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Effect of the Nature of Supports and the Degree of Palladium Dispersion on the Catalyst Activity and Selectivity in the Sunflower Oil Hydrogenation Reaction. / Romanenko, A. V.; Simonov, P. A.; Kulagina, M. A. и др.

в: Catalysis in Industry, Том 15, № 4, 12.2023, стр. 374-386.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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Romanenko AV, Simonov PA, Kulagina MA, Udalova SI, Voropaev IN, Bukhtiyarova GA. Effect of the Nature of Supports and the Degree of Palladium Dispersion on the Catalyst Activity and Selectivity in the Sunflower Oil Hydrogenation Reaction. Catalysis in Industry. 2023 дек.;15(4):374-386. doi: 10.1134/S2070050423040098

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BibTeX

@article{c31d71b810ca4e61a180146ae9ef81ea,
title = "Effect of the Nature of Supports and the Degree of Palladium Dispersion on the Catalyst Activity and Selectivity in the Sunflower Oil Hydrogenation Reaction",
abstract = "Results of studying the Pd/C and Pd/O powder catalysts synthesized by the deposition of 0.5 and 1.0 wt % Pd on carbon materials (Sibunit 159k, thermal carbon black T-900, Vulcan XC-72R) and oxide supports (Ox: γ-Al2O3, Cr2O3, Ga2O3, TiO2, Ta2O5, and V2O5, diatomaceous earth FW-70) and their catalytic properties in the partial hydrogenation of sunflower oil were described. Using a Parr fixed-bed reactor, comparative tests of the catalysts in the kinetic mode conducted to determine their activity (SCA, V 0) and trans-isomerization selectivity parameters (S tr). The effect of the average particle size of supported palladium (d CO) on these parameters in a wide range of d CO values was discussed.",
keywords = "effect of support, palladium catalysts, partial hydrogenation, sunflower oil",
author = "Romanenko, {A. V.} and Simonov, {P. A.} and Kulagina, {M. A.} and Udalova, {S. I.} and Voropaev, {I. N.} and Bukhtiyarova, {G. A.}",
note = "This work was supported by the Ministry of Science and Higher Education of the Russian Federation under a state task to Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences (project no. AAAA-A21-121011390055-8). Публикация для корректировки.",
year = "2023",
month = dec,
doi = "10.1134/S2070050423040098",
language = "English",
volume = "15",
pages = "374--386",
journal = "Catalysis in Industry",
issn = "2070-0504",
publisher = "Maik Nauka-Interperiodica Publishing",
number = "4",

}

RIS

TY - JOUR

T1 - Effect of the Nature of Supports and the Degree of Palladium Dispersion on the Catalyst Activity and Selectivity in the Sunflower Oil Hydrogenation Reaction

AU - Romanenko, A. V.

AU - Simonov, P. A.

AU - Kulagina, M. A.

AU - Udalova, S. I.

AU - Voropaev, I. N.

AU - Bukhtiyarova, G. A.

N1 - This work was supported by the Ministry of Science and Higher Education of the Russian Federation under a state task to Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences (project no. AAAA-A21-121011390055-8). Публикация для корректировки.

PY - 2023/12

Y1 - 2023/12

N2 - Results of studying the Pd/C and Pd/O powder catalysts synthesized by the deposition of 0.5 and 1.0 wt % Pd on carbon materials (Sibunit 159k, thermal carbon black T-900, Vulcan XC-72R) and oxide supports (Ox: γ-Al2O3, Cr2O3, Ga2O3, TiO2, Ta2O5, and V2O5, diatomaceous earth FW-70) and their catalytic properties in the partial hydrogenation of sunflower oil were described. Using a Parr fixed-bed reactor, comparative tests of the catalysts in the kinetic mode conducted to determine their activity (SCA, V 0) and trans-isomerization selectivity parameters (S tr). The effect of the average particle size of supported palladium (d CO) on these parameters in a wide range of d CO values was discussed.

AB - Results of studying the Pd/C and Pd/O powder catalysts synthesized by the deposition of 0.5 and 1.0 wt % Pd on carbon materials (Sibunit 159k, thermal carbon black T-900, Vulcan XC-72R) and oxide supports (Ox: γ-Al2O3, Cr2O3, Ga2O3, TiO2, Ta2O5, and V2O5, diatomaceous earth FW-70) and their catalytic properties in the partial hydrogenation of sunflower oil were described. Using a Parr fixed-bed reactor, comparative tests of the catalysts in the kinetic mode conducted to determine their activity (SCA, V 0) and trans-isomerization selectivity parameters (S tr). The effect of the average particle size of supported palladium (d CO) on these parameters in a wide range of d CO values was discussed.

KW - effect of support

KW - palladium catalysts

KW - partial hydrogenation

KW - sunflower oil

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85180556276&origin=inward&txGid=e505b449bab895ba09fef73d0c2977c3

UR - https://www.mendeley.com/catalogue/5e0ea40b-c99a-3cd5-a98d-a9023f6731e9/

U2 - 10.1134/S2070050423040098

DO - 10.1134/S2070050423040098

M3 - Article

VL - 15

SP - 374

EP - 386

JO - Catalysis in Industry

JF - Catalysis in Industry

SN - 2070-0504

IS - 4

ER -

ID: 59543387