TY - JOUR

T1 - Effect of CO2 on crystallization and properties of diamond from ultra-alkaline carbonate melt

AU - Palyanov, Yuri N.

AU - Kupriyanov, Igor N.

AU - Sokol, Alexander G.

AU - Borzdov, Yuri M.

AU - Khokhryakov, Alexander F.

PY - 2016/11/15

Y1 - 2016/11/15

N2 - An experimental study on diamond crystallization in CO2-rich sodium-carbonate melts has been undertaken at a pressure of 6.3 GPa in the temperature range of 1250–1570 °C and at 7.5 GPa in the temperature range of 1300–1700 °C. Sodium oxalate (Na2C2O4) was used as the starting material, which over the course of the experiment decomposed to form sodium carbonate, carbon dioxide and elemental carbon. The effects of pressure, temperature and dissolved CO2 in the ultra-alkaline carbonate melt on diamond crystallization, morphology, internal structure and defect-and-impurity content of diamond crystals are established. Diamond growth is found to proceed with formation of vicinal structures on the {100} and {111} faces, resulting eventually in the formation of rounded polyhedrons, whose shape is determined by the combination tetragon–trioctahedron, trigon–trioctahedron and cube faces. Spectroscopic studies reveal that the crystallized diamonds are characterized by specific infrared absorption and photoluminescence spectra. The defects responsible for the 1065 cm− 1 band dominating in the IR spectra and the 566 nm optical system dominating in the PL spectra are tentatively assigned to oxygen impurities in diamond.

AB - An experimental study on diamond crystallization in CO2-rich sodium-carbonate melts has been undertaken at a pressure of 6.3 GPa in the temperature range of 1250–1570 °C and at 7.5 GPa in the temperature range of 1300–1700 °C. Sodium oxalate (Na2C2O4) was used as the starting material, which over the course of the experiment decomposed to form sodium carbonate, carbon dioxide and elemental carbon. The effects of pressure, temperature and dissolved CO2 in the ultra-alkaline carbonate melt on diamond crystallization, morphology, internal structure and defect-and-impurity content of diamond crystals are established. Diamond growth is found to proceed with formation of vicinal structures on the {100} and {111} faces, resulting eventually in the formation of rounded polyhedrons, whose shape is determined by the combination tetragon–trioctahedron, trigon–trioctahedron and cube faces. Spectroscopic studies reveal that the crystallized diamonds are characterized by specific infrared absorption and photoluminescence spectra. The defects responsible for the 1065 cm− 1 band dominating in the IR spectra and the 566 nm optical system dominating in the PL spectra are tentatively assigned to oxygen impurities in diamond.

KW - Alkaline carbonate melts

KW - CO-fluid

KW - Defects and impurities

KW - Diamond formation

KW - Diamond properties

KW - HPHT experiment

UR - http://www.scopus.com/inward/record.url?scp=84996618811&partnerID=8YFLogxK

U2 - 10.1016/j.lithos.2016.05.021

DO - 10.1016/j.lithos.2016.05.021

M3 - Article

AN - SCOPUS:84996618811

VL - 265

SP - 339

EP - 350

JO - Lithos

JF - Lithos

SN - 0024-4937

ER -