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Crystal structure and thermal properties of K3[Ir(C2O4)3]·4.25H2O and K3[Ir(C2O4)3]·0.5KCl·4H2O. / Kochetygov, Ilia V.; Filatov, Evgeny Yu; Kuratieva, Natalia V. и др.

в: Journal of Thermal Analysis and Calorimetry, Том 126, № 3, 01.12.2016, стр. 1541-1548.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

APA

Vancouver

Kochetygov IV, Filatov EY, Kuratieva NV, Plyusnin PE, Naumov DY, Zadesenets AV и др. Crystal structure and thermal properties of K3[Ir(C2O4)3]·4.25H2O and K3[Ir(C2O4)3]·0.5KCl·4H2O. Journal of Thermal Analysis and Calorimetry. 2016 дек. 1;126(3):1541-1548. doi: 10.1007/s10973-016-5687-0

Author

Kochetygov, Ilia V. ; Filatov, Evgeny Yu ; Kuratieva, Natalia V. и др. / Crystal structure and thermal properties of K3[Ir(C2O4)3]·4.25H2O and K3[Ir(C2O4)3]·0.5KCl·4H2O. в: Journal of Thermal Analysis and Calorimetry. 2016 ; Том 126, № 3. стр. 1541-1548.

BibTeX

@article{67b1b6756a87469fa9826a1347621e90,
title = "Crystal structure and thermal properties of K3[Ir(C2O4)3]·4.25H2O and K3[Ir(C2O4)3]·0.5KCl·4H2O",
abstract = "The structures of K3[Ir(C2O4)3]·0.5KCl·4H2O and K3[Ir(C2O4)3]·4.25H2O were determined by single-crystal X-ray diffraction. Thermal transformations of the compounds were studied by several physical methods. Single-step coordination sphere decomposition followed by formation of Ir and CO2 was shown. It is found that the redox process with CO2 release passes easier for K3[Ir(C2O4)3]·0.5KCl compound than for K3[Ir(C2O4)3] one.",
keywords = "Crystal structure, Iridium, Oxalatocomplexes, Thermal decomposition",
author = "Kochetygov, {Ilia V.} and Filatov, {Evgeny Yu} and Kuratieva, {Natalia V.} and Plyusnin, {Pavel E.} and Naumov, {Dmitry Yu} and Zadesenets, {Andrey V.} and Korenev, {Sergey V.} and Tsygankova, {Alphiya R.} and Logvinenko, {Vladimir A.}",
year = "2016",
month = dec,
day = "1",
doi = "10.1007/s10973-016-5687-0",
language = "English",
volume = "126",
pages = "1541--1548",
journal = "Journal of Thermal Analysis and Calorimetry",
issn = "1388-6150",
publisher = "Springer Nature",
number = "3",

}

RIS

TY - JOUR

T1 - Crystal structure and thermal properties of K3[Ir(C2O4)3]·4.25H2O and K3[Ir(C2O4)3]·0.5KCl·4H2O

AU - Kochetygov, Ilia V.

AU - Filatov, Evgeny Yu

AU - Kuratieva, Natalia V.

AU - Plyusnin, Pavel E.

AU - Naumov, Dmitry Yu

AU - Zadesenets, Andrey V.

AU - Korenev, Sergey V.

AU - Tsygankova, Alphiya R.

AU - Logvinenko, Vladimir A.

PY - 2016/12/1

Y1 - 2016/12/1

N2 - The structures of K3[Ir(C2O4)3]·0.5KCl·4H2O and K3[Ir(C2O4)3]·4.25H2O were determined by single-crystal X-ray diffraction. Thermal transformations of the compounds were studied by several physical methods. Single-step coordination sphere decomposition followed by formation of Ir and CO2 was shown. It is found that the redox process with CO2 release passes easier for K3[Ir(C2O4)3]·0.5KCl compound than for K3[Ir(C2O4)3] one.

AB - The structures of K3[Ir(C2O4)3]·0.5KCl·4H2O and K3[Ir(C2O4)3]·4.25H2O were determined by single-crystal X-ray diffraction. Thermal transformations of the compounds were studied by several physical methods. Single-step coordination sphere decomposition followed by formation of Ir and CO2 was shown. It is found that the redox process with CO2 release passes easier for K3[Ir(C2O4)3]·0.5KCl compound than for K3[Ir(C2O4)3] one.

KW - Crystal structure

KW - Iridium

KW - Oxalatocomplexes

KW - Thermal decomposition

UR - http://www.scopus.com/inward/record.url?scp=84978096879&partnerID=8YFLogxK

U2 - 10.1007/s10973-016-5687-0

DO - 10.1007/s10973-016-5687-0

M3 - Article

AN - SCOPUS:84978096879

VL - 126

SP - 1541

EP - 1548

JO - Journal of Thermal Analysis and Calorimetry

JF - Journal of Thermal Analysis and Calorimetry

SN - 1388-6150

IS - 3

ER -

ID: 25401666