Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Crystal structure of dense metal-organic frameworks based on Sc(III) and two types of ligands. / Cherezova, S. V.; Barsukova, M. O.; Samsonenko, D. G. и др.
в: Journal of Structural Chemistry, Том 62, № 6, 06.2021, стр. 897-904.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Crystal structure of dense metal-organic frameworks based on Sc(III) and two types of ligands
AU - Cherezova, S. V.
AU - Barsukova, M. O.
AU - Samsonenko, D. G.
AU - Fedin, V. P.
N1 - Funding Information: The study was supported by the Russian Science Foundation (project No.19-73-00169). Publisher Copyright: © 2021, Pleiades Publishing, Ltd.
PY - 2021/6
Y1 - 2021/6
N2 - Interaction of scandium(III) salts with 2,2′-bipyridine-4,4′-dicarboxylic and terephthalic acids under solvothermal conditions yields two novel metal-organic frameworks [Sc2(HCOO)2(OH)2(bpydc)]·2H2O (1) and [Sc(HCOO)(bdc)] (2), where bpydc2– is 2,2′-bipyridine-4,4′-dicarboxylate, bdc2– is terephthalate, HCOO– is formate. The crystal structures of compounds 1 and 2 are determined by single-crystal XRD. Both compounds contain formate anions as additional linkers and have a dense structure. The chemical composition and phase purity of studied compounds are confirmed by powder XRD, TG analysis, elemental analysis, and IR spectroscopy.
AB - Interaction of scandium(III) salts with 2,2′-bipyridine-4,4′-dicarboxylic and terephthalic acids under solvothermal conditions yields two novel metal-organic frameworks [Sc2(HCOO)2(OH)2(bpydc)]·2H2O (1) and [Sc(HCOO)(bdc)] (2), where bpydc2– is 2,2′-bipyridine-4,4′-dicarboxylate, bdc2– is terephthalate, HCOO– is formate. The crystal structures of compounds 1 and 2 are determined by single-crystal XRD. Both compounds contain formate anions as additional linkers and have a dense structure. The chemical composition and phase purity of studied compounds are confirmed by powder XRD, TG analysis, elemental analysis, and IR spectroscopy.
KW - 2,2′-bipyridine-4,4′-dicarboxylic acid
KW - metal-organic frameworks
KW - scandium
KW - terephthalic acid
KW - XRD
UR - http://www.scopus.com/inward/record.url?scp=85111112183&partnerID=8YFLogxK
U2 - 10.1134/S0022476621060093
DO - 10.1134/S0022476621060093
M3 - Article
AN - SCOPUS:85111112183
VL - 62
SP - 897
EP - 904
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 6
ER -
ID: 34031971