Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Effect of carbon coating on spontaneous C12A7 whisker formation. / Zaikovskii, Vladimir I.; Volodin, Alexander M.; Stoyanovskii, Vladimir O. и др.
в: Applied Surface Science, Том 444, 30.06.2018, стр. 336-338.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Effect of carbon coating on spontaneous C12A7 whisker formation
AU - Zaikovskii, Vladimir I.
AU - Volodin, Alexander M.
AU - Stoyanovskii, Vladimir O.
AU - Cherepanova, Svetlana V.
AU - Vedyagin, Aleksey A.
PY - 2018/6/30
Y1 - 2018/6/30
N2 - A carbon nanoreactor concept was applied to study the stabilization effect of carbon shell on phase composition and morphology of dodecacalcium hepta-aluminate Ca12Al14O33. The starting C12A7 powder was obtained using aluminum and calcium hydroxides as precursors. Carbon shell was formed by a chemical vapor deposition of divinyl at 550 °C. After the calcination at 1400 °C, the product was characterized by X-ray diffraction analysis (XRD) and high resolution transmission electron microscopy (HRTEM). It was observed for a first time that spontaneous formation of calcium aluminate whiskers take place under the conditions described. Each whisker consists of a ‘head’ (globular particle of 0.5 microns in diameter) and a ‘tail’ (prolonged whisker of few microns in length and 0.1–0.2 microns in diameter). According to HRTEM, the ‘head’ is characterized with microcrystal lattice of Ca12Al14O33 compound. XRD data show the presence of CaAl2O4 phase traces. The ‘head’ and ‘tail’ of the whisker are covered with structured graphene layers of 10 nm and 3 nm, correspondingly.
AB - A carbon nanoreactor concept was applied to study the stabilization effect of carbon shell on phase composition and morphology of dodecacalcium hepta-aluminate Ca12Al14O33. The starting C12A7 powder was obtained using aluminum and calcium hydroxides as precursors. Carbon shell was formed by a chemical vapor deposition of divinyl at 550 °C. After the calcination at 1400 °C, the product was characterized by X-ray diffraction analysis (XRD) and high resolution transmission electron microscopy (HRTEM). It was observed for a first time that spontaneous formation of calcium aluminate whiskers take place under the conditions described. Each whisker consists of a ‘head’ (globular particle of 0.5 microns in diameter) and a ‘tail’ (prolonged whisker of few microns in length and 0.1–0.2 microns in diameter). According to HRTEM, the ‘head’ is characterized with microcrystal lattice of Ca12Al14O33 compound. XRD data show the presence of CaAl2O4 phase traces. The ‘head’ and ‘tail’ of the whisker are covered with structured graphene layers of 10 nm and 3 nm, correspondingly.
KW - Calcium aluminate
KW - Carbon nanoreactor
KW - HRTEM
KW - Structured carbon layers
KW - Whiskers
KW - ACID
KW - ELECTRIDE
KW - MECHANISM
KW - GROWTH
UR - http://www.scopus.com/inward/record.url?scp=85043595331&partnerID=8YFLogxK
U2 - 10.1016/j.apsusc.2018.03.056
DO - 10.1016/j.apsusc.2018.03.056
M3 - Article
AN - SCOPUS:85043595331
VL - 444
SP - 336
EP - 338
JO - Applied Surface Science
JF - Applied Surface Science
SN - 0169-4332
ER -
ID: 10474848