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Crystal structure of lanthanum-silicate co-substituted apatite obtained by the mechanochemical synthesis. / Makarova, S. V.; Bulina, N. V.; Chaikina, M. V. и др.
в: Materials Today: Proceedings, Том 12, 01.01.2019, стр. 61-65.Результаты исследований: Научные публикации в периодических изданиях › статья по материалам конференции › Рецензирование
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TY - JOUR
T1 - Crystal structure of lanthanum-silicate co-substituted apatite obtained by the mechanochemical synthesis
AU - Makarova, S. V.
AU - Bulina, N. V.
AU - Chaikina, M. V.
AU - Solovyov, L. A.
N1 - Publisher Copyright: © 2019 Elsevier Ltd. All rights reserved.
PY - 2019/1/1
Y1 - 2019/1/1
N2 - This paper presents a structural study of lanthanum-silicate co-substituted apatites synthesized by the mechanochemical method. The compositions of the reaction mixtures were taken such that, theoretically, compounds containing equal concentrations of lanthanum and silicon could be formed. As a high degree of crystallinity is required to carry out the refinement of the crystal structure, the synthesized nanosized co-substituted apatites were annealed at 1200 °C. It was found that, in all annealed samples, the concentration of lanthanum is slightly higher than that of silicon. In the structure of the co-substituted apatites, lanthanum occupies both crystallographic positions of calcium with site 2 preference. It was found that the simultaneous replacement of calcium by lanthanum and phosphate by silicate results in an increase in the thermal stability of the compounds in comparison with unsubstituted hydroxyapatite.
AB - This paper presents a structural study of lanthanum-silicate co-substituted apatites synthesized by the mechanochemical method. The compositions of the reaction mixtures were taken such that, theoretically, compounds containing equal concentrations of lanthanum and silicon could be formed. As a high degree of crystallinity is required to carry out the refinement of the crystal structure, the synthesized nanosized co-substituted apatites were annealed at 1200 °C. It was found that, in all annealed samples, the concentration of lanthanum is slightly higher than that of silicon. In the structure of the co-substituted apatites, lanthanum occupies both crystallographic positions of calcium with site 2 preference. It was found that the simultaneous replacement of calcium by lanthanum and phosphate by silicate results in an increase in the thermal stability of the compounds in comparison with unsubstituted hydroxyapatite.
KW - Co-substituted apatite
KW - lanthanum
KW - silicate
KW - crystal structure
KW - Silicate
KW - Lanthanum
KW - Сo-substituted apatite
KW - Crystal structure
UR - http://www.scopus.com/inward/record.url?scp=85075889018&partnerID=8YFLogxK
U2 - 10.1016/j.matpr.2019.03.064
DO - 10.1016/j.matpr.2019.03.064
M3 - Conference article
VL - 12
SP - 61
EP - 65
JO - Materials Today: Proceedings
JF - Materials Today: Proceedings
SN - 2214-7853
T2 - 5th International Conference on Fundamental Bases of Mechanochemical Technologies (FBMT)
Y2 - 25 June 2018 through 28 June 2018
ER -
ID: 23396535