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Deep-red phosphorescent organic–inorganic hybrid Mn(II) complexes based on 2-(diphenylphosphoryl)-N,N-diethylacetamide ligand. / Artem'ev, Alexander V.; Berezin, Alexey S.; Brel, Valery K. и др.

в: Polyhedron, Том 148, 01.07.2018, стр. 184-188.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Artem'ev, AV, Berezin, AS, Brel, VK, Morgalyuk, VP & Samsonenko, DG 2018, 'Deep-red phosphorescent organic–inorganic hybrid Mn(II) complexes based on 2-(diphenylphosphoryl)-N,N-diethylacetamide ligand', Polyhedron, Том. 148, стр. 184-188. https://doi.org/10.1016/j.poly.2018.04.012

APA

Artem'ev, A. V., Berezin, A. S., Brel, V. K., Morgalyuk, V. P., & Samsonenko, D. G. (2018). Deep-red phosphorescent organic–inorganic hybrid Mn(II) complexes based on 2-(diphenylphosphoryl)-N,N-diethylacetamide ligand. Polyhedron, 148, 184-188. https://doi.org/10.1016/j.poly.2018.04.012

Vancouver

Artem'ev AV, Berezin AS, Brel VK, Morgalyuk VP, Samsonenko DG. Deep-red phosphorescent organic–inorganic hybrid Mn(II) complexes based on 2-(diphenylphosphoryl)-N,N-diethylacetamide ligand. Polyhedron. 2018 июль 1;148:184-188. doi: 10.1016/j.poly.2018.04.012

Author

Artem'ev, Alexander V. ; Berezin, Alexey S. ; Brel, Valery K. и др. / Deep-red phosphorescent organic–inorganic hybrid Mn(II) complexes based on 2-(diphenylphosphoryl)-N,N-diethylacetamide ligand. в: Polyhedron. 2018 ; Том 148. стр. 184-188.

BibTeX

@article{f72ead67f77842a3949685a63b41c2d1,
title = "Deep-red phosphorescent organic–inorganic hybrid Mn(II) complexes based on 2-(diphenylphosphoryl)-N,N-diethylacetamide ligand",
abstract = "Two unprecedented organic–inorganic hybrid complexes, [Mn(L)3]MnCl4 (1) and [Mn(L)3]MnBr4 (2), have been synthesized in 88–92% yields via reaction of Mn(II) halides with Ph2P(O)CH2C(O)NEt2 (L) in a 3:2 M ratio. X-ray diffraction analysis of 2 reveals that the metal ion of the [Mn(L)3]2+ cation has an octahedral geometry, while the [MnBr4]2− anion contains tetrahedrally coordinated Mn(II). At ambient temperature, the solid complexes 1 and 2 exhibit bright deep-red phosphorescence (λmax em = 660 and 670 nm) with the lifetimes of 3–3.7 ms and photoluminescence quantum yields of 6% and 27%, respectively.",
keywords = "Deep-red emission, Manganese, Mn(II) halides, Organic–inorganic hybrid complexes, Phosphorescence, PHOTOLUMINESCENCE, LUMINESCENCE, TRIBOLUMINESCENCE, Organic-inorganic hybrid complexes, LIGHT EMISSION",
author = "Artem'ev, {Alexander V.} and Berezin, {Alexey S.} and Brel, {Valery K.} and Morgalyuk, {Vasily P.} and Samsonenko, {Denis G.}",
year = "2018",
month = jul,
day = "1",
doi = "10.1016/j.poly.2018.04.012",
language = "English",
volume = "148",
pages = "184--188",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Deep-red phosphorescent organic–inorganic hybrid Mn(II) complexes based on 2-(diphenylphosphoryl)-N,N-diethylacetamide ligand

AU - Artem'ev, Alexander V.

AU - Berezin, Alexey S.

AU - Brel, Valery K.

AU - Morgalyuk, Vasily P.

AU - Samsonenko, Denis G.

PY - 2018/7/1

Y1 - 2018/7/1

N2 - Two unprecedented organic–inorganic hybrid complexes, [Mn(L)3]MnCl4 (1) and [Mn(L)3]MnBr4 (2), have been synthesized in 88–92% yields via reaction of Mn(II) halides with Ph2P(O)CH2C(O)NEt2 (L) in a 3:2 M ratio. X-ray diffraction analysis of 2 reveals that the metal ion of the [Mn(L)3]2+ cation has an octahedral geometry, while the [MnBr4]2− anion contains tetrahedrally coordinated Mn(II). At ambient temperature, the solid complexes 1 and 2 exhibit bright deep-red phosphorescence (λmax em = 660 and 670 nm) with the lifetimes of 3–3.7 ms and photoluminescence quantum yields of 6% and 27%, respectively.

AB - Two unprecedented organic–inorganic hybrid complexes, [Mn(L)3]MnCl4 (1) and [Mn(L)3]MnBr4 (2), have been synthesized in 88–92% yields via reaction of Mn(II) halides with Ph2P(O)CH2C(O)NEt2 (L) in a 3:2 M ratio. X-ray diffraction analysis of 2 reveals that the metal ion of the [Mn(L)3]2+ cation has an octahedral geometry, while the [MnBr4]2− anion contains tetrahedrally coordinated Mn(II). At ambient temperature, the solid complexes 1 and 2 exhibit bright deep-red phosphorescence (λmax em = 660 and 670 nm) with the lifetimes of 3–3.7 ms and photoluminescence quantum yields of 6% and 27%, respectively.

KW - Deep-red emission

KW - Manganese

KW - Mn(II) halides

KW - Organic–inorganic hybrid complexes

KW - Phosphorescence

KW - PHOTOLUMINESCENCE

KW - LUMINESCENCE

KW - TRIBOLUMINESCENCE

KW - Organic-inorganic hybrid complexes

KW - LIGHT EMISSION

UR - http://www.scopus.com/inward/record.url?scp=85046171039&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2018.04.012

DO - 10.1016/j.poly.2018.04.012

M3 - Article

AN - SCOPUS:85046171039

VL - 148

SP - 184

EP - 188

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

ER -

ID: 12948658