Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Crystal structure and thermal properties of K3[Ir(C2O4)3]·4.25H2O and K3[Ir(C2O4)3]·0.5KCl·4H2O. / Kochetygov, Ilia V.; Filatov, Evgeny Yu; Kuratieva, Natalia V. и др.
в: Journal of Thermal Analysis and Calorimetry, Том 126, № 3, 01.12.2016, стр. 1541-1548.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Crystal structure and thermal properties of K3[Ir(C2O4)3]·4.25H2O and K3[Ir(C2O4)3]·0.5KCl·4H2O
AU - Kochetygov, Ilia V.
AU - Filatov, Evgeny Yu
AU - Kuratieva, Natalia V.
AU - Plyusnin, Pavel E.
AU - Naumov, Dmitry Yu
AU - Zadesenets, Andrey V.
AU - Korenev, Sergey V.
AU - Tsygankova, Alphiya R.
AU - Logvinenko, Vladimir A.
PY - 2016/12/1
Y1 - 2016/12/1
N2 - The structures of K3[Ir(C2O4)3]·0.5KCl·4H2O and K3[Ir(C2O4)3]·4.25H2O were determined by single-crystal X-ray diffraction. Thermal transformations of the compounds were studied by several physical methods. Single-step coordination sphere decomposition followed by formation of Ir and CO2 was shown. It is found that the redox process with CO2 release passes easier for K3[Ir(C2O4)3]·0.5KCl compound than for K3[Ir(C2O4)3] one.
AB - The structures of K3[Ir(C2O4)3]·0.5KCl·4H2O and K3[Ir(C2O4)3]·4.25H2O were determined by single-crystal X-ray diffraction. Thermal transformations of the compounds were studied by several physical methods. Single-step coordination sphere decomposition followed by formation of Ir and CO2 was shown. It is found that the redox process with CO2 release passes easier for K3[Ir(C2O4)3]·0.5KCl compound than for K3[Ir(C2O4)3] one.
KW - Crystal structure
KW - Iridium
KW - Oxalatocomplexes
KW - Thermal decomposition
UR - http://www.scopus.com/inward/record.url?scp=84978096879&partnerID=8YFLogxK
U2 - 10.1007/s10973-016-5687-0
DO - 10.1007/s10973-016-5687-0
M3 - Article
AN - SCOPUS:84978096879
VL - 126
SP - 1541
EP - 1548
JO - Journal of Thermal Analysis and Calorimetry
JF - Journal of Thermal Analysis and Calorimetry
SN - 1388-6150
IS - 3
ER -
ID: 25401666