Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Defect induced photoluminescence and triboluminescence in layered CaLaAl3O7. / Li, Yezhou; Li, Yezhou; Koskin, Igor P. и др.
в: Dalton Transactions, Том 49, № 13, 07.04.2020, стр. 3942-3945.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Defect induced photoluminescence and triboluminescence in layered CaLaAl3O7
AU - Li, Yezhou
AU - Li, Yezhou
AU - Koskin, Igor P.
AU - Ma, Zhidong
AU - Benassi, Enrico
AU - Wang, Zhaofeng
N1 - Publisher Copyright: This journal is © The Royal Society of Chemistry. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2020/4/7
Y1 - 2020/4/7
N2 - In this work, a layered melilite structure, CaLaAl3O7, was synthesized and observed to have obvious luminescence behaviors under the stimuli of ultraviolet light and rubbing, which were called photoluminescence and triboluminescence, respectively. Considering the wide bandgap of CaLaAl3O7 and its specific crystal structure, the observed luminescence should be attributed to intrinsic defects. Both the photoluminescence and triboluminescence of CaLaAl3O7 show a strong dependence on the synthesis atmosphere, suggesting that they should be related to the oxygen vacancy. It is attractive to find that the triboluminescence of CaLaAl3O7 shows a distinct spectral characteristic compared to its photoluminescence. Further computational results suggest that the applied mechanical stimuli on the CaLaAl3O7 cell could promote the formation of the vacancies of oxygen and calcium, responsible for the spectral differences.
AB - In this work, a layered melilite structure, CaLaAl3O7, was synthesized and observed to have obvious luminescence behaviors under the stimuli of ultraviolet light and rubbing, which were called photoluminescence and triboluminescence, respectively. Considering the wide bandgap of CaLaAl3O7 and its specific crystal structure, the observed luminescence should be attributed to intrinsic defects. Both the photoluminescence and triboluminescence of CaLaAl3O7 show a strong dependence on the synthesis atmosphere, suggesting that they should be related to the oxygen vacancy. It is attractive to find that the triboluminescence of CaLaAl3O7 shows a distinct spectral characteristic compared to its photoluminescence. Further computational results suggest that the applied mechanical stimuli on the CaLaAl3O7 cell could promote the formation of the vacancies of oxygen and calcium, responsible for the spectral differences.
UR - http://www.scopus.com/inward/record.url?scp=85082779560&partnerID=8YFLogxK
U2 - 10.1039/c9dt03849c
DO - 10.1039/c9dt03849c
M3 - Article
C2 - 31729514
AN - SCOPUS:85082779560
VL - 49
SP - 3942
EP - 3945
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9226
IS - 13
ER -
ID: 23940107