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Crystal Structure and Properties of Two Samarium Β-Diketonates. / kyzy, S. Urkasym; Shen, Huang; Mosyagina, S. A. и др.

в: Journal of Structural Chemistry, Том 59, № 2, 01.03.2018, стр. 433-438.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

kyzy, SU, Shen, H, Mosyagina, SA, Korolkov, IV, Pervukhina, NV, Krisyuk, VV & Stabnikov, PA 2018, 'Crystal Structure and Properties of Two Samarium Β-Diketonates', Journal of Structural Chemistry, Том. 59, № 2, стр. 433-438. https://doi.org/10.1134/S0022476618020269

APA

kyzy, S. U., Shen, H., Mosyagina, S. A., Korolkov, I. V., Pervukhina, N. V., Krisyuk, V. V., & Stabnikov, P. A. (2018). Crystal Structure and Properties of Two Samarium Β-Diketonates. Journal of Structural Chemistry, 59(2), 433-438. https://doi.org/10.1134/S0022476618020269

Vancouver

kyzy SU, Shen H, Mosyagina SA, Korolkov IV, Pervukhina NV, Krisyuk VV и др. Crystal Structure and Properties of Two Samarium Β-Diketonates. Journal of Structural Chemistry. 2018 март 1;59(2):433-438. doi: 10.1134/S0022476618020269

Author

kyzy, S. Urkasym ; Shen, Huang ; Mosyagina, S. A. и др. / Crystal Structure and Properties of Two Samarium Β-Diketonates. в: Journal of Structural Chemistry. 2018 ; Том 59, № 2. стр. 433-438.

BibTeX

@article{54b73ee6d4c44df7afb7af9462152dff,
title = "Crystal Structure and Properties of Two Samarium Β-Diketonates",
abstract = "Samarium(III) tris-dipivaloylmethanate [Sm(dpm)3]2 (I) and sodium samarium(III) tetrakishexafluoroacetylacetonate [NaSm(hfa)4]n (II) are obtained. The crystal structures of I at 150(2) K (space group P21/n, a = 12.279(1) {\AA}, b = 27.726(3) {\AA}, с = 21.884(2) {\AA}, β = 105.317(3)°, V = 7186.0(11) {\AA}3, Z = 4) and II at 150(2) K (space group C2/c, a = 21.693(2) {\AA}, b = 12.2068(7) {\AA}, с = 14.402(1) {\AA}, β = 124.731(3)°, V = 3134.2(4) {\AA}3, Z = 4) are determined. The structure of the complex I is similar to that of the previously known dimeric [Ln(dpm)3]2 (Ln = La, Pr, Nd, Eu, Gd, Tb) complexes; and the structure of the complex II is similar to that of the known [NaLn(hfa)4]n (Ln = Y, Eu, Er) complexes. It is shown by thermogravimetry that the volatility of REE tris-dipivaloylmethanates increases from Lu to La, the volatility of REE sodium tetrakis-hexafluoroacetylacetonates increases from La to Lu.",
keywords = "crystal structure, samarium β-diketonates, volatility, LANTHANIDES, COMPLEXES, samarium beta-diketonates",
author = "kyzy, {S. Urkasym} and Huang Shen and Mosyagina, {S. A.} and Korolkov, {I. V.} and Pervukhina, {N. V.} and Krisyuk, {V. V.} and Stabnikov, {P. A.}",
note = "Publisher Copyright: {\textcopyright} 2018, Pleiades Publishing, Ltd.",
year = "2018",
month = mar,
day = "1",
doi = "10.1134/S0022476618020269",
language = "English",
volume = "59",
pages = "433--438",
journal = "Journal of Structural Chemistry",
issn = "0022-4766",
publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",
number = "2",

}

RIS

TY - JOUR

T1 - Crystal Structure and Properties of Two Samarium Β-Diketonates

AU - kyzy, S. Urkasym

AU - Shen, Huang

AU - Mosyagina, S. A.

AU - Korolkov, I. V.

AU - Pervukhina, N. V.

AU - Krisyuk, V. V.

AU - Stabnikov, P. A.

N1 - Publisher Copyright: © 2018, Pleiades Publishing, Ltd.

PY - 2018/3/1

Y1 - 2018/3/1

N2 - Samarium(III) tris-dipivaloylmethanate [Sm(dpm)3]2 (I) and sodium samarium(III) tetrakishexafluoroacetylacetonate [NaSm(hfa)4]n (II) are obtained. The crystal structures of I at 150(2) K (space group P21/n, a = 12.279(1) Å, b = 27.726(3) Å, с = 21.884(2) Å, β = 105.317(3)°, V = 7186.0(11) Å3, Z = 4) and II at 150(2) K (space group C2/c, a = 21.693(2) Å, b = 12.2068(7) Å, с = 14.402(1) Å, β = 124.731(3)°, V = 3134.2(4) Å3, Z = 4) are determined. The structure of the complex I is similar to that of the previously known dimeric [Ln(dpm)3]2 (Ln = La, Pr, Nd, Eu, Gd, Tb) complexes; and the structure of the complex II is similar to that of the known [NaLn(hfa)4]n (Ln = Y, Eu, Er) complexes. It is shown by thermogravimetry that the volatility of REE tris-dipivaloylmethanates increases from Lu to La, the volatility of REE sodium tetrakis-hexafluoroacetylacetonates increases from La to Lu.

AB - Samarium(III) tris-dipivaloylmethanate [Sm(dpm)3]2 (I) and sodium samarium(III) tetrakishexafluoroacetylacetonate [NaSm(hfa)4]n (II) are obtained. The crystal structures of I at 150(2) K (space group P21/n, a = 12.279(1) Å, b = 27.726(3) Å, с = 21.884(2) Å, β = 105.317(3)°, V = 7186.0(11) Å3, Z = 4) and II at 150(2) K (space group C2/c, a = 21.693(2) Å, b = 12.2068(7) Å, с = 14.402(1) Å, β = 124.731(3)°, V = 3134.2(4) Å3, Z = 4) are determined. The structure of the complex I is similar to that of the previously known dimeric [Ln(dpm)3]2 (Ln = La, Pr, Nd, Eu, Gd, Tb) complexes; and the structure of the complex II is similar to that of the known [NaLn(hfa)4]n (Ln = Y, Eu, Er) complexes. It is shown by thermogravimetry that the volatility of REE tris-dipivaloylmethanates increases from Lu to La, the volatility of REE sodium tetrakis-hexafluoroacetylacetonates increases from La to Lu.

KW - crystal structure

KW - samarium β-diketonates

KW - volatility

KW - LANTHANIDES

KW - COMPLEXES

KW - samarium beta-diketonates

UR - http://www.scopus.com/inward/record.url?scp=85048167968&partnerID=8YFLogxK

U2 - 10.1134/S0022476618020269

DO - 10.1134/S0022476618020269

M3 - Article

AN - SCOPUS:85048167968

VL - 59

SP - 433

EP - 438

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 2

ER -

ID: 13794989