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Eu(III) and Tb(III) complexes based on diphenyl(pyrimidin-2-Yl)phosphine oxide : Synthesis, structure and photoluminescent properties. / Bryleva, Yu A.; Artem’ev, A. V.; Glinskaya, L. A. и др.

в: Journal of Structural Chemistry, Том 62, № 2, 02.2021, стр. 265-276.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Bryleva, YA, Artem’ev, AV, Glinskaya, LA, Samsonenko, DG, Rakhmanova, MI, Davydova, MP & Yzhikova, KM 2021, 'Eu(III) and Tb(III) complexes based on diphenyl(pyrimidin-2-Yl)phosphine oxide: Synthesis, structure and photoluminescent properties', Journal of Structural Chemistry, Том. 62, № 2, стр. 265-276. https://doi.org/10.1134/S0022476621020116

APA

Bryleva, Y. A., Artem’ev, A. V., Glinskaya, L. A., Samsonenko, D. G., Rakhmanova, M. I., Davydova, M. P., & Yzhikova, K. M. (2021). Eu(III) and Tb(III) complexes based on diphenyl(pyrimidin-2-Yl)phosphine oxide: Synthesis, structure and photoluminescent properties. Journal of Structural Chemistry, 62(2), 265-276. https://doi.org/10.1134/S0022476621020116

Vancouver

Bryleva YA, Artem’ev AV, Glinskaya LA, Samsonenko DG, Rakhmanova MI, Davydova MP и др. Eu(III) and Tb(III) complexes based on diphenyl(pyrimidin-2-Yl)phosphine oxide: Synthesis, structure and photoluminescent properties. Journal of Structural Chemistry. 2021 февр.;62(2):265-276. doi: 10.1134/S0022476621020116

Author

Bryleva, Yu A. ; Artem’ev, A. V. ; Glinskaya, L. A. и др. / Eu(III) and Tb(III) complexes based on diphenyl(pyrimidin-2-Yl)phosphine oxide : Synthesis, structure and photoluminescent properties. в: Journal of Structural Chemistry. 2021 ; Том 62, № 2. стр. 265-276.

BibTeX

@article{bbea6a572a444504abf72663fb4fdace,
title = "Eu(III) and Tb(III) complexes based on diphenyl(pyrimidin-2-Yl)phosphine oxide: Synthesis, structure and photoluminescent properties",
abstract = "Coordination compounds [Eu{Ph2P(O)Pym}2(NO3)3] (1) and [Tb{Ph2P(O)Pym}2(MeOH)(NO3)3] (2) are synthesized by the interaction of Eu(III) and Tb(III) nitrates with diphenyl(pyrimidin-2-yl)phosphine oxide (Ph2P(O)Pym). According to single crystal XRD data, the crystal structures of 1 and 2 consist of molecules of mononuclear complexes. The Ph2P(O)Pym ligand is bidentate chelating and monodentate in complexes 1 and 2 respectively; coordination polyhedra of the Ln atom are N2O8 in 1 and O9 in 2. The presence of C–H⋯O hydrogen bonds between the neighboring molecules of the complexes leads to the formation of dimeric ensembles organized in chains (in 1) and layers (in 2) by weaker hydrogen bonds. The complexes exhibit metal-centered photoluminescence in the solid state at 300 K with long lifetimes of excited states (τ > 1 ms) and luminescence quantum yields φ = 28% and 14% for complexes 1 and 2 respectively.",
keywords = "complexes, lanthanides, phosphine oxide, photoluminescence, pyrimidine, structure",
author = "Bryleva, {Yu A.} and Artem{\textquoteright}ev, {A. V.} and Glinskaya, {L. A.} and Samsonenko, {D. G.} and Rakhmanova, {M. I.} and Davydova, {M. P.} and Yzhikova, {K. M.}",
note = "Funding Information: The work was supported by RFBR within scientific project No. 19-73-00158. Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = feb,
doi = "10.1134/S0022476621020116",
language = "English",
volume = "62",
pages = "265--276",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "2",

}

RIS

TY - JOUR

T1 - Eu(III) and Tb(III) complexes based on diphenyl(pyrimidin-2-Yl)phosphine oxide

T2 - Synthesis, structure and photoluminescent properties

AU - Bryleva, Yu A.

AU - Artem’ev, A. V.

AU - Glinskaya, L. A.

AU - Samsonenko, D. G.

AU - Rakhmanova, M. I.

AU - Davydova, M. P.

AU - Yzhikova, K. M.

N1 - Funding Information: The work was supported by RFBR within scientific project No. 19-73-00158. Publisher Copyright: © 2021, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/2

Y1 - 2021/2

N2 - Coordination compounds [Eu{Ph2P(O)Pym}2(NO3)3] (1) and [Tb{Ph2P(O)Pym}2(MeOH)(NO3)3] (2) are synthesized by the interaction of Eu(III) and Tb(III) nitrates with diphenyl(pyrimidin-2-yl)phosphine oxide (Ph2P(O)Pym). According to single crystal XRD data, the crystal structures of 1 and 2 consist of molecules of mononuclear complexes. The Ph2P(O)Pym ligand is bidentate chelating and monodentate in complexes 1 and 2 respectively; coordination polyhedra of the Ln atom are N2O8 in 1 and O9 in 2. The presence of C–H⋯O hydrogen bonds between the neighboring molecules of the complexes leads to the formation of dimeric ensembles organized in chains (in 1) and layers (in 2) by weaker hydrogen bonds. The complexes exhibit metal-centered photoluminescence in the solid state at 300 K with long lifetimes of excited states (τ > 1 ms) and luminescence quantum yields φ = 28% and 14% for complexes 1 and 2 respectively.

AB - Coordination compounds [Eu{Ph2P(O)Pym}2(NO3)3] (1) and [Tb{Ph2P(O)Pym}2(MeOH)(NO3)3] (2) are synthesized by the interaction of Eu(III) and Tb(III) nitrates with diphenyl(pyrimidin-2-yl)phosphine oxide (Ph2P(O)Pym). According to single crystal XRD data, the crystal structures of 1 and 2 consist of molecules of mononuclear complexes. The Ph2P(O)Pym ligand is bidentate chelating and monodentate in complexes 1 and 2 respectively; coordination polyhedra of the Ln atom are N2O8 in 1 and O9 in 2. The presence of C–H⋯O hydrogen bonds between the neighboring molecules of the complexes leads to the formation of dimeric ensembles organized in chains (in 1) and layers (in 2) by weaker hydrogen bonds. The complexes exhibit metal-centered photoluminescence in the solid state at 300 K with long lifetimes of excited states (τ > 1 ms) and luminescence quantum yields φ = 28% and 14% for complexes 1 and 2 respectively.

KW - complexes

KW - lanthanides

KW - phosphine oxide

KW - photoluminescence

KW - pyrimidine

KW - structure

UR - http://www.scopus.com/inward/record.url?scp=85102678864&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/fdaa8411-02cc-38cc-8eed-542e7f96ebf1/

U2 - 10.1134/S0022476621020116

DO - 10.1134/S0022476621020116

M3 - Article

AN - SCOPUS:85102678864

VL - 62

SP - 265

EP - 276

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 2

ER -

ID: 28158677