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Do primary carriers of both positive charge and unpaired electron spin exist in irradiated propylene carbonate? / Borovkov, V. I.

в: Physical Chemistry Chemical Physics, Том 19, № 1, 21.12.2016, стр. 49-53.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Borovkov, VI 2016, 'Do primary carriers of both positive charge and unpaired electron spin exist in irradiated propylene carbonate?', Physical Chemistry Chemical Physics, Том. 19, № 1, стр. 49-53. https://doi.org/10.1039/c6cp07477d

APA

Borovkov, V. I. (2016). Do primary carriers of both positive charge and unpaired electron spin exist in irradiated propylene carbonate? Physical Chemistry Chemical Physics, 19(1), 49-53. https://doi.org/10.1039/c6cp07477d

Vancouver

Borovkov VI. Do primary carriers of both positive charge and unpaired electron spin exist in irradiated propylene carbonate? Physical Chemistry Chemical Physics. 2016 дек. 21;19(1):49-53. doi: 10.1039/c6cp07477d

Author

Borovkov, V. I. / Do primary carriers of both positive charge and unpaired electron spin exist in irradiated propylene carbonate?. в: Physical Chemistry Chemical Physics. 2016 ; Том 19, № 1. стр. 49-53.

BibTeX

@article{7f1e13054aac4048bc448c491e0da11f,
title = "Do primary carriers of both positive charge and unpaired electron spin exist in irradiated propylene carbonate?",
abstract = "In disagreement with the common concept of primary radiation-induced events in liquid carbonates, an analysis of the fluorescence response of irradiated luminophore solutions in propylene carbonate to magnetic fields reveals the presence of radical cations formed from the solvent. On the basis of their magnetic resonance characteristics, the radical cations are proposed to be ionised dimeric complexes with the spin density delocalised over two antiparallel carbonyl groups. The finding suggests that the basic models underlying the application of radiolysis to study the mechanisms of the oxidative decomposition of carbonates should be reexamined.",
keywords = "RADICAL CATIONS, ION BATTERIES, DECOMPOSITION, RADIOLYSIS",
author = "Borovkov, {V. I.}",
year = "2016",
month = dec,
day = "21",
doi = "10.1039/c6cp07477d",
language = "English",
volume = "19",
pages = "49--53",
journal = "Physical Chemistry Chemical Physics",
issn = "1463-9076",
publisher = "Royal Society of Chemistry",
number = "1",

}

RIS

TY - JOUR

T1 - Do primary carriers of both positive charge and unpaired electron spin exist in irradiated propylene carbonate?

AU - Borovkov, V. I.

PY - 2016/12/21

Y1 - 2016/12/21

N2 - In disagreement with the common concept of primary radiation-induced events in liquid carbonates, an analysis of the fluorescence response of irradiated luminophore solutions in propylene carbonate to magnetic fields reveals the presence of radical cations formed from the solvent. On the basis of their magnetic resonance characteristics, the radical cations are proposed to be ionised dimeric complexes with the spin density delocalised over two antiparallel carbonyl groups. The finding suggests that the basic models underlying the application of radiolysis to study the mechanisms of the oxidative decomposition of carbonates should be reexamined.

AB - In disagreement with the common concept of primary radiation-induced events in liquid carbonates, an analysis of the fluorescence response of irradiated luminophore solutions in propylene carbonate to magnetic fields reveals the presence of radical cations formed from the solvent. On the basis of their magnetic resonance characteristics, the radical cations are proposed to be ionised dimeric complexes with the spin density delocalised over two antiparallel carbonyl groups. The finding suggests that the basic models underlying the application of radiolysis to study the mechanisms of the oxidative decomposition of carbonates should be reexamined.

KW - RADICAL CATIONS

KW - ION BATTERIES

KW - DECOMPOSITION

KW - RADIOLYSIS

UR - http://www.scopus.com/inward/record.url?scp=85007108670&partnerID=8YFLogxK

U2 - 10.1039/c6cp07477d

DO - 10.1039/c6cp07477d

M3 - Article

C2 - 27929160

AN - SCOPUS:85007108670

VL - 19

SP - 49

EP - 53

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

SN - 1463-9076

IS - 1

ER -

ID: 12693353