Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Distribution of light alkanes in the reaction of graphite hydrogenation at pressure of 0.1–7.8 GPa and temperatures of 1000–1350°C. / Sokol, Alexander G.; Tomilenko, Anatoly A.; Bul’bak, Taras A. и др.
в: High Pressure Research, Том 38, № 4, 02.10.2018, стр. 468-481.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Distribution of light alkanes in the reaction of graphite hydrogenation at pressure of 0.1–7.8 GPa and temperatures of 1000–1350°C
AU - Sokol, Alexander G.
AU - Tomilenko, Anatoly A.
AU - Bul’bak, Taras A.
AU - Sokol, Ivan A.
AU - Persikov, Eduard S.
AU - Bukhtiyarov, Pavel G.
AU - Palyanov, Yury N.
PY - 2018/10/2
Y1 - 2018/10/2
N2 - We studied the effect of pressure and temperature on the hydrocarbon (HC) chain length distribution and total amount of HCs in the reaction of direct graphite hydrogenation at pressures of 0.1–7.8 GPa and temperatures of 1000–1350°C. An increase in pressure was found to lead both to an increase in the absolute yield of HCs due to direct graphite hydrogenation and to chain elongation of HC products. Light alkanes predominate among HCs in the entire studied range of P–T parameters. However, their concentration in quenched fluids increases as pressure is elevated, from less than 10 rel.% at 0.1 GPa to more than 40–50 rel.% at P ≥ 3.8 GPa. Methane is actually the only light alkane among reaction products at 0.1 GPa and 1000°C, while it is a minor component at 7.8 GPa and 1350°C. The most stable alkane at pressures above 3.8 GPa is ethane (C2H6).
AB - We studied the effect of pressure and temperature on the hydrocarbon (HC) chain length distribution and total amount of HCs in the reaction of direct graphite hydrogenation at pressures of 0.1–7.8 GPa and temperatures of 1000–1350°C. An increase in pressure was found to lead both to an increase in the absolute yield of HCs due to direct graphite hydrogenation and to chain elongation of HC products. Light alkanes predominate among HCs in the entire studied range of P–T parameters. However, their concentration in quenched fluids increases as pressure is elevated, from less than 10 rel.% at 0.1 GPa to more than 40–50 rel.% at P ≥ 3.8 GPa. Methane is actually the only light alkane among reaction products at 0.1 GPa and 1000°C, while it is a minor component at 7.8 GPa and 1350°C. The most stable alkane at pressures above 3.8 GPa is ethane (C2H6).
KW - gas chromatography–mass spectrometry
KW - graphite hydrogenation
KW - HPHT experiment
KW - hydrocarbons
KW - gas chromatography-mass spectrometry
KW - P-T CONDITIONS
KW - HYDROCARBONS
KW - EARTHS MANTLE
KW - STABILITY
KW - METHANE
KW - FLUID
KW - DIAMOND FORMATION
KW - NITROGEN
KW - SYSTEMS
KW - WATER
UR - http://www.scopus.com/inward/record.url?scp=85053669780&partnerID=8YFLogxK
U2 - 10.1080/08957959.2018.1517342
DO - 10.1080/08957959.2018.1517342
M3 - Article
AN - SCOPUS:85053669780
VL - 38
SP - 468
EP - 481
JO - High Pressure Research
JF - High Pressure Research
SN - 0895-7959
IS - 4
ER -
ID: 16682927