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Crystal Structure of Metal Complexes with 2-Imidazoline Nitroxides and Dicyanamide. / Romanenko, G. V.; Fursova, E. Yu; Letyagin, G. A. и др.

в: Journal of Structural Chemistry, Том 59, № 6, 01.11.2018, стр. 1412-1420.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Romanenko, GV, Fursova, EY, Letyagin, GA, Bogomyakov, AS, Petrova, MV, Morozov, VA & Ovcharenko, VI 2018, 'Crystal Structure of Metal Complexes with 2-Imidazoline Nitroxides and Dicyanamide', Journal of Structural Chemistry, Том. 59, № 6, стр. 1412-1420. https://doi.org/10.1134/S0022476618060239

APA

Romanenko, G. V., Fursova, E. Y., Letyagin, G. A., Bogomyakov, A. S., Petrova, M. V., Morozov, V. A., & Ovcharenko, V. I. (2018). Crystal Structure of Metal Complexes with 2-Imidazoline Nitroxides and Dicyanamide. Journal of Structural Chemistry, 59(6), 1412-1420. https://doi.org/10.1134/S0022476618060239

Vancouver

Romanenko GV, Fursova EY, Letyagin GA, Bogomyakov AS, Petrova MV, Morozov VA и др. Crystal Structure of Metal Complexes with 2-Imidazoline Nitroxides and Dicyanamide. Journal of Structural Chemistry. 2018 нояб. 1;59(6):1412-1420. doi: 10.1134/S0022476618060239

Author

Romanenko, G. V. ; Fursova, E. Yu ; Letyagin, G. A. и др. / Crystal Structure of Metal Complexes with 2-Imidazoline Nitroxides and Dicyanamide. в: Journal of Structural Chemistry. 2018 ; Том 59, № 6. стр. 1412-1420.

BibTeX

@article{46cfb4e4b9904db7a5b7594af180f207,
title = "Crystal Structure of Metal Complexes with 2-Imidazoline Nitroxides and Dicyanamide",
abstract = "The structure of heterospin complexes[M(DCA)2L2 x]·yH2O, where M = Mn, Co, Ni, Cu, Lx is the nitronyl nitroxide radical; DCA is the dicyanamide anion, y = 0, 1, or 2 is studied. It is found that the nature of[M(DCA)2L2 x]·yH2O is characterized by the formation of multiple hydrogen bonds generating ribbons, layers, or frameworks in the crystals. The analysis of magnetostructural correlations by means of band calculations of the electronic structure confirms the occurrence of ferromagnetic exchange between the unpaired electrons of paramagnetic centers in solid [Cu(DCA)2L2 1]·2H2O when the distances between the copper ion and the coordinated N-O group are short.",
keywords = "2-imidazoline nitroxides, cobalt, copper, dicyanamide, manganese, mixed-ligand complexes, nickel",
author = "Romanenko, {G. V.} and Fursova, {E. Yu} and Letyagin, {G. A.} and Bogomyakov, {A. S.} and Petrova, {M. V.} and Morozov, {V. A.} and Ovcharenko, {V. I.}",
year = "2018",
month = nov,
day = "1",
doi = "10.1134/S0022476618060239",
language = "English",
volume = "59",
pages = "1412--1420",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "6",

}

RIS

TY - JOUR

T1 - Crystal Structure of Metal Complexes with 2-Imidazoline Nitroxides and Dicyanamide

AU - Romanenko, G. V.

AU - Fursova, E. Yu

AU - Letyagin, G. A.

AU - Bogomyakov, A. S.

AU - Petrova, M. V.

AU - Morozov, V. A.

AU - Ovcharenko, V. I.

PY - 2018/11/1

Y1 - 2018/11/1

N2 - The structure of heterospin complexes[M(DCA)2L2 x]·yH2O, where M = Mn, Co, Ni, Cu, Lx is the nitronyl nitroxide radical; DCA is the dicyanamide anion, y = 0, 1, or 2 is studied. It is found that the nature of[M(DCA)2L2 x]·yH2O is characterized by the formation of multiple hydrogen bonds generating ribbons, layers, or frameworks in the crystals. The analysis of magnetostructural correlations by means of band calculations of the electronic structure confirms the occurrence of ferromagnetic exchange between the unpaired electrons of paramagnetic centers in solid [Cu(DCA)2L2 1]·2H2O when the distances between the copper ion and the coordinated N-O group are short.

AB - The structure of heterospin complexes[M(DCA)2L2 x]·yH2O, where M = Mn, Co, Ni, Cu, Lx is the nitronyl nitroxide radical; DCA is the dicyanamide anion, y = 0, 1, or 2 is studied. It is found that the nature of[M(DCA)2L2 x]·yH2O is characterized by the formation of multiple hydrogen bonds generating ribbons, layers, or frameworks in the crystals. The analysis of magnetostructural correlations by means of band calculations of the electronic structure confirms the occurrence of ferromagnetic exchange between the unpaired electrons of paramagnetic centers in solid [Cu(DCA)2L2 1]·2H2O when the distances between the copper ion and the coordinated N-O group are short.

KW - 2-imidazoline nitroxides

KW - cobalt

KW - copper

KW - dicyanamide

KW - manganese

KW - mixed-ligand complexes

KW - nickel

UR - http://www.scopus.com/inward/record.url?scp=85058433001&partnerID=8YFLogxK

U2 - 10.1134/S0022476618060239

DO - 10.1134/S0022476618060239

M3 - Article

AN - SCOPUS:85058433001

VL - 59

SP - 1412

EP - 1420

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 6

ER -

ID: 17896667