TY - CHAP

T1 - Direct C–H Oxidation of Aromatic Substrates in the Presence of Biomimetic Iron Complexes

AU - Лякин, Олег Юрьевич

AU - Талзи, Евгений Павлович

PY - 2019/10/2

Y1 - 2019/10/2

N2 - This chapter is dedicated to one of the most challenging areas of oxidation catalysis—direct oxidation of aromatic C–H groups. The development of environmentally friendly catalyst systems for the direct hydroxylation of aromatic hydrocarbons is an important task of modern catalysis. Biomimetic approach, based on the functional modeling of enzymes by iron complexes of a relatively simple structure, is considered as a promising approach for designing catalyst systems for direct aromatic hydroxylation, relying on nontoxic hydrogen peroxide used as the oxidant. The mechanism of catalytic performance of biomimetic systems is a question of primary importance; deep insight into this issue can both substantially rationalize the development of novel practical catalyst systems for the direct oxidation of aromatic hydrocarbons and enrich our knowledge on the mechanisms of natural metalloenzyme-mediated oxidations. In this chapter, the state-of-the-art in this area is provided, with the mechanistic part based mostly on the authors’ own works

AB - This chapter is dedicated to one of the most challenging areas of oxidation catalysis—direct oxidation of aromatic C–H groups. The development of environmentally friendly catalyst systems for the direct hydroxylation of aromatic hydrocarbons is an important task of modern catalysis. Biomimetic approach, based on the functional modeling of enzymes by iron complexes of a relatively simple structure, is considered as a promising approach for designing catalyst systems for direct aromatic hydroxylation, relying on nontoxic hydrogen peroxide used as the oxidant. The mechanism of catalytic performance of biomimetic systems is a question of primary importance; deep insight into this issue can both substantially rationalize the development of novel practical catalyst systems for the direct oxidation of aromatic hydrocarbons and enrich our knowledge on the mechanisms of natural metalloenzyme-mediated oxidations. In this chapter, the state-of-the-art in this area is provided, with the mechanistic part based mostly on the authors’ own works

U2 - 10.1007/978-981-32-9751-7_10

DO - 10.1007/978-981-32-9751-7_10

M3 - Chapter

SN - 978-981-32-9750-0

T3 - Green Chemistry and Sustainable Technology

SP - 253

EP - 276

BT - Frontiers of Green Catalytic Selective Oxidations

A2 - Brylyakov, Konstantin P.

PB - Springer Singapore

CY - Singapore

ER -