Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Enthalpy of formation and lattice energy of bismuth perrhenate doped by neodymium and indium oxides. / Matskevich, N. I.; Wolf, Th; Adelmann, P. и др.
в: Thermochimica Acta, Том 658, 10.12.2017, стр. 63-67.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Enthalpy of formation and lattice energy of bismuth perrhenate doped by neodymium and indium oxides
AU - Matskevich, N. I.
AU - Wolf, Th
AU - Adelmann, P.
AU - Semerikova, A. N.
AU - Gelfond, N. V.
AU - Zolotova, E. S.
AU - Matskevich, M. Yu
PY - 2017/12/10
Y1 - 2017/12/10
N2 - For the first time the standard formation enthalpy of Bi12.5Nd1.4In0.1ReO24.5 has been determined by solution calorimetry by combining the solution enthalpies of Bi12.5Nd1.4In0.1ReO24.5, 1.4NdCl3 + 0.1InCl30.1InCl3 mixture in 2 M HCl and literature data. The lattice energy for Bi12.5Nd1.4In0.1ReO24.5 has been calculated using Born-Haber cycle. The dependence of lattice energy for Bi12.5R1.5ReO24.5 (R – rare earth element) from radius of rare earth metal was constructed. It was established that dependence was linear and had form: Ulat = −129450 + 45070 rR. Linear character of experimentally obtained dependence was explained using modified variant of Kapustinskii formula obtained by us as following: U = A + BrR.
AB - For the first time the standard formation enthalpy of Bi12.5Nd1.4In0.1ReO24.5 has been determined by solution calorimetry by combining the solution enthalpies of Bi12.5Nd1.4In0.1ReO24.5, 1.4NdCl3 + 0.1InCl30.1InCl3 mixture in 2 M HCl and literature data. The lattice energy for Bi12.5Nd1.4In0.1ReO24.5 has been calculated using Born-Haber cycle. The dependence of lattice energy for Bi12.5R1.5ReO24.5 (R – rare earth element) from radius of rare earth metal was constructed. It was established that dependence was linear and had form: Ulat = −129450 + 45070 rR. Linear character of experimentally obtained dependence was explained using modified variant of Kapustinskii formula obtained by us as following: U = A + BrR.
KW - Doped bismuth oxide
KW - Formation enthalpy
KW - Lattice energy
KW - SYSTEM
KW - PHASE
KW - LN
KW - CONDUCTIVITY
KW - STABILITY
KW - LANTHANIDE
KW - HEAT-CAPACITY
KW - YTTRIUM
UR - http://www.scopus.com/inward/record.url?scp=85032581093&partnerID=8YFLogxK
U2 - 10.1016/j.tca.2017.10.010
DO - 10.1016/j.tca.2017.10.010
M3 - Article
AN - SCOPUS:85032581093
VL - 658
SP - 63
EP - 67
JO - Thermochimica Acta
JF - Thermochimica Acta
SN - 0040-6031
ER -
ID: 9405233