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Double Complex Salt [Pd(NH3)4][VO(H2O)(C2O4)2]·2H2O: Structure and Thermal Properties. / Rudzis, Z. V.; Vorobyeva, S. N.; Sukhikh, T. S. и др.

в: Journal of Structural Chemistry, Том 66, № 5, 02.06.2025, стр. 955-965.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Rudzis, ZV, Vorobyeva, SN, Sukhikh, TS, Filatov, EY, Nadolinny, VA, Berdyugin, SN & Korenev, SV 2025, 'Double Complex Salt [Pd(NH3)4][VO(H2O)(C2O4)2]·2H2O: Structure and Thermal Properties', Journal of Structural Chemistry, Том. 66, № 5, стр. 955-965. https://doi.org/10.1134/S0022476625050099

APA

Rudzis, Z. V., Vorobyeva, S. N., Sukhikh, T. S., Filatov, E. Y., Nadolinny, V. A., Berdyugin, S. N., & Korenev, S. V. (2025). Double Complex Salt [Pd(NH3)4][VO(H2O)(C2O4)2]·2H2O: Structure and Thermal Properties. Journal of Structural Chemistry, 66(5), 955-965. https://doi.org/10.1134/S0022476625050099

Vancouver

Rudzis ZV, Vorobyeva SN, Sukhikh TS, Filatov EY, Nadolinny VA, Berdyugin SN и др. Double Complex Salt [Pd(NH3)4][VO(H2O)(C2O4)2]·2H2O: Structure and Thermal Properties. Journal of Structural Chemistry. 2025 июнь 2;66(5):955-965. doi: 10.1134/S0022476625050099

Author

Rudzis, Z. V. ; Vorobyeva, S. N. ; Sukhikh, T. S. и др. / Double Complex Salt [Pd(NH3)4][VO(H2O)(C2O4)2]·2H2O: Structure and Thermal Properties. в: Journal of Structural Chemistry. 2025 ; Том 66, № 5. стр. 955-965.

BibTeX

@article{e340836d81da44fdafa1b20229bd650b,
title = "Double Complex Salt [Pd(NH3)4][VO(H2O)(C2O4)2]·2H2O: Structure and Thermal Properties",
abstract = "Abstract: A synthesis of the [Pd(NH3)4][VO(H2O)(C2O4)2]·2H2O double complex salt (DCS) is developed and optimized. The compound is characterized by single-crystal and powder XRD, IR spectroscopy, and diffuse reflectance spectroscopy (DRS). Crystal data: space group, a = 7.3160(10) {\AA}, b = 8.2700(2) {\AA}, c = 12.9205(2) {\AA}, α = 71.576(10)°, β = 78.477(10)°, γ = 83.844(10)°, Z = 2. An exchange interaction between complex anions is revealed by EPR. The process of DCS thermal decomposition in inert and reducing atmospheres is studied. It is established that the final thermolysis product in the reducing atmosphere is a mixture of the Pd0.90V0.10 solid solution and vanadium(III) oxide. The DRS spectra for the obtained DCS are theoretically calculated.",
keywords = "alloys, double complex salts, palladium, structure, thermal transformations, vanadium",
author = "Rudzis, {Z. V.} and Vorobyeva, {S. N.} and Sukhikh, {T. S.} and Filatov, {E. Y.} and Nadolinny, {V. A.} and Berdyugin, {S. N.} and Korenev, {S. V.}",
note = "This work was funded by the Russian Science Foundation (project No. 24-23-00260). ",
year = "2025",
month = jun,
day = "2",
doi = "10.1134/S0022476625050099",
language = "English",
volume = "66",
pages = "955--965",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer",
number = "5",

}

RIS

TY - JOUR

T1 - Double Complex Salt [Pd(NH3)4][VO(H2O)(C2O4)2]·2H2O: Structure and Thermal Properties

AU - Rudzis, Z. V.

AU - Vorobyeva, S. N.

AU - Sukhikh, T. S.

AU - Filatov, E. Y.

AU - Nadolinny, V. A.

AU - Berdyugin, S. N.

AU - Korenev, S. V.

N1 - This work was funded by the Russian Science Foundation (project No. 24-23-00260).

PY - 2025/6/2

Y1 - 2025/6/2

N2 - Abstract: A synthesis of the [Pd(NH3)4][VO(H2O)(C2O4)2]·2H2O double complex salt (DCS) is developed and optimized. The compound is characterized by single-crystal and powder XRD, IR spectroscopy, and diffuse reflectance spectroscopy (DRS). Crystal data: space group, a = 7.3160(10) Å, b = 8.2700(2) Å, c = 12.9205(2) Å, α = 71.576(10)°, β = 78.477(10)°, γ = 83.844(10)°, Z = 2. An exchange interaction between complex anions is revealed by EPR. The process of DCS thermal decomposition in inert and reducing atmospheres is studied. It is established that the final thermolysis product in the reducing atmosphere is a mixture of the Pd0.90V0.10 solid solution and vanadium(III) oxide. The DRS spectra for the obtained DCS are theoretically calculated.

AB - Abstract: A synthesis of the [Pd(NH3)4][VO(H2O)(C2O4)2]·2H2O double complex salt (DCS) is developed and optimized. The compound is characterized by single-crystal and powder XRD, IR spectroscopy, and diffuse reflectance spectroscopy (DRS). Crystal data: space group, a = 7.3160(10) Å, b = 8.2700(2) Å, c = 12.9205(2) Å, α = 71.576(10)°, β = 78.477(10)°, γ = 83.844(10)°, Z = 2. An exchange interaction between complex anions is revealed by EPR. The process of DCS thermal decomposition in inert and reducing atmospheres is studied. It is established that the final thermolysis product in the reducing atmosphere is a mixture of the Pd0.90V0.10 solid solution and vanadium(III) oxide. The DRS spectra for the obtained DCS are theoretically calculated.

KW - alloys

KW - double complex salts

KW - palladium

KW - structure

KW - thermal transformations

KW - vanadium

UR - https://www.mendeley.com/catalogue/2c0f5862-3db7-3733-8f81-d8d29a82465b/

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-105007037907&origin=inward&txGid=3d7111ca185c5855ddc4f87e2346f34f

U2 - 10.1134/S0022476625050099

DO - 10.1134/S0022476625050099

M3 - Article

VL - 66

SP - 955

EP - 965

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 5

ER -

ID: 67648226