X-ray diffraction. Complex [Cu(trzadc)2(MeOH)]·MeOH was shown to act as a catalyst in the Chan-Evans-Lam arylation reaction.

AB - For the first time, orthogonally substituted azole-carboxylate adamantane ligands were synthesized and used for preparation of coordination polymers. The angle-shaped ligands were prepared by the reaction of 1-adamantanecarboxylic acid and azoles (1H-1,2,4-triazole, 3-methyl-1H-1,2,4-triazole, 3,5-dimethyl-1H-1,2,4-triazole, 1H-tetrazole, 5-methyl-1H-tetrazole) in concentrated sulfuric acid. Variation of the solvent and substituents in azole rings allowed to prepare both 1D and 2D copper(II) and nickel(II) coordination polymers, [Cu2(trzadc)4(H2O)0.7]·DMF·0.3H2O, [Cu(trzadc)2(MeOH)]·MeOH, [Ni(trzadc)2(MeOH)2] and [Cu2(mtrzadc)3(MeOH)]+NO3 – (trzadc-3-(1,2,4-triazol-1-yl)-adamantane-1-carboxylic acid; mtrzadc-3-(3-methyl-1,2,4-triazol-1-yl)-adamantane-1-carboxylic acid) which were structurally characterized by single crystal X-ray diffraction. Complex [Cu(trzadc)2(MeOH)]·MeOH was shown to act as a catalyst in the Chan-Evans-Lam arylation reaction.

KW - Adamantane

KW - Carboxylate ligands

KW - Chain structures

KW - Heterocyclic ligands

KW - Metal-organic frameworks

KW - DESIGN

KW - CRYSTAL-STRUCTURE

KW - COMPLEXES

KW - ADAMANTANEDICARBOXYLATE

KW - metal-organic frameworks

KW - CATALYZED ADAMANTYLATION

KW - adamantane

KW - TECTONS

KW - carboxylate ligands

KW - heterocyclic ligands

KW - chain structures

KW - DIVERSITY

KW - ADAMANTANE

UR - http://www.scopus.com/inward/record.url?scp=85070107811&partnerID=8YFLogxK

U2 - 10.3390/molecules24152717

DO - 10.3390/molecules24152717

M3 - Article

C2 - 31357420

AN - SCOPUS:85070107811

VL - 24

JO - Molecules

JF - Molecules

SN - 1420-3049

IS - 15

M1 - 2717

ER -

ID: 21144724