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Exploration of structural, thermal, vibrational and spectroscopic properties of new noncentrosymmetric double borate Rb3NdB6O12. / Atuchin, V. V.; Subanakov, A. K.; Aleksandrovsky, A. S. и др.

в: Advanced Powder Technology, Том 28, № 5, 01.05.2017, стр. 1309-1315.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Atuchin, VV, Subanakov, AK, Aleksandrovsky, AS, Bazarov, BG, Bazarova, JG, Dorzhieva, SG, Gavrilova, TA, Krylov, AS, Molokeev, MS, Oreshonkov, AS, Pugachev, AM, Tushinova, YL & Yelisseyev, AP 2017, 'Exploration of structural, thermal, vibrational and spectroscopic properties of new noncentrosymmetric double borate Rb3NdB6O12', Advanced Powder Technology, Том. 28, № 5, стр. 1309-1315. https://doi.org/10.1016/j.apt.2017.02.019

APA

Atuchin, V. V., Subanakov, A. K., Aleksandrovsky, A. S., Bazarov, B. G., Bazarova, J. G., Dorzhieva, S. G., Gavrilova, T. A., Krylov, A. S., Molokeev, M. S., Oreshonkov, A. S., Pugachev, A. M., Tushinova, Y. L., & Yelisseyev, A. P. (2017). Exploration of structural, thermal, vibrational and spectroscopic properties of new noncentrosymmetric double borate Rb3NdB6O12. Advanced Powder Technology, 28(5), 1309-1315. https://doi.org/10.1016/j.apt.2017.02.019

Vancouver

Atuchin VV, Subanakov AK, Aleksandrovsky AS, Bazarov BG, Bazarova JG, Dorzhieva SG и др. Exploration of structural, thermal, vibrational and spectroscopic properties of new noncentrosymmetric double borate Rb3NdB6O12. Advanced Powder Technology. 2017 май 1;28(5):1309-1315. doi: 10.1016/j.apt.2017.02.019

Author

Atuchin, V. V. ; Subanakov, A. K. ; Aleksandrovsky, A. S. и др. / Exploration of structural, thermal, vibrational and spectroscopic properties of new noncentrosymmetric double borate Rb3NdB6O12. в: Advanced Powder Technology. 2017 ; Том 28, № 5. стр. 1309-1315.

BibTeX

@article{e5a430e145b74b2ea1065df7010ed07f,
title = "Exploration of structural, thermal, vibrational and spectroscopic properties of new noncentrosymmetric double borate Rb3NdB6O12",
abstract = "New noncentrosymmetric rare earth borate Rb3NdB6O12 is found in the ternary system Rb2O–Nd2O3–B2O3. The Rb3NdB6O12 powder was fabricated by solid state synthesis at 1050 K for 72 h and the crystal structure was obtained by the Rietveld method. Rb3NdB6O12 crystallized in space group R32 with unit cell parameters a = 13.5236(4), c = 31.162(1) {\AA}, Z = 3. From DSC measurements, the reversible phase transition (I type) in Rb3NdB6O12 is observed at 852–936 K. The 200 μm thick tablet is transparent over the spectral range of 0.3–6.5 μm and the band gap is found as Eg ∼ 6.29 eV. Nonlinear optical response of Rb3NdB6O12 tested via SHG is estimated to be higher than that of K3YB6O12. Blue shift of Nd luminescent lines is found in comparison with other borates. The vibrational parameters of Rb3NdB6O12 are evaluated by experimental methods.",
keywords = "DSC, Raman scattering, Rietveld refinement, Rubidium neodymium borate, Solid state reaction, NONLINEAR-OPTICAL CRYSTAL, LUMINESCENCE, RAMAN-SPECTROSCOPY, GROWTH, ORTHOBORATE, NA3LA9O3(BO3)(8), ELECTRONIC-STRUCTURE",
author = "Atuchin, {V. V.} and Subanakov, {A. K.} and Aleksandrovsky, {A. S.} and Bazarov, {B. G.} and Bazarova, {J. G.} and Dorzhieva, {S. G.} and Gavrilova, {T. A.} and Krylov, {A. S.} and Molokeev, {M. S.} and Oreshonkov, {A. S.} and Pugachev, {A. M.} and Tushinova, {Yu L.} and Yelisseyev, {A. P.}",
year = "2017",
month = may,
day = "1",
doi = "10.1016/j.apt.2017.02.019",
language = "English",
volume = "28",
pages = "1309--1315",
journal = "Advanced Powder Technology",
issn = "0921-8831",
publisher = "Elsevier",
number = "5",

}

RIS

TY - JOUR

T1 - Exploration of structural, thermal, vibrational and spectroscopic properties of new noncentrosymmetric double borate Rb3NdB6O12

AU - Atuchin, V. V.

AU - Subanakov, A. K.

AU - Aleksandrovsky, A. S.

AU - Bazarov, B. G.

AU - Bazarova, J. G.

AU - Dorzhieva, S. G.

AU - Gavrilova, T. A.

AU - Krylov, A. S.

AU - Molokeev, M. S.

AU - Oreshonkov, A. S.

AU - Pugachev, A. M.

AU - Tushinova, Yu L.

AU - Yelisseyev, A. P.

PY - 2017/5/1

Y1 - 2017/5/1

N2 - New noncentrosymmetric rare earth borate Rb3NdB6O12 is found in the ternary system Rb2O–Nd2O3–B2O3. The Rb3NdB6O12 powder was fabricated by solid state synthesis at 1050 K for 72 h and the crystal structure was obtained by the Rietveld method. Rb3NdB6O12 crystallized in space group R32 with unit cell parameters a = 13.5236(4), c = 31.162(1) Å, Z = 3. From DSC measurements, the reversible phase transition (I type) in Rb3NdB6O12 is observed at 852–936 K. The 200 μm thick tablet is transparent over the spectral range of 0.3–6.5 μm and the band gap is found as Eg ∼ 6.29 eV. Nonlinear optical response of Rb3NdB6O12 tested via SHG is estimated to be higher than that of K3YB6O12. Blue shift of Nd luminescent lines is found in comparison with other borates. The vibrational parameters of Rb3NdB6O12 are evaluated by experimental methods.

AB - New noncentrosymmetric rare earth borate Rb3NdB6O12 is found in the ternary system Rb2O–Nd2O3–B2O3. The Rb3NdB6O12 powder was fabricated by solid state synthesis at 1050 K for 72 h and the crystal structure was obtained by the Rietveld method. Rb3NdB6O12 crystallized in space group R32 with unit cell parameters a = 13.5236(4), c = 31.162(1) Å, Z = 3. From DSC measurements, the reversible phase transition (I type) in Rb3NdB6O12 is observed at 852–936 K. The 200 μm thick tablet is transparent over the spectral range of 0.3–6.5 μm and the band gap is found as Eg ∼ 6.29 eV. Nonlinear optical response of Rb3NdB6O12 tested via SHG is estimated to be higher than that of K3YB6O12. Blue shift of Nd luminescent lines is found in comparison with other borates. The vibrational parameters of Rb3NdB6O12 are evaluated by experimental methods.

KW - DSC

KW - Raman scattering

KW - Rietveld refinement

KW - Rubidium neodymium borate

KW - Solid state reaction

KW - NONLINEAR-OPTICAL CRYSTAL

KW - LUMINESCENCE

KW - RAMAN-SPECTROSCOPY

KW - GROWTH

KW - ORTHOBORATE

KW - NA3LA9O3(BO3)(8)

KW - ELECTRONIC-STRUCTURE

UR - http://www.scopus.com/inward/record.url?scp=85015669916&partnerID=8YFLogxK

U2 - 10.1016/j.apt.2017.02.019

DO - 10.1016/j.apt.2017.02.019

M3 - Article

AN - SCOPUS:85015669916

VL - 28

SP - 1309

EP - 1315

JO - Advanced Powder Technology

JF - Advanced Powder Technology

SN - 0921-8831

IS - 5

ER -

ID: 10272248