Standard

Efficient MOF-Catalyzed Ortho-Para Hydrogen Conversion for Practical Liquefaction and Energy Storage. / Polyukhov, Daniil M.; Kudriavykh, Nikita A.; Gromilov, Sergey A. и др.

в: ACS Energy Letters, Том 7, № 12, 09.12.2022, стр. 4336-4341.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Polyukhov, DM, Kudriavykh, NA, Gromilov, SA, Kiryutin, AS, Poryvaev, AS & Fedin, MV 2022, 'Efficient MOF-Catalyzed Ortho-Para Hydrogen Conversion for Practical Liquefaction and Energy Storage', ACS Energy Letters, Том. 7, № 12, стр. 4336-4341. https://doi.org/10.1021/acsenergylett.2c02149

APA

Polyukhov, D. M., Kudriavykh, N. A., Gromilov, S. A., Kiryutin, A. S., Poryvaev, A. S., & Fedin, M. V. (2022). Efficient MOF-Catalyzed Ortho-Para Hydrogen Conversion for Practical Liquefaction and Energy Storage. ACS Energy Letters, 7(12), 4336-4341. https://doi.org/10.1021/acsenergylett.2c02149

Vancouver

Polyukhov DM, Kudriavykh NA, Gromilov SA, Kiryutin AS, Poryvaev AS, Fedin MV. Efficient MOF-Catalyzed Ortho-Para Hydrogen Conversion for Practical Liquefaction and Energy Storage. ACS Energy Letters. 2022 дек. 9;7(12):4336-4341. doi: 10.1021/acsenergylett.2c02149

Author

Polyukhov, Daniil M. ; Kudriavykh, Nikita A. ; Gromilov, Sergey A. и др. / Efficient MOF-Catalyzed Ortho-Para Hydrogen Conversion for Practical Liquefaction and Energy Storage. в: ACS Energy Letters. 2022 ; Том 7, № 12. стр. 4336-4341.

BibTeX

@article{6f2be54f64134338be0eab9db04988e2,
title = "Efficient MOF-Catalyzed Ortho-Para Hydrogen Conversion for Practical Liquefaction and Energy Storage",
abstract = "Parahydrogen, being one of two nuclear spin isomers of molecular hydrogen, is required in a number of applications, including hydrogen liquefaction for energy storage and transportation. Obtaining pure parahydrogen is vital for these tasks, thus requiring approaches for efficient ortho-para (OP) hydrogen conversion. In this work, we for the first time demonstrate the extraordinary potential of metal-organic frameworks (MOF) as OP-conversion catalysts. In particular, the specific conversion rate constant of Ni-MOF-74 is found 145-fold higher than that of industrially used catalysts (e.g., hydrous ferric oxide), thus opening new horizons in hydrogen liquefaction and storage and, ultimately, in the broad use of hydrogen energy.",
author = "Polyukhov, {Daniil M.} and Kudriavykh, {Nikita A.} and Gromilov, {Sergey A.} and Kiryutin, {Alexey S.} and Poryvaev, {Artem S.} and Fedin, {Matvey V.}",
note = "Funding Information: This work was supported by the Ministry of Science and Higher Education (075-15-2021-580). We are very thankful to Prof. Geoffrey Bodenhausen (ENS Paris) for fruitful and stimulating discussions. Publisher Copyright: {\textcopyright} 2022 American Chemical Society.",
year = "2022",
month = dec,
day = "9",
doi = "10.1021/acsenergylett.2c02149",
language = "English",
volume = "7",
pages = "4336--4341",
journal = "ACS Energy Letters",
issn = "2380-8195",
publisher = "ACS Publication",
number = "12",

}

RIS

TY - JOUR

T1 - Efficient MOF-Catalyzed Ortho-Para Hydrogen Conversion for Practical Liquefaction and Energy Storage

AU - Polyukhov, Daniil M.

AU - Kudriavykh, Nikita A.

AU - Gromilov, Sergey A.

AU - Kiryutin, Alexey S.

AU - Poryvaev, Artem S.

AU - Fedin, Matvey V.

N1 - Funding Information: This work was supported by the Ministry of Science and Higher Education (075-15-2021-580). We are very thankful to Prof. Geoffrey Bodenhausen (ENS Paris) for fruitful and stimulating discussions. Publisher Copyright: © 2022 American Chemical Society.

PY - 2022/12/9

Y1 - 2022/12/9

N2 - Parahydrogen, being one of two nuclear spin isomers of molecular hydrogen, is required in a number of applications, including hydrogen liquefaction for energy storage and transportation. Obtaining pure parahydrogen is vital for these tasks, thus requiring approaches for efficient ortho-para (OP) hydrogen conversion. In this work, we for the first time demonstrate the extraordinary potential of metal-organic frameworks (MOF) as OP-conversion catalysts. In particular, the specific conversion rate constant of Ni-MOF-74 is found 145-fold higher than that of industrially used catalysts (e.g., hydrous ferric oxide), thus opening new horizons in hydrogen liquefaction and storage and, ultimately, in the broad use of hydrogen energy.

AB - Parahydrogen, being one of two nuclear spin isomers of molecular hydrogen, is required in a number of applications, including hydrogen liquefaction for energy storage and transportation. Obtaining pure parahydrogen is vital for these tasks, thus requiring approaches for efficient ortho-para (OP) hydrogen conversion. In this work, we for the first time demonstrate the extraordinary potential of metal-organic frameworks (MOF) as OP-conversion catalysts. In particular, the specific conversion rate constant of Ni-MOF-74 is found 145-fold higher than that of industrially used catalysts (e.g., hydrous ferric oxide), thus opening new horizons in hydrogen liquefaction and storage and, ultimately, in the broad use of hydrogen energy.

UR - http://www.scopus.com/inward/record.url?scp=85141958849&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/c739794c-7154-38a8-92cb-b15f53ac38b8/

U2 - 10.1021/acsenergylett.2c02149

DO - 10.1021/acsenergylett.2c02149

M3 - Article

AN - SCOPUS:85141958849

VL - 7

SP - 4336

EP - 4341

JO - ACS Energy Letters

JF - ACS Energy Letters

SN - 2380-8195

IS - 12

ER -

ID: 39517089