Crystal Structures of Metal-Organic Frameworks Based on Magnesium Cations and Isomeric Tetrafluorobenzenedicarboxylate Ligands

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Crystal Structures of Metal-Organic Frameworks Based on Magnesium Cations and Isomeric Tetrafluorobenzenedicarboxylate Ligands. / Cheplakova, A. M.; Eliseev, E. A.; Samsonenko, D. G. и др.

в: Journal of Structural Chemistry, Том 65, № 6, 10, 06.2024, стр. 1219-1226.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{df21839bc5f9432a881028afa163acc3,

title = "Crystal Structures of Metal-Organic Frameworks Based on Magnesium Cations and Isomeric Tetrafluorobenzenedicarboxylate Ligands",

abstract = "Coordination polymers [Mg(EtOH)3(H2O)(1,3-tFBDC)]·EtOH (1), [Mg(MeOH)2(1,2-tFBDC)] (2), [{Mg(H2O)2(EtOH)2}Mg(1,2-tFBDC)2] (3), and [Mg(EtOH)2(1,4-tFBDC)] (4) are obtained in the interaction of magnesium hydroxide with various isomers of tetrafluorobenzene dicarboxylic acid (phthalic, isophthalic, and terephthalic; H2tFBDC) in alcohol solutions (MeOH or EtOH). The compositions and structures of these compounds are determined by single crystal X-ray diffraction. Compound 1 is a chain coordination polymer; compounds 2–4 have layered structures.",

keywords = "crystal structure, magnesium complexes, metal-organic framework, tetrafluorobenzene dicarboxylic complexes",

author = "Cheplakova, {A. M.} and Eliseev, {E. A.} and Samsonenko, {D. G.} and Fedin, {V. P.}",

note = "The study was supported by the Russian Science Foundation (Project No. 19-73-20087).",

year = "2024",

month = jun,

doi = "10.1134/S0022476624060106",

language = "English",

volume = "65",

pages = "1219--1226",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "6",

}

RIS

TY - JOUR

T1 - Crystal Structures of Metal-Organic Frameworks Based on Magnesium Cations and Isomeric Tetrafluorobenzenedicarboxylate Ligands

AU - Cheplakova, A. M.

AU - Eliseev, E. A.

AU - Samsonenko, D. G.

AU - Fedin, V. P.

N1 - The study was supported by the Russian Science Foundation (Project No. 19-73-20087).

PY - 2024/6

Y1 - 2024/6

N2 - Coordination polymers [Mg(EtOH)3(H2O)(1,3-tFBDC)]·EtOH (1), [Mg(MeOH)2(1,2-tFBDC)] (2), [{Mg(H2O)2(EtOH)2}Mg(1,2-tFBDC)2] (3), and [Mg(EtOH)2(1,4-tFBDC)] (4) are obtained in the interaction of magnesium hydroxide with various isomers of tetrafluorobenzene dicarboxylic acid (phthalic, isophthalic, and terephthalic; H2tFBDC) in alcohol solutions (MeOH or EtOH). The compositions and structures of these compounds are determined by single crystal X-ray diffraction. Compound 1 is a chain coordination polymer; compounds 2–4 have layered structures.

AB - Coordination polymers [Mg(EtOH)3(H2O)(1,3-tFBDC)]·EtOH (1), [Mg(MeOH)2(1,2-tFBDC)] (2), [{Mg(H2O)2(EtOH)2}Mg(1,2-tFBDC)2] (3), and [Mg(EtOH)2(1,4-tFBDC)] (4) are obtained in the interaction of magnesium hydroxide with various isomers of tetrafluorobenzene dicarboxylic acid (phthalic, isophthalic, and terephthalic; H2tFBDC) in alcohol solutions (MeOH or EtOH). The compositions and structures of these compounds are determined by single crystal X-ray diffraction. Compound 1 is a chain coordination polymer; compounds 2–4 have layered structures.

KW - crystal structure

KW - magnesium complexes

KW - metal-organic framework

KW - tetrafluorobenzene dicarboxylic complexes

UR - https://www.scopus.com/record/display.uri?eid=2-s2.0-85198123628&origin=inward&txGid=b657380a0799dd28c8a36c8fd7f569d7

UR - https://www.elibrary.ru/item.asp?id=68537979

UR - https://www.mendeley.com/catalogue/003e3d2d-1f9a-3b33-9d7a-b11303f9be0b/

U2 - 10.1134/S0022476624060106

DO - 10.1134/S0022476624060106

M3 - Article

VL - 65

SP - 1219

EP - 1226

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 6

M1 - 10

ER -

ID: 60749811