Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Crystallographic analysis of phase transformations in danburite CaSi2B2O8. / Borisov, S. V.; Magarill, S. A.; Pervukhina, N. V.
в: Journal of Structural Chemistry, Том 61, № 7, 01.07.2020, стр. 1059-1067.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Crystallographic analysis of phase transformations in danburite CaSi2B2O8
AU - Borisov, S. V.
AU - Magarill, S. A.
AU - Pervukhina, N. V.
PY - 2020/7/1
Y1 - 2020/7/1
N2 - The crystallographic analysis of the structures of danburite CaSi2B2O8, which is orthorhombic (Pnma) at normal pressure, triclinic (P1 ¯) at a pressure of 25.4 GPa, and monoclinic (P21/c) at a pressure of 32.3 GPa, shows that they are based on a joint packing of Ca cations and O anions whose regularity increases with pressure. A common structural fragment is the configuration of atoms related by the glide reflection plane retaining for Ca and a part of O, B positions with a possible Si migration according to the seesaw mechanism (N. V. Belov).
AB - The crystallographic analysis of the structures of danburite CaSi2B2O8, which is orthorhombic (Pnma) at normal pressure, triclinic (P1 ¯) at a pressure of 25.4 GPa, and monoclinic (P21/c) at a pressure of 32.3 GPa, shows that they are based on a joint packing of Ca cations and O anions whose regularity increases with pressure. A common structural fragment is the configuration of atoms related by the glide reflection plane retaining for Ca and a part of O, B positions with a possible Si migration according to the seesaw mechanism (N. V. Belov).
KW - cation and anion sublattices
KW - crystallographic analysis
KW - danburite phases under pressure
KW - pseudo symmetry
KW - stable fragments
KW - symmetry–stability
KW - SYMMETRY
KW - symmetry-stability
UR - http://www.scopus.com/inward/record.url?scp=85090218551&partnerID=8YFLogxK
U2 - 10.1134/S0022476620070070
DO - 10.1134/S0022476620070070
M3 - Article
AN - SCOPUS:85090218551
VL - 61
SP - 1059
EP - 1067
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 7
ER -
ID: 25299763