Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Determination of the equilibrium miscibility gap in the Pd-Rh alloy system using metal nanopowders obtained by decomposition of coordination compounds. / Shubin, Yu V.; Plyusnin, P. E.; Korenev, S. V.
в: Journal of Alloys and Compounds, Том 622, 15.02.2015, стр. 1055-1060.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Determination of the equilibrium miscibility gap in the Pd-Rh alloy system using metal nanopowders obtained by decomposition of coordination compounds
AU - Shubin, Yu V.
AU - Plyusnin, P. E.
AU - Korenev, S. V.
PY - 2015/2/15
Y1 - 2015/2/15
N2 - The Pd-Rh phase diagram has been reinvestigated in the subsolidus region using X-ray diffraction, scanning and transmission electron microscopy. The true equilibrium at the miscibility boundary was achieved with the two-way approach. Nanosized powders of metastable solid solutions and two-phase palladium-rhodium mixtures were used to shorten the time required to equilibrate the system. The initial samples were prepared by decomposition of coordination compounds [Pd(NH3)2Cl2], [Rh(NH3)5Cl]Cl2, [Pd(NH3)4]3[Rh(NO2)6]2and [Pd(NH3)4][Rh(NH3)(NO2)5]. The obtained phase diagram exhibits miscibility gap wider than generally accepted with the critical point of solubility at 58 at.% Rh and 820 °C.
AB - The Pd-Rh phase diagram has been reinvestigated in the subsolidus region using X-ray diffraction, scanning and transmission electron microscopy. The true equilibrium at the miscibility boundary was achieved with the two-way approach. Nanosized powders of metastable solid solutions and two-phase palladium-rhodium mixtures were used to shorten the time required to equilibrate the system. The initial samples were prepared by decomposition of coordination compounds [Pd(NH3)2Cl2], [Rh(NH3)5Cl]Cl2, [Pd(NH3)4]3[Rh(NO2)6]2and [Pd(NH3)4][Rh(NH3)(NO2)5]. The obtained phase diagram exhibits miscibility gap wider than generally accepted with the critical point of solubility at 58 at.% Rh and 820 °C.
KW - Metals and alloys
KW - Nanofabrication
KW - Palladium
KW - Phase diagrams
KW - Rhodium
KW - X-ray diffraction
UR - http://www.scopus.com/inward/record.url?scp=84913534528&partnerID=8YFLogxK
U2 - 10.1016/j.jallcom.2014.10.187
DO - 10.1016/j.jallcom.2014.10.187
M3 - Article
AN - SCOPUS:84913534528
VL - 622
SP - 1055
EP - 1060
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
SN - 0925-8388
ER -
ID: 25402233