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Different behavior of Bi3+ to [XW12O40] n - (X = P, Si; n = 3, 4). / Mukhacheva, Anna A.; Adonin, Sergey A.; Abramov, Pavel A. и др.
в: Polyhedron, Том 141, 15.02.2018, стр. 393-397.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Different behavior of Bi3+ to [XW12O40] n - (X = P, Si; n = 3, 4)
AU - Mukhacheva, Anna A.
AU - Adonin, Sergey A.
AU - Abramov, Pavel A.
AU - Sokolov, Maxim N.
N1 - Publisher Copyright: © 2017 Elsevier Ltd
PY - 2018/2/15
Y1 - 2018/2/15
N2 - Two Keggin-type polyoxometalates ([H3PW12O40] and [H4SiW12O40]) reveal different behavior toward Bi3+ solvated by N,N-dimethylformamide (DMF): less negatively charged tungstophosphate forms double complex salt [Bi(DMF)8][PW12O40] (1), while tungstosilicate produces a molecular complex [Bi(DMF)7(HSiW12O40)]·1.7DMF·1.25H2O (2a), where POM is coordinated to Bi3+ via one of its terminal oxygen atoms. This difference in coordination can be due to different charge densities of the polyoxoanions.
AB - Two Keggin-type polyoxometalates ([H3PW12O40] and [H4SiW12O40]) reveal different behavior toward Bi3+ solvated by N,N-dimethylformamide (DMF): less negatively charged tungstophosphate forms double complex salt [Bi(DMF)8][PW12O40] (1), while tungstosilicate produces a molecular complex [Bi(DMF)7(HSiW12O40)]·1.7DMF·1.25H2O (2a), where POM is coordinated to Bi3+ via one of its terminal oxygen atoms. This difference in coordination can be due to different charge densities of the polyoxoanions.
KW - Bismuth
KW - Coordination modes
KW - Crystal structure
KW - DMF
KW - Polyoxometalate
KW - CRYSTAL-STRUCTURE
KW - PROPERTY
KW - COMPOUND
KW - METATUNGSTATE
KW - KEGGIN
KW - CHEMISTRY
KW - INCLUSION
KW - COORDINATION POLYMERS
KW - HETEROPOLYANION
KW - DERIVATIVES
UR - http://www.scopus.com/inward/record.url?scp=85034835638&partnerID=8YFLogxK
U2 - 10.1016/j.poly.2017.11.013
DO - 10.1016/j.poly.2017.11.013
M3 - Article
AN - SCOPUS:85034835638
VL - 141
SP - 393
EP - 397
JO - Polyhedron
JF - Polyhedron
SN - 0277-5387
ER -
ID: 8968806